Bounds on the maximum numbers of clear two-factor interactions for 2^{(n_1 + n_2 ) - (k_1 + k_2 )} fractional factorial split-plot designs

Fractional factorial split-plot (FFSP) designs have an important value of investigation for their special structures. There are two types of factors in an FFSP design: the whole-plot (WP) factors and sub-plot (SP) factors, which can form three types of two-factor interactions: WP2fi, WS2fi and SP2fi. This paper considers FFSP designs with resolution III or IV under the clear effects criterion. It derives the upper and lower bounds on the maximum numbers of clear WP2fis and WS2fis for FFSP designs, and gives some methods for constructing the desired FFSP designs. It further examines the performance of the construction methods.     

GRIN透镜在细径内窥镜中的应用

介绍在细径内窥镜中ＧＲＩＮ透镜的应用原理及其设计方法。     

基于小波包分析及支持向量机的超音速目标识别方法研究

提出了基于小波包分析及支持向量机的超音速目标识别方法 .通过 5 .5 6mm ,7.6 2mm和 12 .7mm三种枪弹试验获取信号 ,用小波包分解激波信号 ,统计每个频带的能量特征 ,用支持向量机方法训练测试样本 ,获得了很好的分类效果 .仿真结果表明基于超音速飞行体产生的激波信号来识别目标是可行的 .     

甲亢病人血清镁含量及其临床意义

用火焰原子吸收法测定了２０００例甲亢病人的血清镁含量及１２００例天津市正常人群血清镁含量，结果显示，甲亢病人血清镁含量显著低于正常人群，有显著统计意义（Ｐ〈０．０１）。提示：甲亢病人血清镁含量对甲亢病诊断及治疗过程的镁的摄入补充有重要的意义。     

α-氨基膦酸酯的合成方法研究进展

从Lewis催化剂合成法、非Lewis催化剂合成法、绿色合成法3个方面综述了近年来国内外在α-氨基膦酸酯合成研究领域的最新进展.参考文献33篇.     

强脉冲电磁场对金属凝固组织影响的研究

提出了用强脉冲磁场和电流细化金属凝固组织的新工艺.与未经磁场或电流处理的凝固样品相比,强脉冲电磁场能够显著地改善LY12铝合金的凝固组织,使晶粒明显细化、球化;电磁场的强度愈强,这种改善效果愈明显.对该新工艺的细化机理进行了理论分析,同时,指出了实验中的新现象和新问题. 关键词：     

Screening of glycoside isomers in P. scrophulariiflora using ionic liquid‐based ultrasonic‐assisted extraction and ultra‐performance liquid chromatography/electrospray ionization quadrupole time‐of‐flight tandem mass spectrometry

A powerful ionic liquid‐based ultrasonic‐assisted extraction (ILUAE) method combined with ultra‐performance liquid chromatography coupled to electrospray ionization quadrupole time‐of‐flight tandem mass spectrometry (UPLC/ESI‐QTOFMSⁿ) was employed in the rapid simultaneous screening of iridoid glycosides, phenylethanoid glycosides, and cucurbitacin glycosides from P. scrophulariiflora. The ILUAE procedure was optimized over several ultrasonic parameters, including the ultrasonic power, concentration of the ionic liquid, and solid–liquid ratio. A comparison with conventional heat‐reflux extraction and regular UAE demonstrated that the optimized approach yielded a high extraction efficiency (Picroside I, 2.84%; Picroside II, 3.57%; 6‐O‐E‐feruloyl catalpol, 2.20%) within a short extraction time of 30 min. Negative ion mode ESI‐QTOFMS² analysis of the fragmentation reactions of the [M–H]^– ions was conducted to characterize the diagnostic ions related to the glycosyl moieties, aglycone units, and the type and substituted position of the ester groups. Interestingly, the positional isomers of the iridoid glycosides could be easily discriminated based on the characteristic ions. A total of 15 glycosides, including three groups of iridoid glycoside isomers and two groups of phenylethanoid glycoside isomers, were conveniently identified within 13.5 min. Moreover, 6'‐O‐vanilloyl catalpol was identified in P. scrophulariiflora for the first time. The method developed here was further validated by measuring the recovery, correlation coefficient (R²), and reproducibility (RSD, n = 5) of three iridoid glycosides: 89.60%–109.02%, 0.9991–0.9998, and 0.93%–1.44%, respectively. This study demonstrated the capabilities of ILUAE combined with UPLC/ESI‐QTOFMSⁿ for the rapid screening of glycosides in P. scrophulariiflora. This method offers an approach to similar studies on other natural plants. Copyright © 2012 John Wiley & Sons, Ltd.     

Terpenoids from Loxocalyx urticifolius

Two new diterpenoids, loxocalyxin A ( 1 ) and 13‐epiloxocalyxin A ( 2 ), and two new sesquiterpenoids, loxocalyxins B and C ( 3 and 4 , resp.), together with three known compounds, were isolated from the MeOH extract of the whole plant of Loxocalyx urticifolius Hemsl . The structures of the new compounds were established by means of spectroscopic analysis including one‐ and two‐dimensional NMR spectroscopy. All new structures were confirmed by X‐ray crystallographic analysis. Their absolute configurations were established.