首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6906篇
  免费   1073篇
  国内免费   805篇
化学   5064篇
晶体学   109篇
力学   393篇
综合类   44篇
数学   737篇
物理学   2437篇
  2024年   23篇
  2023年   143篇
  2022年   251篇
  2021年   265篇
  2020年   352篇
  2019年   312篇
  2018年   279篇
  2017年   289篇
  2016年   376篇
  2015年   403篇
  2014年   374篇
  2013年   544篇
  2012年   600篇
  2011年   577篇
  2010年   425篇
  2009年   410篇
  2008年   418篇
  2007年   365篇
  2006年   342篇
  2005年   301篇
  2004年   254篇
  2003年   179篇
  2002年   209篇
  2001年   142篇
  2000年   130篇
  1999年   112篇
  1998年   55篇
  1997年   53篇
  1996年   54篇
  1995年   43篇
  1994年   22篇
  1993年   41篇
  1992年   41篇
  1991年   32篇
  1990年   24篇
  1989年   22篇
  1988年   26篇
  1987年   18篇
  1986年   23篇
  1985年   34篇
  1984年   22篇
  1983年   14篇
  1982年   24篇
  1979年   19篇
  1978年   20篇
  1977年   13篇
  1976年   16篇
  1975年   15篇
  1974年   13篇
  1973年   12篇
排序方式: 共有8784条查询结果,搜索用时 15 毫秒
1.
在实际应用中,常常使用多个重写系统。本文主要讨论重写系统和的合流性,并给出了一个重写系统和具有合流性的充分条件。  相似文献   
2.
3.
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004  相似文献   
4.
5.
应用七级目测法对浙江中部地区27个夏熟作物田样点的杂草进行了优势等级调查,将所得数据转换成重要值,以杂草在27个样点中的重要值为运算指标,应用主成分分析法和图论聚类中的最小生成树法,对24种杂草的生态学相似性进行了比较,指出了长期使用单一的除草剂导致农田杂草种群迅速更迭的原因:杂草对除草剂的敏感性差异及不同杂草间的生态学特性的差异。  相似文献   
6.
On interpolatory divergence-free wavelets   总被引:1,自引:0,他引:1  
We construct interpolating divergence-free multiwavelets based on cubic Hermite splines. We give characterizations of the relevant function spaces and indicate their use for analyzing experimental data of incompressible flow fields. We also show that the standard interpolatory wavelets, based on the Deslauriers-Dubuc interpolatory scheme or on interpolatory splines, cannot be used to construct compactly supported divergence-free interpolatory wavelets.

  相似文献   

7.
Because of package, a single FBG has dual Bragg wavelength. One is sensitive to stress and the other is sensitive to temperature. By using the special mechanism, the wavelengths can be tuned by stress and temperature respectively.  相似文献   
8.
This paper presents a model for optimally designing a collateralized mortgage obligation (CMO) with a planned amortization class (PAC)-companion structure using dynamic cash reserve. In this structure, the mortgage pool’s cash flow is allocated by rule to the two bond classes such that PAC bondholders receive substantial prepayment protection, that protection being provided by the companion bondholders. The structure we propose provides greater protection to the PAC bondholders than current structures during periods of rising interest rates when this class of bondholders faces greater extension risk. We do so by allowing a portion of the cash flow from the collateral to be reserved to meet the PAC’s scheduled cash flow in subsequent periods. The greater protection is provided by the companion bondholders exposure to interest loss. To tackle this problem, we transform the problem of designing the optimal PAC-companion structure into a standard stochastic linear programming problem which can be solved efficiently. Moreover, we present an extended model by considering the quality of the companion bond and by relaxing the PAC bondholder shortfall constraint. Based on numerical experiments through Monte Carlo simulation, we show the utility of the proposed model.  相似文献   
9.
We use the PCP-SAFT equation of state, which is of the Van der Waals type and has a sound physical basis, to predict mixture properties, such as vapor–liquid and liquid–liquid equilibria, as well as excess enthalpies. We use molecular properties, such as dipole moment, quadrupole moment, polarizability and dispersion interaction coefficients, that have been determined quantum mechanically in Part I of this publication and adjust the remaining three pure compound parameters to pure compound data. We finally present a new combination rule for the dispersion energy parameter ? that is based on the quantum mechanically determined data. The predictions based on quantum mechanically determined pure compound properties along with the new combination rule show an improved performance compared to the original PCP-SAFT combination rule.  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号