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1.
The photoexcited triplet state of phenazine in toluene glasses at 35 K is investigated by light modulation-EPR spectroscopy. From the transient EPR spectra and the kinetics in the three canonical orientations (p = x, y, z) the rate parameters are determined. Thus, the depopulation rate constants kp, the anisotropic spin lattice relaxation rate constants Wp, and the ratios between the population constants Ap are calculated: kx = (2.2 ± 0.3) × 102 s?1, ky = (0.21 ± 0.04) × 102 s?1, kz = (0.06 ± 0.03) × 102 s?1, Wx = (8.6 ± 0.9) × 103 s?1, Wy = (11.0 ± 1.0) × 103 s?1, Wz = (14.0 ± 1.4) × 103 s?1, and Ax: Ay:Az ≈ 1:0.04:0.02. It is concluded therefore that the in-plane spin state |τx > is the active one.  相似文献   
2.
In the longitudinal study of multiple sclerosis (MS) lesions, varying position of the patient inside the MRI scanner is one of the major sources of assessment errors. We propose to use analytical indices that are invariant to spatial orientation to describe the lesions, rather than focus on patient repositioning or image realignment. Studies were made on simulated lesions systematically rotated, from in vitro MS lesions scanned on different days, and from in vivo MS lesions from a patient that was scanned five times the same day with short intervals of time between scans. Each of the lesions' 3D surfaces was approximated using spherical harmonics, from which indices that are invariant to space rotation were derived. From these indices, an accurate and highly reproducible volume estimate can be derived, which is superior to the common approach of 2D slice stacking. The results indicate that the suggested approach is useful in reducing part of the errors that affect the analysis of changes of MS lesions during follow-up studies. In conclusion, our proposed method circumvents the need for precise patient repositioning and can be advantageous in MRI longitudinal studies of MS patients.  相似文献   
3.
We consider a ubiquitous scenario where a fluctuating, semipermeable vesicle is embedded in solution while enclosing a fixed number of solute particles. The swelling with increasing number of particles or decreasing concentration of the outer solution exhibits a continuous phase transition from a fluctuating state to the maximum-volume configuration, whereupon appreciable pressure difference and surface tension build up. This criticality is unique to particle-encapsulating vesicles, whose volume and inner pressure both fluctuate. It implies a universal swelling behavior of such vesicles as they approach their limiting volume and osmotic lysis.  相似文献   
4.
Minimum action solutions of some vector field equations   总被引:2,自引:0,他引:2  
The system of equations studied in this paper is –u i =g i (u) on d ,d2, withu: d n andg i (u)=G/u i . Associated with this system is the action,S(u)={1/2|u|2G(u)}. Under appropriate conditions onG (which differ ford=2 andd3) it is proved that the system has a solution,u 0, of finite action and that this solution also minimizes the action within the class {v is a solution,v has finite action,v 0}.Work partially supported by U.S. National Science Foundation Grant PHY-81-16101-A02  相似文献   
5.
Cold stage Scanning Electron Microscopy (SEM) with a rapid cooling technique makes it possible to investigate the water phase within unsaturated porous media. It is thought that this technique preserves the main features of the micromorphology of the water menisci as it exists in the liquid phase in soils. Saddle-shaped elements, as well as pendular rings of water, were observed with concave and convex curvatures of the water-air interface. The hydraulic conductivity of an unsaturated soil may be inferred from SEM photographs. Observations of isolated water menisci indicate the existence of an immobile water domain. The surface geometry of the water menisci was analyzed quantitatively and surface tension and capillary pressure were determined.  相似文献   
6.
We report on a measurement of the inclusive jet production cross section as a function of the jet transverse momentum in pp collisions at (square root s)=1.96 TeV using data collected with the upgraded Collider Detector at Fermilab in run II, corresponding to an integrated luminosity of 385 pb-1. The measurement is carried out for jets with rapidity 0.1相似文献   
7.
8.
Transgressive dune fields, which are active sand areas surrounded by vegetation, exist on many coasts. In some regions like in Fraser Island in Australia, small dunes shrink while large ones grow, although both experience the same climatic conditions. We propose a general mathematical model for the spatiotemporal dynamics of vegetation cover on sand dunes and focus on the dynamics of transgressive dunes. Among other possibilities, the model predicts growth parallel to the wind with shrinkage perpendicular to the wind, where, depending on geometry and size, a transgressive dune can initially grow although eventually shrink. The larger is the initial area the slower its stabilization process. The model’s predictions are supported by field observations from Fraser Island in Australia.  相似文献   
9.
We present the first precise measurement of the Bs0-Bs0 oscillation frequency Deltams. We use 1 fb-1 of data from pp collisions at sqrts=1.96 TeV collected with the CDF II detector at the Fermilab Tevatron. The sample contains signals of 3600 fully reconstructed hadronic Bs decays and 37,000 partially reconstructed semileptonic Bs decays. We measure the probability as a function of proper decay time that the Bs decays with the same, or opposite, flavor as the flavor at production, and we find a signal consistent with Bs0-Bs0 oscillations. The probability that random fluctuations could produce a comparable signal is 0.2%. Under the hypothesis that the signal is due to Bs0-Bs0 oscillations, we measure Deltams=17.31(-0.18)+0.33(stat)+/-0.07(syst) ps-1 and determine |Vtd/Vts|=0.208(-0.002)+0.001(expt)-0.006(+0.008)(theor).  相似文献   
10.
We report the first observation of B(0)(s)-->Psi(2S)Phi decay in p(p_) collisions at square root of 8=1.96 TeV using 360 pb(-1) of data collected by the CDF II detector at the Fermilab Tevatron. We observe 20.2 +/- 5.0 and 12.3 +/- 4.1 B(0)(s)-->Psi(2S)Phi candidates, in Psi(2S)-->mu(+)mu(-) and Phi(2S)-->J/Phipi(+)pi(-) decay modes, respectively. We present a measurement of the relative branching fraction Beta(B(0)(s)-->Psi(2S)Phi)/Beta(B(0)(s)-->J/PsiPhi)=0.52 +/- 0.13(stat) +/- 0.04(syst) +/- 0.06(BR) using the Psi(2S)-->mu(+)mu(-) decay mode.  相似文献   
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