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1.
Patrick Mather Nino Grizzuti Glenn Heffner Mathias Ricker Willie E. Rochefort Markus Seitz Hans-Werner Schmidt Dale S. Pearson 《Liquid crystals》1994,17(6):811-826
In this paper, we report on the synthesis and detailed characterization of a new semiflexible nematic liquid crystalline polyester which could serve as a 'model' polyester for a variety of physical and physico-chemical investigations. The polymer is a nematic liquid over a wide temperature range-from the glass transition temperature at ∼95°C to the isotropic transition at ∼240°C. We expect this polyester to be particularly useful for studying the effect of flow on the orientation of liquid crystalline polymers, as well as the production and removal of disclinations. 相似文献
2.
3.
The effects of the organometallic compounds Bu2Sn-D -(?;)sorbitol, Bu2Sn-D -(+)glucose, Bu2Sn-D -(?)fructose and Bu2Sn-D -(+)glyceraldehyde were tested in vivo on different stages of Ascidian development, larval movement and metamorphosis. Organotin(IV) complexes are organometallic compounds widely used as industrial biocides, antifouling agents and agricultural fungicides and are toxic to a range of organisms. Two-cell stage embryos, if incubated for one hour in the organotin (IV) solutions, stopped the cleavage, which was restored when they were transferred into normal sea water. The gastrula stage was seriously affected in 10?4mol dm?3 solutions of the above-mentioned complexes: 85% of the embryos were anomalous neurulae with open neural folds, 5% were twisted larvae. The gastrulae, when incubated for 1 h in 10?5mol dm?3 solutions, developed twisted larvae in ovular envelopes and immobile larvae with twisted tails. Larvae treated with 10?4mol dm?3 and 10?5 mol dm?3 Bu2Sn-D -(?)sorbitol, Bu2Sn-D -(+)glucose and Bu2Sn-D -(+)glyceraldehyde solutions stopped swimming, did not metamorphose and afterwards underwent cytolysis. An initial hyperactivity of circular movements, followed by immobility, was observed in the larvae incubated in Bu2Sn-D -(?;)fructose. 相似文献
4.
To any spatial point-reflection geometry there corresponds a determined commutative kinematic space.Dedicated to Professor Raphael Artzy on his 80th birthday.Research supported by the NATO Scientific Affairs Division grant CRG 900103. 相似文献
5.
Franco Piacenti Mario Bianchi Piero Frediani Ugo Matteoli 《Journal of organometallic chemistry》1975,87(3):C54-C55
Both normal and secondary alkylcobalt carbonyls are shown not to undergo isomerization under catalytic “oxo” conditions, and the relevance of this obervation for the mechanism of the “oxo” reaction is discussed. 相似文献
6.
Summary LetX⊂P
3 be an irreducible smooth curve which is not a complete intersection. The main result of this paper shows that whenX is an a.c.i. of special type, i.e. its homogeneous ideal is generated by three polynomial of the same degreem, and additionallym>2, the subbundles of maximal degree of the normal bundle ofX inP
3 correspond to the singular points of maximal multiplicity of a plane curve which is the image ofX by a map
(the linear system of the surfaces of minimal degree throughX). In particular this normal bundle is stable. The initial case of this family of curves, i.e. form=3, has been studied by E. Ballico-Ph. Ellia with different methods.
This research is supported by GNSAGA (Italy).
The main results of this paper have been the object of a talk at the meeting on ?Curves in Projective Space? held at Rocca di Papa in june 1985. 相似文献
Riassunto SiaX⊂P 3 una curva irriducibile e liscia che non è una completa intersezione. Il risultato principale di questa Nota mostra che quandoX è una almost completa intersezione di tipo speciale, cioè il suo ideale omogeneo è generato minimamente da 3 polinomi dello stesso gradom, e, inoltre,m>2, i sottofibrati di grado massimo del fibrato normale diX inP 3 corrispondono ai punti singolari di molteplicità massima di una curva piana che è l’immagine diX tramite una mappa (il sistema lineare delle superficie di grado minimo passanti perX). In particolare questo fibrato normale è stabile. Il caso iniziale di questa famiglia di curve, i.e. perm=3, è stato studiato da E. Ballico-Ph. Ellia con differenti metodi.
