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排序方式: 共有45条查询结果,搜索用时 11 毫秒
1.
D. Fennell Evans Martin Allen B. W. Ninham Abdel Fouda 《Journal of solution chemistry》1984,13(2):87-101
Critical micelle concentrations were determined by conductance measurements for decyl-, dodecyl-, tetradecyl- and hexadecyltrimethylammonium bromide in water at 25, 60, 95, 130, and 160°C. The results are discussed in terms of the equilibrium model and the nonlinear Poisson-Boltzmann model for micelle formation. The free energies of transferring a methylene group from water to the oil-like interior of the micelle are found to be –781 at 25°C, –796 at 60°C, –819 at 95°C, –815 at 130°C, and –787 at 160°C cal-mol–1. 相似文献
2.
S.A. Scott J.F. Davidson J.S. Dennis P.S. Fennell A.N. Hayhurst 《Proceedings of the Combustion Institute》2005,30(2):2151-2159
Three chars and an activated carbon were gasified by reaction with CO2 in a fluidised bed of sand, at 800–1050 °C. The chars were produced from (i) dried sewage sludge, (ii) car tyres, and (iii) a bituminous coal. For the conditions used, the rate of CO2 + C → 2CO was largely determined by chemical kinetics; there was a small effect from mass transfer for the most reactive char, derived from sewage sludge. The rate of CO formation, r, differed greatly for these chars, but was well described by:The reactivity of a char depends on: (i) its pore structure, (ii) catalytic activity of the associated ash, and (iii) the activity of the char’s carbon. The sewage sludge char was the most reactive, on the basis of either BET area or mass by 2 orders of magnitude. The activated carbon had the lowest reactivity per unit BET surface area, indicating that the area in its micropores is comparatively unreactive. 相似文献
3.
Fennell J.F. Koons H.C. Chen M.W. Blake J.B. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2000,28(6):2029-2036
Internal charging has been indicated as the cause of many satellite anomalies. In some cases, it has been argued that internal charging has caused satellite system failures. It may be possible to predict the occurrence of an internal charging threat in the future but that does not remove the necessity to know what the environmental threat may be. The existence, for many years now, of energetic electron and internal charging measurements in the inner magnetosphere provides the ability to identify the threat levels and generate internal charging specifications. The specifications must embody the worst-case environments that can be expected from magnetic storms and extreme solar/interplanetary conditions. Internal-charging environment specifications are needed by satellite manufacturers for setting design requirements for their systems. The specifications are also required for defining the worst-case energetic electron flux levels and total fluence levels from events. These are used for electron beam testing to verify that critical systems are immune to internal charging, for performing tests on subsystems, and for use in anomaly investigation programs. Data from the GOES, LANL, and CRRES satellites were used to develop preliminary internal-charging environment specifications for some commonly used orbits such as geosynchronous and Molniya or high earth orbits (HEO), and they are discussed. A specification is also given for a highly elliptical equatorial orbit that is used for lunar-transfer orbital maneuvers. The preliminary environments were used to estimate the shielding required to reduce worst-case electron fluxes to safe levels for these orbits 相似文献
4.
Geometry‐Related Children's Literature Improves the Geometry Achievement and Attitudes of Second‐Grade Students
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Erica M. McAndrew Wendy L. Morris Francis Fennell 《School science and mathematics》2017,117(1-2):34-51
Use of mathematics‐related literature can engage students' interest and increase their understanding of mathematical concepts. A quasi‐experimental study of two second‐grade classrooms assessed whether daily inclusion of geometry‐related literature in the classroom improved attitudes toward geometry and achievement in geometry. Consistent with the hypothesis, only the students in the classroom with a strong emphasis on geometry‐related children's literature showed a significant improvement in their attitudes about geometry over time. While both classes improved their geometry performance over the 4 weeks of the study, the class with a strong emphasis on geometry‐related literature improved significantly more (51.2%) than the control class (33.47%). Children's literature can provide a useful and interesting context in which students can develop their understanding of geometry. 相似文献
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6.
