Synthesis of 1-aryl-3H-[1,2,5]triazepino[5,4-a]benzimidazol-4(5H)-ones and quantum chemical investigation of the rotamers of the Boc-protected hydrazide key intermediate

1. Download : Download high-res image (123KB)
2. Download : Download full-size image

     

Syntheses of chiral fused 4,5-diazafluorene–bis(nopinane) derivatives

1. Download : Download high-res image (122KB)
2. Download : Download full-size image

     

Cyclometallated 1,2,3-triazol-5-ylidene iridium(III) complexes: synthesis,structure, and photoluminescence properties

1. Download high-res image (67KB)
2. Download full-size image

     

Pericyclic reactions in the synthesis of new 5-aryl-5,6-dihydroquinolino[2,1-b]quinazolin-12-ones

1. Download high-res image (52KB)
2. Download full-size image

     

Unexpected formation of dinaphthoaza-17-crown-5 ether containing γ-aminopiperidine subunit

1. Download : Download high-res image (90KB)
2. Download : Download full-size image

     

Intermolecular interactions between natural humic substances and tricyclic antidepressants

1. Download : Download high-res image (128KB)
2. Download : Download full-size image

     

Metastable states in high carbon C–(Fe,Ni, Co) films obtained by three-electrode ion-plasma sputtering

Abstract

The effect of ion-plasma deposition on the structure of high-carbon films (at. %) Fe–(20–84) % С, Co–(5–52) % С, Ni–(7–61) % С was investigated. The lattice periods and crystallite sizes of nonequilibrium phases in the as-deposited state and after heating are determined. The temperatures of the beginning and end of the decay of metastable phases during heating at a constant speed are established. The transition from an amorphous to an equilibrium crystalline state in Fe–C films passes through the stage of formation and subsequent decomposition of an intermediate, metastable hcp phase of variable composition. The electrical and hysteretic magnetic properties of the films were measured in the as-deposited state and after heat treatment. The compositions and conditions for producing films with low values of the temperature coefficient of electrical resistance and high coercive force are established. Thus, high-carbon films of Ni–61% C in the as-depoteted state and Fe–69% C films after heating to 900?K are characterized by small TCR values (± 10^?6 К^?1) over a wide temperature range.