全文获取类型
收费全文 | 245325篇 |
免费 | 5987篇 |
国内免费 | 3411篇 |
专业分类
化学 | 129288篇 |
晶体学 | 4121篇 |
力学 | 11411篇 |
综合类 | 250篇 |
数学 | 26467篇 |
物理学 | 83186篇 |
出版年
2022年 | 2156篇 |
2021年 | 2511篇 |
2020年 | 2747篇 |
2019年 | 2816篇 |
2018年 | 3205篇 |
2017年 | 3188篇 |
2016年 | 5002篇 |
2015年 | 3465篇 |
2014年 | 5218篇 |
2013年 | 11475篇 |
2012年 | 9668篇 |
2011年 | 11377篇 |
2010年 | 8153篇 |
2009年 | 8128篇 |
2008年 | 10264篇 |
2007年 | 9878篇 |
2006年 | 9350篇 |
2005年 | 8287篇 |
2004年 | 7512篇 |
2003年 | 6750篇 |
2002年 | 6418篇 |
2001年 | 8232篇 |
2000年 | 6230篇 |
1999年 | 4897篇 |
1998年 | 3899篇 |
1997年 | 3711篇 |
1996年 | 3426篇 |
1995年 | 3191篇 |
1994年 | 3061篇 |
1993年 | 2877篇 |
1992年 | 3418篇 |
1991年 | 3318篇 |
1990年 | 3191篇 |
1989年 | 2960篇 |
1988年 | 2904篇 |
1987年 | 2934篇 |
1986年 | 2730篇 |
1985年 | 3506篇 |
1984年 | 3487篇 |
1983年 | 2945篇 |
1982年 | 3009篇 |
1981年 | 2805篇 |
1980年 | 2748篇 |
1979年 | 3005篇 |
1978年 | 3058篇 |
1977年 | 3005篇 |
1976年 | 2961篇 |
1975年 | 2801篇 |
1974年 | 2814篇 |
1973年 | 2925篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Gang Wang Xiulin Zhu Zhenping Cheng Jian Zhu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2912-2921
A series of (di)picolinic acids and their derivates are investigated as novel complexing tridentate or bidentate ligands in the iron‐mediated reverse atom transfer radical polymerization of methyl methacrylate in N,N‐dimethylformamide at 100 °C with 2,2′‐azobisisobutyrontrile as an initiator. The polymerization rates and polydispersity indices (1.32–1.8) of the resulting polymers are dependent on the structures of the ligands employed. Different iron complexes may be involved in iron‐mediated reverse atom transfer radical polymerization, depending on the type of acid used. 1H NMR spectroscopy has been used to study the structure of the resulting polymers. Chain‐extension reactions have been performed to further confirm the living nature of this catalytic system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2912–2921, 2006 相似文献
2.
In this work, the natural convection in a concentric annulus between a cold outer square cylinder and a heated inner circular cylinder is simulated using the differential quadrature (DQ) method. The vorticity‐stream function formulation is used as the governing equation, and the coordinate transformation technique is introduced in the DQ computation. It is shown in this paper that the outer square boundary can be approximated by a super elliptic function. As a result, the coordinate transformation from the physical domain to the computational domain is set up by an analytical expression, and all the geometrical parameters can be computed exactly. Numerical results for Rayleigh numbers range from 104 to 106 and aspect ratios between 1.67 and 5.0 are presented, which are in a good agreement with available data in the literature. It is found that both the aspect ratio and the Rayleigh number are critical to the patterns of flow and thermal fields. The present study suggests that a critical aspect ratio may exist at high Rayleigh number to distinguish the flow and thermal patterns. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
3.
LYNDA D. RODWELL EDWARD B. BARBIER CALLUM M. ROBERTS TIM R. McCLANAHAN 《Natural Resource Modeling》2002,15(4):453-486
ABSTRACT. The excessive and unsustainable exploitation of our marine resources has led to the promotion of marine reserves as a fisheries management tool. Marine reserves, areas in which fishing is restricted or prohibited, can offer opportunities for the recovery of exploited stock and fishery enhancement. In this paper we examine the contribution of fully protected tropical marine reserves to fishery enhancement by modeling marine reserve‐fishery linkages. The consequences of reserve establishment on the long‐run equilibrium fish biomass and fishery catch levels are evaluated. In contrast to earlier models this study highlights the roles of both adult (and juvenile) fish migration and larval dispersal between the reserve and fishing grounds by employing a spawner‐recruit model. Uniform larval dispersal, uniform larval retention and complete larval retention combined with zero, moderate and high fish migration scenarios are analyzed in turn. The numerical simulations are based on Mombasa Marine National Park, Kenya, a fully protected coral reef marine reserve comprising approximately 30% of former fishing grounds. Simulation results suggest that the establishment of a fully protected marine reserve will always lead to an increase in total fish biomass. If the fishery is moderately to heavily exploited, total fishery catch will be greater with the reserve in all scenarios of fish and larval movement. If the fishery faces low levels of exploitation, catches can be optimized without a reserve but with controlled fishing effort. With high fish migration from the reserve, catches are optimized with the reserve. The optimal area of the marine reserve depends on the exploitation rate in the neighboring fishing grounds. For example, if exploitation is maintained at 40%, the ‘optimal’ reserve size would be 10%. If the rate increases to 50%, then the reserve needs to be 30% of the management area in order to maximize catches. However, even in lower exploitation fisheries (below 40%), a small reserve (up to 20%) provides significantly higher gains in fish biomass than losses in catch. Marine reserves are a valuable fisheries management tool. To achieve maximum fishery benefits they should be complemented by fishing effort controls. 相似文献
4.
