Sur la stabilité thermique des étalons analytiques. XI

Résumé Nous avons étudié par thermogravimétrie et par spectrophotométrie infrarouge, entre 6 et 15, douze substances nouvelles proposées pour étalons en chimie analytique. Le chlorure de magnésium et d'ammonium, l'hydrogénocarbonate d'ammonium et le fluorure d'ammonium paraissent d'emploi douteux pour préparer avec certitude une liqueur titrée.

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Summary Twelve new substances suggested as standards in analytical chemistry have been investigated by thermogravimetry and infrared spectrography, between 6 and 15. Magnesium ammonium chloride, ammonium bicarbonate and ammonium fluoride seem to be of doubtful value for the accurate preparation of a standard solution.

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Zusammenfassung Zwölf zur Herstellung von Urtiterlösungen neu vorgeschlagene Substanzen wurden thermogravimetrisch und infrarotspektrophotometrisch zwischen 6 und 15 geprüft. Magnesium-Ammoniumchlorid, Ammoniumhydrogencarbonat und Ammoniumfluorid scheinen für diesen Zweck von zweifelhaftem Wert zu sein.

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Pour le dixième mémoire de cette série, voir Mikrochim. Acta [Wien]1962, 268.     

1H, 13C and 15N NMR spectral analysis of substituted 1,2,3,4‐tetrahydro‐pyrido[1,2‐a]pyrimidines

The NMR spectroscopic data of a series of thirty‐four 3‐acylpyrido[1,2‐a]pyrimidinium salts are analyzed, which were prepared as either perchlorates or chlorides. Methyl group substituted 3‐aroyltetrahydropyrido[1,2‐a]pyrimidines with the methyl substituent in positions 6, 8 and 9 as well as both in positions 6 and 8 were investigated bearing various aroyl substituents. Unequivocal assignment of all resonances was achieved via two‐dimensional ¹H,¹H‐COSY measurements, ¹H,¹³C and ¹H,¹⁵N HSQC as well as HMBC experiments, and important diagnostic CH and NH couplings in the heteroaromatic ring system are evaluated. The influence of the methyl substituents was analyzed on the proton, carbon and nitrogen shifts. A significant effect of the counter ion on some chemical shifts of the nuclei under discussion of the pyridopyrimidines is found, allowing the indirect detection of the anion, which is confirmed by direct measurement of the ³⁵Cl nucleus of the perchlorates. Copyright © 2013 John Wiley & Sons, Ltd.     

Genetics of Vocal Quality Characteristics in Monozygotic Twins: A Multiparameter Approach

The main purpose of this study was to determine the vocal quality characteristics among the 45 monozygotic cotwins (MT). As the performance of the voice is related to several genetically determined anatomical and physiological factors, the authors hypothesized that the vocal characteristics and the overall vocal quality by means of the Dysphonia Severity Index (DSI) will be identical in MT. An additional objective of this study was to determine whether sex and age influence vocal similarities in MT and to compare the voice characteristics of MT with the normative data of unrelated peers. As more environmental factors influence the aging of the voice, age-related differences were expected. No sex-related differences were expected. Subjective and objective assessment techniques determined the vocal quality. No significant differences were obtained, and most comparisons resulted in significant correlation coefficients. For the acoustic parameters jitter and shimmer only, no significant correlation coefficients could be obtained. It is clear that the perceptual voice characteristics, the laryngeal aerodynamic measurements of maximum phonation time (MPT), the vocal performances, and the overall vocal quality by means of the DSI are similar in MT. These vocal characteristics are not influenced either by the subjects' age or sex and are situated within the normative range of unrelated peers. To what extent other aspects (environment, anxiety, tension, etc) might play a role in the acoustical dimensions regarding frequency and amplitude perturbation, which were in the normal range, is a subject of further research.     

Experimental study of the hydrodynamic behaviour of a high frequency ultrasonic reactor

In relation to design and modeling of sonochemical reactors, the hydrodynamic behaviour of a high-frequency ultrasonic reactor has been investigated. Residence time distribution (RTD) measurements have been performed by means of a tracer method. The influence of ultrasound on the response to an inlet pulse was evidenced. It was shown that the reactor behaves like a completely stirred tank reactor (CSTR) as soon as ultrasonic irradiation operates. Preliminary observations on acoustic streaming occurring within the reactor will also be presented.     

Search for a bound trineutron with the 3He(π−pgr;+)nnn reaction

A search for the production of a bound trineutron state has been performed using the reaction ³He(π⁻,π⁺)nnn at incident pion energies of 65, 75, and 120 MeV. No evidence for the existence of the ³n was found, and an upper limit for the production cross section of approximately 30 nb/sr (2σ confidence level) was obtained. Received: 22 October 1998     

Erratum to: Upgrade of the ATLAS Hadronic Tile Calorimeter for the High Luminosity LHC

Physics of Atomic Nuclei - An Erratum to this paper has been published: https://doi.org/10.1134/S1063778822010082     

Enhanced ultrasound transmission through the human skull using shear mode conversion

A new transskull propagation technique, which deliberately induces a shear mode in the skull bone, is investigated. Incident waves beyond Snell's critical angle experience a mode conversion from an incident longitudinal wave into a shear wave in the bone layers and then back to a longitudinal wave in the brain. The skull's shear speed provides a better impedance match, less refraction, and less phase alteration than its longitudinal counterpart. Therefore, the idea of utilizing a shear wave for focusing ultrasound in the brain is examined. Demonstrations of the phenomena, and numerical predictions are first studied with plastic phantoms and then using an ex vivo human skull. It is shown that at a frequency of 0.74 MHz the transskull shear method produces an amplitude on the order of--and sometimes higher than--longitudinal propagation. Furthermore, since the shear wave experiences a reduced overall phase shift, this indicates that it is plausible for an existing noninvasive transskull focusing method [Clement, Phys. Med. Biol. 47(8), 1219-1236 (2002)] to be simplified and extended to a larger region in the brain.     

Non-skew symmetric orthogonal matrices with constant diagonals

A matrix C of order n is orthogonal if CC^T=dI. In this paper, we restrict the study to orthogonal matrices with a constant m > 1 on the diagonal and ±1's off the diagonal. It is observed that all skew symmetric orthogonal matrices of this type are constructed from skew symmetric Hadamard matrices and vice versa. Some simple necessary conditions for the existence of non-skew orthogonal matrices are derived. Two basic construction techniques for non-skew orthogonal matrices are given. Several families of non-skew orthogonal matrices are constructed by applying the basic techniques to well-known combinatorial objects like balanced incomplete block designs. It is also shown that if m is even and n=0 (mod 4), then an orthogonal matrix must be skew symmetric. The structure of a non-skew orthogonal matrix in the special case of m odd,n=2 (mod 4) and m?1/6n is also studied in detail. Finally, a list of cases with n?50 is given where the existence of non-skew orthogonal matrices are unknown.