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Determination of iodide in drinking water by isotope dilution analysis

The most suitable way of determination iodine-deficiency is to measure iodine concentrations in water and urine. For this reason, a method that can determine iodide concentrations in drinking water and suitable for routine analysis, is developed. Water samples have been collected from four Aegean localities: Izmir, Salihli, Ödemis and Tire situated in the western Turkey. The method is based on substochiometric isotope dilution analysis. Iodile concentrations vary within 9.86–85.14 μg/l ranges in the analyzed samples. Mean value is 44.92±22.07 μg/l.     

Vibrational Spectroscopic Studies on the Hofmann-dabn-Type Benzene Clathrates: M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Mn, Fe, Co, Ni or Cd)

IR spectra of M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Mn, Fe, or Co), and IR and Raman spectra of M(1,4-diaminobutane)Ni(CN)4° 1.5C6H6 (M = Ni or Cd) clathrates are reported. The spectral features suggest that the compounds are similar in structure to the Hofmann-dabn-type clathrates.     

Immobilization of Mercuric reductase from aPseudomonas putida strain on different activated carriers

Mercuric reductase was isolated fromPseudomonas putida KT2442::mer-73 and immobilized on Chromatographic carriers activated by various methods. The immobilization methods for covalent coupling were compared with regard to preservation of enzymatic activity and coupling yields. Highest yields were obtained with carriers bearing the most reactive functional groups. Best results were achieved with tresyl chloride-activated carriers. The optimum binding conditions were found at pH 8. Application of the immobilized mercuric reductase for continuous treatment of Hg(II)-containing water was examined in a fixed bed reactor. Space-time yields up to 510 nmol/min-mL were attained. The kinetics of immobilized enzyme systems were not diffusion-controlled.     

基于Teager能量算子（TEO）基频的应力影响下的变异语音分类

变异语音识别是一项极具挑战意义的研究课题,一种解决方法是在前端对语音进行变异分类,然后根据不同变异情况采用相关的处理算法。在各种语音变异中,说话人在战斗机、航天飞机座舱等环境中,身体受到应力(重力)影响时的情况更具有特殊性。其所引起的发音变异有别于因心理的、感知的或生理的因素所引起的变异,目前国内外还鲜见有关应力影响不变异语音分类问题的专门研究。木文从对应力影响下的几种基于基频的语音特征的分析出发,提出了对应力影响下的变异语音和正常语音进行分类的方法。对航空模拟飞行器中采集的小词表实验样本,特定人平均分类正确率达到了93.3%,多说话人分类上确率达到了85.8%。     

语言长时平均频谱与发话声级和发话速度的关系

在五种发话声级和两种发话速度下测量了试验句“他去无锡市,我到黑龙江”的长时平均频谱。五种发话总声级是:55分贝、60分贝、65分贝、70分贝、75分贝;两种发话速度是:正常速度和尽量加快速度,速度变化1.5倍,发音人共12人,男、女各6人。
试验结果表明:(1)发话总声级对平均频谱有明显的影响,随着总声级的提高,一方面语音的平均基频也提高,另一方面语音的高次共振峰也得到加强。(2)发话速度的变化对长时平均频谱几乎没有影响。     

The lowest electronic states of Ne2 +, Ar2 + and Kr2 +: comparison of theory and experiment

Non-relativistic configuration interaction (CI) ab initio calculations using large basis sets have been carried out to determine the potential curves of the first electronic states of Ne₂ ⁺, Ar₂ ⁺ and Kr₂ ⁺. The spin—orbit interaction was treated assuming that the spin—orbit coupling constant is independent of the internuclear separation (R). For Ar₂ ⁺, calculated dissociation energies and equilibrium separations are in good agreement with experimental results. The calculations for Ne₂ ⁺ suggest that the lowest vibrational level of the I(1/2u) ground state observed by threshold photoelectron spectroscopy by Hall et al. [1995, J. Phys. B: At. molec. opt. Phys., 28, 2435] and assigned to either ν = 0 or ν = 2 actually corresponds to ν = 4. The calculations also predict the I(1/2g) state of Ne₂ ⁺ and Ar₂ ⁺ to possess a double-well potential and that of Kr₂ ⁺ to be repulsive at short range and to only possess a single shallow well at large internuclear separation. The ab initio calculations provide an explanation for the observation made by Yoshii et al. [2002, J. chem. Phys., 117, 1517] that Kr₂ ⁺ and Xe₂ ⁺ dissociate after photoemission from the II(1/2u) state to the I(1/2g) state whereas Ar₂ ⁺ does not.     

The measurement of the magnetic susceptibility of some elements (Fe,Co, Ni,Ge, Sn,Te) in the liquid state

A magnetic balance was used for measuring the susceptibility of metals and alloys, in an atmosphere of purified argon, up to 1800°c.

Comparison of the susceptibilities of liquid Fe, Co and Ni gives information on the liquid state. The changes in the susceptibilities of Ge, Sn and Te on melting are typical of semi-metallic elements and semiconductors, but their behaviour differs according to the degree of symmetry in the solid state.     

湍流边界层激励下腔体内水动力自噪声预报与测量

循环水槽中试验测量了腔体内水动力自噪声,并与模态法建立的湍流脉动压力引起腔体自噪声预报进行比较验证。透声窗振动以简支边界为条件,腔体内部声波以刚性边界为条件模态展开,通过辐射边界条件建立模态耦合振动方程。在随机湍流脉动压力作用下,推导了模态振动方程在随机力激励下的自噪声功率谱响应。对循环水槽中5 m/s和8 m/s两种流速工况下的腔体水动力自噪声和湍流脉动压力进行了测试,结合测量的脉动压力预报方法可以计算腔体水动力自噪声量值,理论预报与试验测量结果大致吻合,趋势一致,为声呐罩材料选取及声学环境控制提供了一种分析方法。     

光纤水听器解调技术研究进展

光纤水听器是水声研究领域的关键技术,在实际应用中具有显著优势,广泛应用于AUV导航定位、资源勘探、海水警戒等场景.光纤水听器将声信号转化为光信号传播,在接收信号时就需要对光信号进行解调提取出声压信号.总结了几种常用的信号解调算法及关键技术,包括PGC解调法、3×3耦合器解调法和外差解调法;介绍了各种解调算法的基本原理和...