首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   513篇
  免费   3篇
化学   385篇
晶体学   3篇
力学   14篇
数学   52篇
物理学   62篇
  2023年   3篇
  2022年   9篇
  2021年   10篇
  2020年   18篇
  2019年   25篇
  2018年   9篇
  2017年   6篇
  2016年   16篇
  2015年   16篇
  2014年   33篇
  2013年   34篇
  2012年   22篇
  2011年   50篇
  2010年   25篇
  2009年   24篇
  2008年   20篇
  2007年   23篇
  2006年   21篇
  2005年   16篇
  2004年   18篇
  2003年   13篇
  2002年   24篇
  2001年   4篇
  2000年   5篇
  1999年   4篇
  1998年   8篇
  1997年   2篇
  1996年   8篇
  1995年   1篇
  1994年   1篇
  1993年   4篇
  1991年   3篇
  1990年   1篇
  1988年   2篇
  1987年   5篇
  1986年   1篇
  1985年   2篇
  1984年   4篇
  1982年   3篇
  1981年   2篇
  1980年   2篇
  1979年   4篇
  1978年   3篇
  1977年   2篇
  1976年   3篇
  1975年   3篇
  1974年   3篇
  1971年   1篇
排序方式: 共有516条查询结果,搜索用时 0 毫秒
1.
2.
We study the interaction between a solid particle and a liquid interface. A semianalytical solution of the nonlinear equation that describes the interface deformation points out the existence of a bifurcation behavior for the apex deformation as a function of the distance. We show that the apex curvature obeys a simple power-law dependency on the deformation. Relationships between physical parameters disclose the threshold distance at which the particle can approach the liquid before capillarity provokes a "jump to contact." A prediction of the interface original position before deformation takes place, as well as the attraction force measured by an approaching probe, are produced. The results of our analysis agree with the force curves obtained from atomic force microscopy experiments over a liquid puddle.  相似文献   
3.
Summary We give a general construction of infinite dimensional Ornstein-Uhlenbeck processes. We present expansions of these processes based on the expansion of the covariance operators in generalized eigenfunctions, and we answer positively some question left open by J.B. Walsh on properties of the hitting times of these processes.Partially supported by NSF-Grant MCS 8202045  相似文献   
4.
This paper describes an IBM-PC menu-driven and user-friendly procedure which can help sales management in setting up optimal quota-bonus plans. For a given sales force, the resulting quotabonus plan maximizes the firm's current profits subject to (1) keeping every individual sales-force member at least at his/her current level of satisfaction (or eventually, increasing this level), and (2) being consistent and harmonious across sales representatives. The QUOPLAN system is composed of two submodels. The first submodel is used by salespersons for eliciting their own utility functions, and is essentially based upon the principles of conjoint analysis. The second submodel is used by management for reconciling all the individuals' judgements and the company's objectives into a consistent quota-bonus plan.  相似文献   
5.
Nuclear suppression factor and u 2 measurements as a function of transverse momentum for neutral strange particles are shown and compared to particle identified spectra from PHENIX and WA98 and to models that attempt to describe the suppression of particles at moderate pt in central RHIC Au?Au collisions. It is shown that identified spectra carry additional information to the published charged particle spectra. In particular, dependencies of the R AA and u 2 values on the measured particle species will be discussed in the context of several models.  相似文献   
6.
Summary The thiolato-bridged dinuclear compounds [Rh(-SR)-(COD)]2, where R=p-C6HF4 (1),p-C6H4F (2) and CF3 (3), are obtained from the chloro-bridged analogue by ligand exchange.Compound (1) crystallizes in the space group P1 with a=9.740(3)Å, b=11.642(4)Å, c=13.997(6)Å, =103.87(3)°, =106.98(3)° and =105.10(2)°; z=2. In this dinuclear molecule both Rh atoms have a square planar coordination sharing one edge, namely the two sulphur bridging atoms. The Rh—Rh separation of 2.96 Å is consistent with at most a very weak metal-metal interaction. Upon addition of CO the dimeric [Rh(-SR)(CO)2]2 (4), (5) and (6) are obtained, but addition of PPh3 affords the monomeric species [Rh(SR)(PPh3)-(COD)] (7), (8) and (9). Reactions of the dimeric tetracarbonyl derivatives with PPh3 vary with the nature of R; [Rh(-SR)(PPh3)(CO)]2 is obtained when R=p-C6H4F (10) and CF3 (11) but monomeric [Rh(SR)-(PPh3)(CO)2] (12) is produced when R=p-C6HF4. The latter mononuclear compounds, with R=p-C6H4F (13) and CF3 (14), are also formed by reaction of [Rh(SR)-(PPh3)(COD)] with CO.  相似文献   
7.