This research is supported by GNSAGA (Italy).
The main results of this paper have been the object of a talk at the meeting on ?Curves in Projective Space? held at Rocca di Papa in june 1985. 相似文献
7.
Cushman M Yang D Gerhardt S Huber R Fischer M Kis K Bacher A 《The Journal of organic chemistry》2002,67(16):5807-5816
A series of 6-carboxyalkyl and 6-phosphonoxyalkyl derivatives of 7-oxo-8-D-ribityllumazine were synthesized as inhibitors of both Escherichia coli riboflavin synthase and Bacillus subtilis lumazine synthase. The compounds were designed to bind to both the ribitylpurine binding site and the phosphate binding site of lumazine synthase. In the carboxyalkyl series, maximum activity against both enzymes was observed with the 3'-carboxypropyl compound 22. Lengthening or shortening the chain linking the carboxyl group to the lumazine by one carbon resulted in decreased activity. In the phosphonoxyalkyl series, the 3'-phosphonoxypropyl compound 33 was more potent than the 4'-phosphonoxybutyl derivative 39 against lumazine synthase, but it was less potent against riboflavin synthase. Molecular modeling suggested that the terminal carboxyl group of 6-(3'-carboxypropyl)-7-oxo-8-D-ribityllumazine (22) may bind to the side chains of Arg127 and Lys135 of the enzyme. A hypothetical molecular model was also constructed for the binding of 6-(2'-carboxyethyl)-7-oxolumazine (15) in the active site of E. coli riboflavin synthase, which demonstrated that the active site could readily accommodate two molecules of the inhibitor. 相似文献
8.
The new hexaalkylborazine chromium tricarbonyls (n-Pr)3B3N3Me3Cr(CO)3 (V), Me3B3N3(n-Pr)3Cr(CO)3 (VI), (i-Pr)3B3N3Me3Cr(CO)3 (VII) and Me3B3N3(i-Pr)3Cr(CO)3 (VIII) have been prepared from fac-Cr(CO)3(MeCN)3 and the corresponding borazine in dioxane or without solvent. They are much more labile than the isomeric complex Et3B3N3Et3Cr(CO)3 (IV) which can be readily obtained from Et3B3N3Me3Cr(CO)3 and Et3B3N3Et3 by ring ligand exchange. The NMR., IR., UV. and Mass spectroscopic data of the complexes IV–VIII will be briefly discussed. The preparation of the borazine derivatives (n-Pr)3B3N3Me3 (IX) and Me3B3N3(n-Pr)3 (X) is also reported. 相似文献
9.
The first total synthesis of (±)-cyclooroidin, a member of the pyrrole-imidazole alkaloid family recently isolated from the sponge Agelas oroides in optically pure form, is described. The synthesis was achieved in nine linear steps, with an overall yield of 10%. Key step was a Wolff bromoketone synthesis performed on the intermediate longamide B. 相似文献
10.
The addition of carboxylic acids to dimethylamino-propinal ( 1a ) and 4-dimethyl-amino-but-3-in-2-on ( 1b ) gives, after rearrangement of the very instable primary adducts ( 2 ), Z-3-acetoxy-N,N-dimethylacrylamides and -crotonamides 3 to 8 in excellent yields and in a stereospecific manner. Similarly, the adducts of HCl and HBr to the alkynes 1a and 1b may be rearranged at low temperature by traces of acid to cis/trans equilibria of 3-halo-acrylamides and -crotonamides 9 and 10 . - On the other hand, treatment of 3-alkoxy-3-dimethylaminoacrolein with traces of acid yields alkylesters of E-3-dimethylaminoacrylic acid ( 12 , X = OR). - The preparative aspects of the rearrangement are discussed, and a brief outline of the spectroscopic properties of the compounds 3 to 8 is given. 相似文献