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N—对甲苯磺酰基—α—氨基膦酸及其单酯的合成及活性研究 总被引:3,自引:1,他引:3
用^31P NMR谱跟踪反应的方法,研究了对甲苯磺酰胺与取代苯甲醛及三氯化磷(或烷氧基二氯化磷)在乙酰氯为溶剂的条件下的类Mannich反应的机理,找到了合成标题化合物的简单方法。初步生物活性测试表明其中某些化合物具有较好的抗烟草花叶病毒活性。 相似文献
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Monitoring the chemical and structural changes in protein side chains and endpoints by infrared(IR)spectroscopy is important for studying the chemical reaction and physical adsorption process of proteins.However, the detection of side chains and endpoints in nanoscale proteins is still challenging due to its weak IR response. Here, by designing a double layered graphene plasmon sensor on MgF_2/Si substrate in the IR fingerprint region, we detect the vibrational modes in side chains and endpoints(1397 cm~(-1) and 1458 cm~(-1)) of monolayer protein. The sensor could be applied on biochemistry to investigate the physical and chemical reaction of biomolecules. 相似文献
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Graphene plasmons have become promising candidates for deep-subwavelength nanoscale optical devices due to their strong field confinement and low damping. Among these nanoscale optical devices, band-pass filter for wavelength selection and noise filtering are key devices in an integrated optical circuit. However, plasmonic filters are still oversized because large resonant cavities are needed to perform frequency selection. Here, an ultra-compact filter integrated in a graphene plasmonic waveguide was designed, where a rectangular resonant cavity is inside a graphene nanoribbon waveguide. The properties of the filter were studied using the finite-difference time-domain method and demonstrated using the analytical model. The results demonstrate the band-pass filter has a high quality factor(20.36) and electrically tunable frequency response. The working frequency of the filter could also be tuned by modifying the cavity size. Our work provides a feasible structure for a graphene plasmonic nano-filter for future use in integrated optical circuits. 相似文献
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Five chiral stationary phases (CSPs) were used to separate the enantiomers of a series of O,O-diethyl (p-methyl-benzenesulfonamindo)- aryl(alkyl)-methylphosphonates. A chiral recognition mechanism was presented to explain the resolution of these compounds. Results show that CSP with strong π-acceptor 3,5-dinitrobenzoyl group and high steric hindrance has the best resolution ability in chiral separation of O,O-diethyi (p-methyl-benzenesulfonamindo)- aryl(alkyl)-methylphosphonates. When a CSP has just a strong π-acceptor 3,5-dinitrobenzoyl or high steric hindrance it does not have good chiral resolution ability. The chiral recognition is more difficult when the CSP has more than one asymmetric center. 相似文献
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报道了N-苯磺酰基磷酰二胺酯类化合物的合成。用电生理细胞内微电极技术研究了这些化合物的结构对昆虫谷氨酸电位阻断作用的影响。结果表明:它们均能阻断果蝇幼虫神经肌肉兴奋性接点电位,但其阻断时间相差很大。阻断过程可分为3种:(1)电位逐渐被阻断;(2)电位开始有短暂的兴奋,然后被阻断;(3)电位迅速被阻断。活体实验表明:具有第2种杀虫机制的化合物杀虫效果最好。 相似文献
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原子是物质世界中最基本的构成单元。原子制造通过精确操纵原子及功能基元来从最底层创造全新的物质、材料和器件,并构建具有革命性能的装备和系统。原子制造既是先进制造技术的极致化,也是量子理论的试验场,还是物质科学的未来技术,甚至未来态。文章以团簇束流、扫描隧道显微镜、原子级多层异质结以及其他单原子体系为例,介绍原子精准操控技术及其放大和集成,并探讨了原子制造在物质科学中的发展意义和未来前景。
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