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We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV_2O_4.The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed at 50 K and 37 K,respectively.By analysis of the hysteresis behavior between the specific heat curves obtained in warming and cooling processes,the structural transition was confirmed to be the first-order transition,while the antiferromagnetic transition was found to be of the second-order type.At the structural transition,the latent heat and entropy change were calculated from the excess specific heat,and the derivative of pressure with respect to temperature was obtained using the Clausius-Clapayron equation.At the magnetic transition,the width of the critical fluctuation region was obtained to be about 0.5 K by comparing with Gaussian fluctuations.In the critical region,the critical behavior was analyzed by using renormalization-group theory.The critical amplitude ratio A~+/A~- = 1.46,which deviates from the 3D Heisenburg model;while the critical exponent α is-0.011,which is close to the 3D XY model.We proposed that these abnormal critical behaviors can be attributed to strong spin-orbital coupling accompanied with the antiferromagnetic transition.Moreover,in the low temperature range(2-5 K),the Fermi energy,the density of states near the Fermi surface,and the low limit of Debye temperature were estimated to be2.42 eV,2.48 eV~(-1),and 240 K,respectively. 相似文献
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用变温X射线及热分析等方法研究Bi_4Ti_3O_12铁电薄膜的相变,结果表明,在温度为350~445℃之间,薄膜经历由烧绿石相向钙钛矿相的结构相变,在670℃附近,薄膜由铁电相向顺电相转变;该相变是由于晶格畸变量b/a随温度上升连续减小,使得薄膜晶体对称性发生改变引起,在相变点附近未观察到潜热的产生。 相似文献
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报道了金属与金属氧化物复合靶的射频溅射法,制备Bi4Ti3O(12)(BTO)铁电陶瓷薄膜的方法,研究BTO薄膜的晶体结构,表面形貌以及断面.实验表明采用复合靶能够制备质量好、成分均匀的BTO薄膜,其结晶取向与基片材料有关,且退火工艺对膜的质量有影响. 相似文献
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