自掺杂磺酸化聚苯胺之最优化实验设计(英文)

应用实验设计法包括部分析因设计与中心组合设计,优化自掺杂磺酸化聚苯胺的导电性.部分析因设计发现,需用低温(4℃)、短反应时间(1 h)和少量发烟硫酸(10 mL)等实验条件进行磺酸化反应才能得到好的导电性(ca.127 mS.cm-1);中心组合设计与确认实验表明,其最佳导电性(ca.141 mS/cm)的磺酸化条件是4℃、75 m in反应时间以及8 mL 30%的发烟硫酸.应用傅立叶变换红外光谱(FTIR)、四探针与X光光电子能谱等分析制备的材料.此外,发现磺酸化速率与程度与聚合反应时所使用的酸有关.     

Effect of Kinetic Alfvén Waves on Electron Transport in an Ion-Scale Flux Rope

At the Earth's magnetopause, the electron transport due to kinetic Alfvén waves(KAWs) is investigated in an ion-scale flux rope by the Magnetospheric Multiscale mission. Clear electron dropout around 90° pitch angle is observed throughout the flux rope, where intense KAWs are identified. The KAWs can effectively trap electrons by the wave parallel electric field and the magnetic mirror force, allowing electrons to undergo Landau resonance and be transported into more field-aligned directions. The pitch angle range for the trapped electrons is estimated from the wave analysis, which is in good agreement with direct pitch angle measurements of the electron distributions. The newly formed beam-like electron distribution is unstable and excites whistler waves,as revealed in the observations. We suggest that KAWs could be responsible for the plasma depletion inside a flux rope by this transport process, and thus be responsible for the formation of a typical flux rope.     

粒子入射角度对冷喷涂涂层形成的影响

采用有限元数值计算方法，研究冷喷涂材料改性过程中铜粒子与铜基体非垂直碰撞的变形行为。针对单个粒子相同入射速度不同入射角度的碰撞条件，探讨粒子与基体的结合强度、侵彻深度以及绝热剪切失稳的发生条件。结果表明:随着粒子入射角度的增大，侵彻深度逐渐减少，粒子与基体的结合强度逐渐减弱。发生绝热剪切失稳的条件是入射速度的法向分量大于碰撞过程的临界速度。