P. R. Latthe P. S. Shinge Bharati V. Badami P. B. Patil S. N. Holihosur 《Journal of Chemical Sciences》2006,118(3):249-256
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been
found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e). 相似文献
5.
X Y Liu C J Li 《Science in China. Series B, Chemistry, life sciences & earth sciences》1989,32(10):1215-1223
To further evaluate the causality between endogenous pyrogen (EP)-induced fever and cyclic adenosine-3',5'-monophosphate (cyclic AMP) level, the effects of sodium salicylate (SS) on the febrile response and increased levels of cyclic AMP in both cerebrospinal fluid (c.s.f.) and plasma during EP-induced fever in rabbits were observed. The results suggest that cyclic AMP is probably involved in the central mediation of EP-induced fever and that increased concentration of cyclic AMP in c.s.f. associated with EP-induced fever is not the result of temperature elevation but appears to be caused by the increased synthesis in the central nervous system. In addition it is confirmed that blood is impossibly a contributory source of increased cyclic AMP in c.s.f. during EP fever, and that SS may act subsequent to the increase in cyclic AMP. 相似文献
6.
We show that, in dimensions equal or greater than three, classical strings do not join or split. This is part of a no-interaction theorem that is also proved. The quantum theory is considered. 相似文献
7.
D. N. Karimov E. A. Krivandina Z. I. Zhmurova B. P. Sobolev V. A. Bezhanov S. P. Chernov G. M. Shapochkin 《Crystallography Reports》2006,51(6):1009-1015
Crystalline materials that are transparent in the vacuum UV spectral region and currently used have been reviewed. Transmission of crystals of solid solutions with the fluorite structure Ca1?x R xF2+x (R = Sc, Y, La, Yb, Lu) in the UV and vacuum UV spectral regions has been investigated. It is shown that application of different methods of purification of fluorides from some impurities can significantly improve the optical quality of fluoride multicomponent crystals in the short-wavelength spectral region. 相似文献
8.
Xuding Zhu 《Journal of Graph Theory》2005,48(3):186-209
For 1 ≤ d ≤ k, let Kk/d be the graph with vertices 0, 1, …, k ? 1, in which i ~j if d ≤ |i ? j| ≤ k ? d. The circular chromatic number χc(G) of a graph G is the minimum of those k/d for which G admits a homomorphism to Kk/d. The circular clique number ωc(G) of G is the maximum of those k/d for which Kk/d admits a homomorphism to G. A graph G is circular perfect if for every induced subgraph H of G, we have χc(H) = ωc(H). In this paper, we prove that if G is circular perfect then for every vertex x of G, NG[x] is a perfect graph. Conversely, we prove that if for every vertex x of G, NG[x] is a perfect graph and G ? N[x] is a bipartite graph with no induced P5 (the path with five vertices), then G is a circular perfect graph. In a companion paper, we apply the main result of this paper to prove an analog of Haj?os theorem for circular chromatic number for k/d ≥ 3. Namely, we shall design a few graph operations and prove that for any k/d ≥ 3, starting from the graph Kk/d, one can construct all graphs of circular chromatic number at least k/d by repeatedly applying these graph operations. © 2005 Wiley Periodicals, Inc. J Graph Theory 48: 186–209, 2005 相似文献
9.
A one-dimensional bulk reaction model for the oxidation of nickeltitanium is formulated, with preferential oxidation of titaniumbeing included. The modelling is directed at the better understandingof the dominant mechanisms involved in the oxidation processand their significance for the biocompatibility of the alloy.Two different regimes for the relative diffusivities of oxygenand the metals are investigated. By assuming fast bulk reactions,different asymptotic structures emerge in different parameterregimes and the resulting models take the form of moving boundaryproblems. Different profiles of nickel concentration are obtained:in particular a nickel-rich layer (observed in practice) ispresent below the oxide/metal interface for the case when oxygenand the metals diffuse at comparable rates. 相似文献
10.
D. Amutha Rani Y. Yamamoto S. Mohri M. Sivakumar Y. Tsujita H. Yoshimizu 《Journal of Polymer Science.Polymer Physics》2003,41(3):269-273
In this study, a novel stepwise extraction method has been examined. The guest molecules housed between the helices of the clathrate δ form of syndiotactic polystyrene can be removed completely with this method. A systematic study of the preparation of a solvent‐free mesophase (emptied clathrate) membrane, its helical and residual solvent contents, and its structural transformations has been performed. In this first attempt, an enhancement in the TTGG helical content has been observed in the extracted membrane, and a conceptual mechanism is proposed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 269–273, 2003 相似文献