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以聚乙二醇丙烯酸酯(PEGMEA)为起始原料, 将原子转移自由基聚合(ATRP)技术和从主干接枝(grafting-from)策略相结合, 合成了结构规整的聚甲基醚聚乙二醇丙烯酸酯-g-聚(N,N’-二乙基胺乙基甲基丙烯酸酯) (PPEGMEA-g- PDEAEMA)接枝共聚物. 这种接枝共聚物通过静电作用形成胶束包埋甲氨喋呤(MTX), 得到具有98.7%高包封率的药物载体, 体外药物释放得到很好的控制. 相似文献
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Hard coatings have been widely applied to enhance tribological performance of mechanical components.However,it was predicted that thin hard coatings may have a weakening effect which could reduce the coating/substrate system’s resistance to plastic yielding compared with the uncoated substrate material.In this paper,analytical simulation is utilized to investigate the origin of weakening effect.The functions of material mechanical properties and coating thickness on the weakening effect are theoretically investigated.Partial-unloading spherical nanoindentation tests are performed on tungsten coated single crystalline silicon and copper to acquire the stress-strain curves and compared with the uncoated cases.The experimental results are in consistence with the analytical solutions,demonstrating the presence of weakening effect. 相似文献
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