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排序方式: 共有95条查询结果,搜索用时 15 毫秒
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Liam McElroy Mark Nieuwenhuyzen Graham C. Saunders 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(6):678-679
The title molecule, [Mo{P(C6H5)2(C6H4F)}(HNC5H10)(CO)4] or [Mo(C18H14FP)(C5H11N)(CO)4], has irregular octahedral geometry about the Mo atom. The molecules form a complicated hydrogen‐bonded network comprising C—H?O, C—H?F and C—H?π hydrogen bonds and π–π interactions. The C—H?π and π–π interactions form chains containing C—H?π/π–π dimers linked via C—H?π interactions and the chains are linked into a three‐dimensional network via C—H?O and C—H?F hydrogen bonds. 相似文献
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Sulfur-containing compounds in diesel have been speciated by comprehensive two-dimensional gas chromatography (GCxGC) with a sulfur chemiluminescence detector (SCD). The advantages of GCxGC technique are higher resolution and greater sensitivity. GCxGC-SCD can achieve the class separation of sulfur-containing compounds with an appropriate separation column combination. The major classes of sulfur-containing compounds in diesel are benzothiophenes and dibenzothiophenes. Relative concentration of each class as well as each carbon number family can be quantitated by the summation of the integrated areas corresponding to the individual group(s) in the GCxGC space. In practical applications, GCxGC-SCD can be used to characterize different diesels and to reflect desulfurization process efficiency. In this study, GCxGC-SCD has demonstrated its value in speciation of sulfur-containing compounds classes, which is difficult to accomplish by any other single technique. 相似文献
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Liondas CA; Chrissoulidis DP 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(3):275-287
This paper is intended to clarify a misunderstanding concerningthe source singularity of the electric Green's tensor for aperfectly conducting semi-infinite cone of circular cross-section.Tai's series expansion of the Green's tensor is known to lacka singular term at the source region. Jones has reconstructedthe solution to this problem and has pointed out the differencebetween his result and that of Tai. The aim of our paper isto demonstrate that, although Jones's closed-form solution iscorrect, there is a mistake in his comparison with Tai's seriessolution. We conclude that one of the two additional singularterms that Jones claims as missing from Tai's formula must beomitted. Besides, we compare Jones's closed-form solution withSmyshlyaev's solution to the very same problem. We concludethat the magnetic field expressions given by Jones and Smyshlyaevcoincide, but a singular term is missing from Smyshlyaev's expressionfor the electric field. 相似文献
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McElroy Tucker S. Politis Dimitris N. 《Statistical Inference for Stochastic Processes》2022,25(3):471-483
Statistical Inference for Stochastic Processes - The problem of linear interpolation in the context of a multivariate time series having multiple (possibly non-consecutive) missing values is... 相似文献
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为实现三维光存储中折射率失配引起的球差补偿,建立了光学存储系统模型,获得了折射率失配引起的波前偏差函数与存储深度的表达式.采用泽尔尼克循环多项式对波前偏差函数进行补偿展开.在双光子荧光和单光子共焦荧光读出方式下,均可获得读出荧光强度与存储深度的关系:在折射率失配引起的球差未得到补偿矫正的情况下,存储深度在200 μm左右读出荧光强度基本上下降为零;当折射率失配引起的初级球差被补偿矫正后,读出荧光强度随存储深度的下降得到较好改善;当折射率失配引起的二级球差被补偿矫正后,存储深度在1 mm内存储点强度随深度基本上没有明显地变化.并且对像差补偿方法进行了具体地分析. 相似文献
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Shu L Baumbach RE Janoschek M Gonzales E Huang K Sayles TA Paglione J O'Brien J Hamlin JJ Zocco DA Ho PC McElroy CA Maple MB 《Physical review letters》2011,106(15):156403
X-ray diffraction, electrical resistivity, magnetic susceptibility, and specific heat measurements on Ce(1-x)Yb(x)CoIn5 (0≤x≤1) reveal that many of the characteristic features of the x=0 correlated electron state are stable for x≤0.775 and that phase separation occurs for x>0.775. The stability of the correlated electron state is apparently due to cooperative behavior of the Ce and Yb ions, involving their unstable valences. Low-temperature non-Fermi liquid behavior is observed and varies with x, even though there is no readily identifiable quantum critical point. The superconducting critical temperature T(c) decreases linearly with x towards 0 K as x→1, in contrast with other HF superconductors where T(c) scales with T(coh). 相似文献
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Tucker McElroy 《Extremes》2016,19(3):467-490
The paper reviews the topic of extremal time series. The literature documenting the presence of extremes in time series data is first reviewed, followed by a discussion of various probabilistic measures, along with the associated statistical inference problems. The impact of extremes upon statistical analyses is discussed, and the connection to extremal latent components is emphasized. Two data sets illustrate the methods. 相似文献