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排序方式: 共有59条查询结果,搜索用时 15 毫秒
1.
Serber Z Straub W Corsini L Nomura AM Shimba N Craik CS Ortiz de Montellano P Dötsch V 《Journal of the American Chemical Society》2004,126(22):7119-7125
Studying protein components of large intracellular complexes by in-cell NMR has so far been impossible because the backbone resonances are unobservable due to their slow tumbling rates. We describe a methodology that overcomes this difficulty through selective labeling of methyl groups, which possess more favorable relaxation behavior. Comparison of different in-cell labeling schemes with three different proteins, calmodulin, NmerA, and FKBP, shows that selective labeling with [(13)C]methyl groups on methionine and alanine provides excellent sensitivity with low background levels at very low costs. 相似文献
2.
Kevin W. Gao Xi Jiang Zach J. Hoffman Gurmukh K. Sethi Saheli Chakraborty Irune Villaluenga Nitash P. Balsara 《Journal of polymer science. Part A, Polymer chemistry》2020,58(2):363-371
Poly(ethylene oxide)-b-polyhedral oligomeric silsesquioxane (PEO–POSS) mixed with lithium bis(trifluoromethanesulfonyl)imide salt is a nanostructured hybrid organic–inorganic block copolymer electrolyte that may enable lithium metal batteries. The synthesis and characteristics of three PEO–POSS block copolymer electrolytes which only differ by their POSS silica cage substituents (ethyl, isobutyl, and isooctyl) is reported. Changing the POSS monomer structure results in differences in both thermodynamics and ion transport. All three neat polymers exhibit lamellar morphologies. Adding salt results in the formation of a disordered window which closes and gives way to lamellae at higher salt concentrations. The width of disordered window decreases with increasing length of the POSS alkyl chain substituent from ethyl to isobutyl and is absent in the isooctyl sample. Rheological measurements demonstrate good mechanical rigidity when compared with similar all-organic block copolymers. While salt diffusion coefficient and current ratio are unaffected by substituent length, ionic conductivity increases as the length of the alkyl chain substituent decreases: the ethyl substituent is optimal for ion transport. This is surprising because conventional wisdom suggests that ion transport occurs primarily in the PEO-rich domains, that is, ion transport should be unaffected by substituent length after accounting for the minor change in conducting phase volume fraction. © 2020 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2020 © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 363–371 相似文献
3.
Nichole Cates Miller Roman Gysel Chad E. Miller Eric Verploegen Zach Beiley Martin Heeney Iain McCulloch Zhenan Bao Michael F. Toney Michael D. McGehee 《Journal of Polymer Science.Polymer Physics》2011,49(7):499-503
Polymer:fullerene blends have been widely studied as an inexpensive alternative to traditional silicon solar cells. Some polymer:fullerene blends, such as blends of poly(2,5‐bis(3‐tetradecylthiophen‐2‐yl)thieno[3,2‐b]thiophene (pBTTT) with phenyl‐c71‐butyric acid methyl ester (PC71BM), form bimolecular crystals due to fullerene intercalation between the polymer side chains. Here we present the determination of the eutectic pBTTT:PC71BM phase diagram using differential scanning calorimetry (DSC) and two‐dimensional grazing incidence X‐ray scattering (2D GIXS) with in‐situ thermal annealing. The phase diagram explains why the most efficient pBTTT:PC71BM solar cells have 75–80 wt % PC71BM since these blends lie in the center of the only room‐temperature phase region containing both electron‐conducting (PC71BM) and hole‐conducting (bimolecular crystal) phases. We show that intercalation can be suppressed in 50:50 pBTTT:PC71BM blends by using rapid thermal annealing to heat the blends above the eutectic temperature, which forces PC71BM out of the bimolecular crystal, followed by quick cooling to kinetically trap the pure PC71BM phase. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
4.
5.
An automatic aberration correction method has been implemented in scanning electron microscopes (SEM). Necessity of the automatic aberration correction is discussed. The procedure of the automatic aberration correction is explained in detail, where deconvolution techniques are used in order to extract probe information from SEM images. Due to the precise digitization and the usage of proper combinations of correction fields, linearity has been found between the amplitude of each aberration and the corresponding field strength. Experimental results are shown which demonstrate that the aberrations are corrected automatically by a linear feedback control method. After the automatic aberration correction, the image quality has been improved drastically. 相似文献
6.
Zach Teitler 《Proceedings of the American Mathematical Society》2008,136(5):1575-1579
In 2006, M. Mustaţă used jet schemes to compute the multiplier ideals of reduced hyperplane arrangements. We give a simpler proof using a log resolution and generalize to non-reduced arrangements. By applying the idea of wonderful models introduced by De Concini-Procesi in 1995, we also simplify the result. Indeed, Mustaţă's result expresses the multiplier ideal as an intersection, and our result uses (generally) fewer terms in the intersection.
7.
Polarization distributions of ground state neutrons emitted from the14C(d,n 0)15N reaction were investigated over the angular range from 15 ° (lab) to 150 ° (lab) at bombarding energies of 1.28, 1.55 and 1.88 MeV. Scattering of neutrons from helium served as polarization analyzer. The experimental results show a large variation with energy of the polarization ranging betweenP(Θlab=130 °)=?21% andP(Θlab=130 °)=+50% at 1.28 and 1.88 MeV respectively. 相似文献
8.
9.
M. Faber A.N. Ivanov A. Müller N.I. Trotskaya M. Zach 《The European Physical Journal C - Particles and Fields》1999,7(4):685-695
The magnetic monopole condensate is calculated in the dual Monopole Nambu–Jona–Lasinio model with dual Dirac strings suggested
in [1,2] as a functional of the dual Dirac string shape. The calculation is carried out in the tree approximation in the scalar
monopole–antimonopole collective excitation field. The integration over quantum fluctuations of the dual–vector monopole–antimonopole
collective excitation field around the Abrikosov flux line and string shape fluctuations are performed explicitly. We claim
that there are important contributions of quantum and string shape fluctuations to the magnetic monopole condensate.
Received: 3 June 1998 / Revised version: 1 September 1998 / Published online: 19 November 1998 相似文献
10.
Michael Dion Greg Eiden Orville Farmer Zach Finch Martin Liezers 《Journal of mass spectrometry : JMS》2016,51(8):591-595
A technique that uses the intrinsic mass‐based separation capability of a quadrupole mass spectrometer has been used to resolve spectral radiometric interference of two isotopes of the same element. In this work the starting sample was a mixture of 137Cs and 134Cs and was (activity) dominated by 137Cs. This methodology separated and ‘implanted’ 134Cs that was later quantified for spectral features and activity with traditional radiometric techniques. This work demonstrated a 134Cs/137Cs activity ratio enhancement of >4 orders of magnitude and complete removal of 137Cs spectral features from the implanted target mass (i.e. 134). Copyright © 2016 John Wiley & Sons, Ltd. 相似文献