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1.
Drummy LF Koerner H Farmer K Tan A Farmer BL Vaia RA 《The journal of physical chemistry. B》2005,109(38):17868-17878
With the use of high-resolution transmission electron microscopy the structure and morphology of montmorillonite (MMT), a material of current interest for use in polymer nanocomposites, was characterized. Using both imaging theory and experiment, the procedures needed to generate lattice images from MMT were established. These procedures involve careful control of the microscope's objective lens defocus to maximize contrast from features of a certain size, as well as limiting the total dose of electrons received by the sample. Direct images of the MMT lattice were obtained from neat Na+ MMT, organically modified MMT, and organically modified MMT/epoxy nanocomposites. The degree of crystallinity and turbostratic disorder were characterized using electron diffraction and high-resolution electron microscopy (HREM). Also, the extent of the MMT sheets to bend when processed into an epoxy matrix was directly visualized. A minimum radius of curvature tolerable for a single MMT sheet during bending deformation was estimated to be 15 nm, and from this value a critical failure strain of 0.033 was calculated. HREM can be used to improve the understanding of the structure of polymer nanocomposites at the nanometer-length scale. 相似文献
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Thomas Wiesner Dr. Zhu Wu Dr. Jie Han Prof. Dr. Lei Ji Dr. Alexandra Friedrich Dr. Ivo Krummenacher Michael Moos Prof. Dr. Christoph Lambert Prof. Dr. Holger Braunschweig Benjamin Rudin Dr. Hilmar Reiss Olena Tverskoy Dr. Frank Rominger Prof. Dr. Andreas Dreuw Prof. Dr. Todd B. Marder Dr. Jan Freudenberg Prof. Dr. Uwe H. F. Bunz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(69):e202201919
Tetraiodotetraazapentacene I4TAP , the last missing derivative in the series of halogenated silylated tetraazapentacenes, was synthesized via condensation chemistry from a TIPS-ethynylated diaminobenzothiadiazol in three steps. Single and double reduction furnished its air-stable monoanion and relatively air-stable dianion, both of which were characterized by crystallography. All three species are structurally and spectroscopically compared to non-halogenated TAP and Br4TAP . I4TAP is an n-channel material in thin-film transistors with average electron mobilities exceeding 1 cm2 (Vs)−1. 相似文献
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We demonstrate the preparation and probing of the coherence between the hyperfine ground states |S(1/2),F=1> and |5S(1/2),F=2> of the Rb87 isotope. The effects of various coherence control techniques, i.e., fractional stimulated Raman adiabatic passage and coherent population return, on the coherence are investigated. These techniques are implemented using nearly degenerate pump and Stokes lasers at 795 nm (Rb D1 transition), which couple the two hyperfine ground states via the excited state |5P(1/2),F=1> through a resonant two-photon process in which a coherent superposition of the two hyperfine ground states is established. The medium is probed by an additional weak laser, which generates a four-wave mixing signal proportional to the ground state coherence and allows us to monitor its evolution in time. The experimental data are compared with numerical simulations. 相似文献
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It is shown that s-wave induced reactions with polarized particles can be described much more conveniently in new coordinates. Even with higher partial waves, cross sections can be fitted with less parameters than in conventional expansions. 相似文献
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Let k be a commutative ring, GG finite affine algebraic k-groups, and HH the dual Hopfalgebras of the affine algebras of G resp. G. The main results of this paper are: (I) If k is semilocal (e.g. k a field) there is an H-linear, HH-colinear, unitary, augmented isomorphism HHH H, where HH is the coalgebra belonging to G/G. (II) If the k-submodule of the fixelements of (HH)* is isomorphic to k (e.g. k principal or semilocal), then HH is a Frobeniusextension of the second kind. 相似文献
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Background
In hippocampal neurons, nuclear calcium signaling is important for learning- and neuronal survival-associated gene expression. However, it is unknown whether calcium signals generated by neuronal activity at the cell membrane and propagated to the soma can unrestrictedly cross the nuclear envelope to invade the nucleus. The nuclear envelope, which allows ion transit via the nuclear pore complex, may represent a barrier for calcium and has been suggested to insulate the nucleus from activity-induced cytoplasmic calcium transients in some cell types. 相似文献9.
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