Effect of Mechanochemical Activation on the Catalytic Properties of Ferrites with the Spinel Structure

It was found experimentally that stacking defects formed in the mechanochemical activation of zinc ferrite enhanced the specific catalytic activity in the reaction of CO oxidation. The specific rate of CO oxidation was a linear function of defect concentration, which was determined using Mössbauer spectroscopy and X-ray diffraction. A conclusion was drawn that the same centers are responsible for an increase in the catalytic activity, the sorption capacity for hydrogen sulfide, and the reactivity of zinc ferrite in the interaction with hydrochloric acid. It was assumed that analogous factors caused an increase in the catalytic activity and reactivity of magnesium ferrite.     

Viscoelastic Properties of Aqueous Anionic Surfactant (Potassium Oleate) Solutions

The dependence of the viscosity of potassium oleate salt-containing solutions on the surfactant concentration is studied. The potassium oleate concentration corresponding to the formation of semidilute solution of cylindrical micelles is determined. It is shown that, in the semidilute regime, one can distinguish two regions characterized by different exponential dependences of the viscosity on the surfactant concentration. The first region corresponds to unbreakable micelle chains that have no time to be destroyed during the characteristic time of reptation, whereas the second region corresponds to “living chains” whose lifetime is shorter than the characteristic time of reptation. In the second region, rheological properties of semidilute potassium oleate solutions are adequately described by the Maxwell model with a single relaxation time.     

Study of coherent diffractive production reactions ofp+C→[Y 0 K +]+C type and observation of narrow structures in ∑ (1385)0 K + and ∑0 K + effective mass spectra

In the experiments at the SPHINX facility in 70 GeV proton beam of the IHEP accelerator the coherent diffractive production reactions on carbon nucleip+C [(1385)⁰ K ⁺+C andp+C[⁰ K ⁺]+C were investigated. The evidences for new baryon states were obtained in the study of hyperon-kaon effective mass spectra in these two reactions:X (2050) with massM=(2052±6) MeV and width =(35 _–35 ⁺²² ) MeV inM[(1385)⁰ K ⁺] andX(2000) withM=1999±6 MeV and =91±17 MeV inM[⁰ K ⁺]. The unusual features of these massive states (small enough decay widths, anomalously large branching ratios for decays with strange particles emission) make them very serious candidates for cryptoexotic pentaquark baryons with hidden strangeness.     

α + 12C scattering at 110 MeV: Has exotic 7.65 MeV Hoyle’s state signatures “alpha-condensate” structure?

We present new measurements of the α + ¹²C elastic and inelastic (to the states 4.44, 7.65, and 9.64 MeV) scattering at E _lab = 110 MeV in the wide angular range from ～10° to 175°, which enable us to examine the condensate and cluster properties of the low-lying excited states in ¹²C. We present the diffraction-radius analysis of our data together with a considerable amount of the existing data. The magnitudes of the diffraction radii for the ground and the first excited (4.44 MeV) states are found to be equal, whereas they appear to be enhanced by ～0.6 fm both for 7.65 and 9.64 MeV states. This result shows that the radius of the Hoyle’s 0 ₂ ⁺ , 7.65 MeV state in ¹²C is by a factor of ～1.2–1.3 larger than that of the ground state. It is demonstrated that the direct transfer mechanism of ⁸Be dominates at the largest angles in all four reactions reported here. The configuration corresponding to the transfer of ⁸Be in its ground state (I ^π = 0⁺) with L = 0 turns out to be the most important for the 7.65 MeV state of ¹²C. Evidence of existence of some features of α-condensed structure of the Hoyle’s 0 ₂ ⁺ state in ¹²C was obtained: its enhanced radius and large contribution of α-particle configuration with L = 0.     

Control of the self-assembly processes in a droplet of a colloidal solution by an acoustic field

The formation of structured films consisting of ensembles of micro- or nanoparticles and possessing preset functional characteristics is studied both experimentally and theoretically. The films are obtained by drying out droplets of colloidal solutions on a solid substrate under the acoustic effect produced by a standing SAW field.     

Methyl (E)-2-(2-phenylcyclopropylidene)acetate: Synthesis, isomerization, and reaction with 1,3-diphenyl-2-benzofuran

Treatment of 3-methyl-2-phenylcycloprop-2-ene-1-carboxylic acid with potassium tert-butoxide induced its isomerization into trans-2-methylidene-3-phenylcyclopropane-1-carboxylic acid which was converted into methyl ester, and heating of the latter for 1 h in toluene gave methyl (E)-2-(2-phenylcyclopropylidene)acetate. Thermal isomerization of methyl (E)-2-(2-phenylcyclopropylidene)acetate on prolonged heating in toluene afforded 5-methoxy-3-methyl-2-phenylfuran, and the reaction with 1,3-diphenyl-2-benzofuran resulted in [4 + 2]-cycloaddition at the exocyclic double bond.     

Magnetically separable biocatalysts based on glucose oxidase for d-glucose oxidation

Russian Chemical Bulletin - Biocatalytic systems based on glucose oxidase immobilized on the surface of magnetically separable oxides SiO2 and Al2O3 were studied. Silicon and aluminum oxides...     

Viscoelastic Nanocomposites of Wormlike Micelles of Surfactant and Aluminosilicate Clay Nanoplates

Bulletin of the Lebedev Physics Institute - Viscoelastic nanocomposites based on a matrix of semidilute aqueous solutions of entangled wormlike (polymer-like) micelles of a cationic surfactant and...     

Cyclopropenes and methylenecyclopropanes in 1,3-dipolar cycloaddition reactions

The review considers the main results of the cycloaddition reactions involving cyclopropenes and methylenecyclopropanes, the compounds bearing strained three-membered rings and, respectively, endo- and exocyclic double bonds. The main attention is focused on the reactions of these compounds with 1,3-dipoles (nitrones, azomethine imines, azomethine ylides, carbonyl ylides, etc.), which gave complex heterocyclic systems with high regio- and stereoselectivity.