Pure gas and hydrocarbon vapor transport properties of blends of two glassy, polyacetylene-based polymers, poly(1-trimethylsilyl-1-propyne) [PTMSP] and poly(1-phenyl-1-propyne) [PPP], have been determined. Solid-state CP/MAS NMR proton rotating frame relaxation times were determined in the pure polymers and the blends. NMR studies show that PTMSP and PPP form strongly phase-separated blends. The permeabilities of the pure polymers and each blend were determined with hydrogen, nitrogen, oxygen, carbon dioxide, and n-butane. PTMSP exhibits unusual gas and vapor transport properties which result from its extremely high free volume. PTMSP is more permeable to large organic vapors, such as n-butane, than to small, permanent gases, such as hydrogen. PPP exhibits gas permeation characteristics of conventional low free volume glassy polymers; PPP is more permeable to hydrogen than to n-butane. In PTMSP/PPP blends, both n-butane permeability and n-butane/hydrogen selectivity increase as the PTMSP content of the blends increases. © 1996 John Wiley & Sons, Inc.  相似文献   
8.
The gas permeation properties of poly(1-trimethylsilyl-1-propyne) (PTMSP), poly(1-phenyl-1-propyne) (PPP), and blends of PTMSP and PPP have been determined with hydrocarbon/hydrogen mixtures. For a glassy polymer, PTMSP has unusual gas permeation properties which result from its very high free volume. Transport in PPP is similar to that observed in conventional, low-free-volume glassy polymers. In experiments with n-butane/hydrogen gas mixtures, PTMSP and PTMSP/PPP blend membranes were more permeable to n-butane than to hydrogen. PPP, on the other hand, was more permeable to hydrogen than to n-butane. As the PTMSP composition in the blend increased from 0 to 100%, n-butane permeability increased by a factor of 2600, and n-butane/hydrogen selectivity increased from 0.4 to 24. Thus, both hydrocarbon permeability and hydrocarbon/hydrogen selectivity increase with the PTMSP content in the blend. The selectivities measured with gas mixtures were markedly higher than selectivities calculated from the corresponding ratio of pure gas permeabilities. The difference between mixed gas and pure gas selectivity becomes more pronounced as the PTMSP content in the blend increases. The mixed gas selectivities are higher than pure gas selectivities because the hydrogen permeability in the mixture is much lower than the pure hydrogen permeability. For example, the hydrogen permeability in PTMSP decreased by a factor of 20 as the relative propane pressure (p/psat) in propane/hydrogen mixtures increased from 0 to 0.8. This marked reduction in permanent gas permeability in the presence of a more condensable hydrocarbon component is reminiscent of blocking of permanent gas transport in microporous materials by preferential sorption of the condensable component in the pores. The permeability of PTMSP to a five-component hydrocarbon/hydrogen mixture, similar to that found in refinery waste gas, was determined and compared with published permeation results for a 6-Å microporous carbon membrane. PTMSP exhibited lower selectivities than those of the carbon membrane, but permeability coefficients in PTMSP were nearly three orders of magnitude higher. © 1996 John Wiley & Sons, Inc.  相似文献   
9.
2-Alkoxy-3-nitro-2H-chromenes have been obtained by the reaction of β-nitroacetaldehyde dialkyl acetals with some salicylic aldehydes in the presence of triethylamine p-toluene sulfonate.  相似文献   
10.
    
Electrochemical hydrogen generation is a rising prospect for future renewable energy storage and conversion. Platinum remains a leading choice of catalyst, but because of its high cost and low natural abundance, it is critical to optimize its use. In the present study, platinum oxide nanoparticles of approximately 2 nm in diameter are deposited on carbon nitride (C3N4) nanosheets by thermal refluxing of C3N4 and PtCl2 or PtCl4 in water. These nanoparticles exhibit apparent electrocatalytic activity toward the hydrogen evolution reaction (HER) in acid. Interestingly, the HER activity increases with increasing Pt4+ concentration in the nanoparticles, and the optimized catalyst even outperforms commercial Pt/C, exhibiting an overpotential of only −7.7 mV to reach the current density of 10 mA cm−2 and a Tafel slope of −26.3 mV dec−1. The results from this study suggest that the future design of platinum oxide catalysts should strive to maximize the Pt4+ sites and minimize the formation of the less active Pt2+ species.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号