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1.
The disorientation and disalignment cross sections for the depolarization of Rb 52P1/2 and 52P3/2 states due to collisions with the inert gases He, Ne, Ar, Kr, Xe were measured at a temperature of 317 K. The experiments were done in a static magnetic field H0 which served to decouple the nuclear spin. Unpolarized Rb-D2-radiation was made incident on the Rb-vapour parallel to H0 thus generating an alignment in the2P3/2-state. The linear polarization of the fluorescent D2-light emitted at right angles towards the incident light beam was measured as a function of the rare gas pressure (0... 3 Torr). Similarly, for the disorientation measurements the vapour was excited by circularly polarized D2- or D1-radiation parallel to H0 and circularly polarized fluorescent light was observed at small angles towards the backward direction. From the decrease of the polarizations observed at rising pressure the cross sections were determined. The comparison with theoretical results gives satisfactory agreement.  相似文献   
2.
A reflecting time of flight mass spectrometer (RETOF) is used to study unimolecular and collision induced fragmentation of ammonia cluster ions. Synchrotron radiation from the BESSY electron storage ring is used in a range of photon energies from 9.08 up to 17.7 eV for single photon ionisation of neutral clusters in a supersonic beam. The threshold photoelectron photoion coincidence technique (TPEPICO) is used to define the energy initially deposited into the cluster ions. Metastable unimolecular decay (µs range) is studied using the RETOF's capacity for energy analysis. Under collision free conditions the by far most prominent metastable process is the evaporation of one neutral NH3 monomer from protonated clusters (NH3) n ? 2NH 4 + . Abundance of homogeneous vs. protonated cluster ions and of metastable fragments are reported as a function of photon energy and cluster size up ton=10.  相似文献   
3.
The cross sections for the collision induced transfer2P1/2mj=1/2 → mj = ?1/2 optically polarized Rb-vapour has been measured for collisions with He, Kr and Xe in the temperature range 30 °C → ~ 400 °C. The measurements were done by observing the degree of polarization in the fluorescent light emitted by the Rb-vapour. To avoid hyperfine structure effects, the nuclear spin was decoupled with a magnetic field. Calculations are presented in the temperature range 20 K → 1000 K using a semiclassical treatment and the Pascale Vandeplanque potentials. In the case of helium theoretical and experimental results are at variance, whereas for krypton and xenon satisfactory agreement is obtained. For the heavy rare gases the importance of trajectory effects, notably orbiting, becomes apparent.  相似文献   
4.
Nuclear spin polarization in diatomic potassium molecules is produced by polarization transfer between dimers and optically pumped potassium atoms. NMR signals from K2-molecules have been measured. Linewidth studies give information on relaxation processes of nuclear magnetic polarization.  相似文献   
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Ohne Zusammenfassung  相似文献   
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Ohne ZusammenfassungTübingen, 10. 7. 1927  相似文献   
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Ohne ZusammenfassungVorgetragen am 18. Sept. 1933 bei der Deutschen Mathematikertagung in Würzburg.  相似文献   
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