Emiliano Brini S. Shanaka Paranahewage Christopher J. Fennell Ken A. Dill 《Journal of computer-aided molecular design》2016,30(11):1067-1077
We describe here some tests we made in the SAMPL5 communal event of ‘Semi-Explicit Assembly’ (SEA), a recent method for computing solvation free energies. We combined the prospective tests of SAMPL5 with followup retrospective calculations, to improve two technical aspects of the field variant of SEA. First, SEA uses an approximate analytical surface around the solute on which a water potential is computed. We have improved and simplified the mathematical model of that surface. Second, some of the solutes in SAMPL5 were large enough to need a way to treat solvating waters interacting with ‘buried atoms’, i.e. interior atoms of the solute. We improved SEA with a buried-atom correction. We also compare SEA to Thermodynamic Integration molecular dynamics simulations, so that we can sort out force field errors. 相似文献
7.
P.S. Fennell J.S. Dennis A.N. Hayhurst 《Proceedings of the Combustion Institute》2009,32(2):2051-2058
Measurements of the oxidation of a coal char in a fluidised bed have the advantages that the rates of heat and mass transfer to and from a reacting particle are large and characterised well. However, problems have arisen from a combination of the slow, but typical, response–time (4 s) of the analysers for CO and CO2 and the slow mixing of gases when filling a fairly large fluidised bed. The resulting time constant for the sampling system was 8 s and comparable to the time for combustion at 900 °C or above. The purpose of this work was to measure the kinetics of oxidation of a char in a smaller fluidised bed (with a shorter mixing time) using an analyser for CO and CO2 with a response time as low as 0.1 s. The result is that the oxidation of an anthracitic char is now found to be first order in O2 between 700 and 900 °C; at 900 °C the order previously measured was almost zero. The activation energy is now measured here to be 145 ± 25 kJ/mol, in agreement with some early work. 相似文献
8.
We investigate pairwise electrostatic interaction methods and show that there are viable computationally efficient (O(N)) alternatives to the Ewald summation for typical modern molecular simulations. These methods are extended from the damped and cutoff-neutralized Coulombic sum originally proposed by Wolf et al. [J. Chem. Phys. 110, 8255 (1999)]. One of these, the damped shifted force method, shows a remarkable ability to reproduce the energetic and dynamic characteristics exhibited by simulations employing lattice summation techniques. Comparisons were performed with this and other pairwise methods against the smooth particle-mesh Ewald summation to see how well they reproduce the energetics and dynamics of a variety of molecular simulations. 相似文献
9.
Teachers and teacher educators play a critical role in the improvement of mathematics education. Recommendations for appropriate teacher support can be gained from examining the Teaching Principle in the document, Principles and Standards for School Mathematics ( NCTM, 2000 ), as well as earlier recommendations from the Professional Standards for Teaching Mathematics ( NCTM, 1991 ). This paper discusses implications of the recommendations for preservice teacher preparation, the continuing professional development of teachers, and mathematics teacher certification policy. 相似文献
10.
Libo Li Ken A. Dill Christopher J. Fennell 《Journal of computer-aided molecular design》2014,28(3):259-264
Here, we test a method, called semi-explicit assembly (SEA), that computes the solvation free energies of molecules in water in the SAMPL4 blind test challenge. SEA was developed with the intention of being as accurate as explicit-solvent models, but much faster to compute. It is accurate because it uses pre-simulations of simple spheres in explicit solvent to obtain structural and thermodynamic quantities, and it is fast because it parses solute free energies into regionally additive quantities. SAMPL4 provided us the opportunity to make new tests of SEA. Our tests here lead us to the following conclusions: (1) The newest version, called Field-SEA, which gives improved predictions for highly charged ions, is shown here to perform as well as the earlier versions (dipolar and quadrupolar SEA) on this broad blind SAMPL4 test set. (2) We find that both the past and present SEA models give solvation free energies that are as accurate as TIP3P. (3) Using a new approach for force field parameter optimization, we developed improved hydroxyl parameters that ensure consistency with neat-solvent dielectric constants, and found that they led to improved solvation free energies for hydroxyl-containing compounds in SAMPL4. We also learned that these hydroxyl parameters are not just fixing solvent exposed oxygens in a general sense, and therefore do not improve predictions for carbonyl or carboxylic-acid groups. Other such functional groups will need their own independent optimizations for potential improvements. Overall, these tests in SAMPL4 indicate that SEA is an accurate, general and fast new approach to computing solvation free energies. 相似文献