Crystal structure and morphology of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state

A series of crystals of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 Å, b = 8.82 Å, c = 23.20 Å, and β = 95.03°, as determined using electron diffraction tilting method combined with wide‐angle X‐ray diffraction experiment. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 764–769, 2006     

Improving catalyst scope: use of multiple aniline substrates to optimize a palladium-catalyzed bisdiene cyclization

[reaction: see text] Combinatorial screening of five catalyst precursors and nine ligands with three substituted aniline trapping reagents uncovered a catalyst system that promotes efficient palladium-catalyzed cyclization-trapping with a series of substituted anilines of varying steric and electronic character. The results of the parallel optimization study illustrate the interdependency of the key reaction variables.     

基于束流位置探测器的束团长度测量

分析了驱动电子束团的频域特性,研究了基于该特性进行长度测量的理论基础;使用三维模拟软件对束流位置探测器(BPM)进行建模,用模拟的方法对传输阻抗进行了数值计算;对不同长度的束团进行了测量和计算,并且分析了束团位置在真空管道中偏移对束团长度测量的影响。由测量结果可见,电子束团长度在10~100 ps(3~30 mm)时,测量误差均小于2%,满足中国工程物理研究院高平均功率自由电子激光太赫兹实验测量的使用要求。     

信息化课堂教学设计--以“刚体定轴转动的角动量及角动量守恒定律”为例

遵循“学生主体、教师主导”的教育教学理念,借助信息化教学工具,合理有效地设计好每一个教学环节.采用演示、体验、探究、问题导向和分组讨论等教学手段和方法,让学生在课堂中自主发现问题、分析问题并解决问题,实现“学生做中学、教师做中教”,大大提升教学效果.     

塞曼效应仿真实验平台

塞曼效应实验是学生了解原子具有磁矩和空间取向量子化现象的重要实验,至今塞曼效应仍是研究能级结构的重要方法之一.为了能够让学生更加清楚地了解塞曼效应实验的基本原理和操作规程,针对教学中的重点和难点,运用flash软件制作出塞曼效应仿真实验.该程序可全程高度仿真实验过程,具有界面友好、易于操作、无需安装等优点.为实验教学提供了一种新的辅助方式.     

PPLT倍频宽线宽掺镱双包层光纤放大激光

分别通过理论和实验研究了周期性极化的钽酸锂（PPLT）倍频宽线宽准连续掺镱双包层光纤放大激光.PPLT样品长为40 mm,极化周期为7.67 μm.基频光的中心波长为1064 nm,线宽约为6 nm.从基频光的光谱特性出发,利用超晶格倍频理论,解释了实验中获得的倍频温度与二次谐波功率之间的关系.在基频光的功率为2.2 W时,获得的宽线宽光纤激光倍频效率为1.8%.     

动态水声环境不确定性的预报与估计

水声环境具有强烈的时空易变性,为了解其变化中的规律和产生的不确定性,将POM海洋数值模型和水声传播模型FOR3D进行耦合,建立海洋—声学耦合数值模式。对海区的温盐等环境参数和水下声场进行预报,给出了典型断面的温度垂直结构、实验海区声速剖面和传播损失。同时,采用集合卡尔曼滤波(EnKF)方法结合海洋—声学耦合数值模式分析了水声环境的不确定性,对不同深度与频率下,传播损失的均值与满足90%的可能区间进行了计算,同时给出了不同点声速、传播损失、声纳作用距离的不确定性直方图。和实验数据的对比结果表明该方法具有较高的有效性,能对水声环境的不确定性进行合理的预报与估计。     

Optical mm-wave generation by using external modulator based on optical carrier suppression

In this paper, we have theoretically investigated the transmission performance of the optical millimeter (mm)-wave generated by using an external modulator based on optical carrier suppression for the first time. According to our theory, the data signals carried by the optical mm-wave are transmitted in the dispersion fiber without fading but are degraded greatly because of the time shift of the code edges, which still limits the transmission distance. The experimental results agree well with our theory.     

智能化掺铒光纤放大器

介绍一种智能化的掺铒光纤放大器(EDFA)技术.基于掺铒光纤的光放大特性与EDFA内外部工作参量(如构成EDFA的元器件参量、泵浦激光参量、输入/输出光信号参量等)的关系,采用智能化处理技术使EDFA能按照外界条件,自动地调整自身工作状态,使之符合应用系统的需要.智能化掺铒光纤放大技术可以使EDFA的应用更灵活,既可用作前置放大,也可用作功率放大或线路放大,同时还带来一些新的特点和优越性能.实验制作的智能化EDFA可以在输入信号小到-40dBm或大到+10dBm即约50dB的宽动态范围内正常工作.