全文获取类型
收费全文 | 97810篇 |
免费 | 934篇 |
国内免费 | 742篇 |
专业分类
化学 | 37399篇 |
晶体学 | 909篇 |
力学 | 7267篇 |
综合类 | 30篇 |
数学 | 34403篇 |
物理学 | 19478篇 |
出版年
2022年 | 242篇 |
2021年 | 313篇 |
2020年 | 289篇 |
2019年 | 319篇 |
2018年 | 10600篇 |
2017年 | 10387篇 |
2016年 | 6518篇 |
2015年 | 1282篇 |
2014年 | 838篇 |
2013年 | 1427篇 |
2012年 | 4776篇 |
2011年 | 11571篇 |
2010年 | 6342篇 |
2009年 | 6687篇 |
2008年 | 7559篇 |
2007年 | 9745篇 |
2006年 | 1137篇 |
2005年 | 2207篇 |
2004年 | 2406篇 |
2003年 | 2811篇 |
2002年 | 1844篇 |
2001年 | 762篇 |
2000年 | 757篇 |
1999年 | 520篇 |
1998年 | 464篇 |
1997年 | 402篇 |
1996年 | 486篇 |
1995年 | 393篇 |
1994年 | 336篇 |
1993年 | 295篇 |
1992年 | 252篇 |
1991年 | 267篇 |
1990年 | 273篇 |
1989年 | 239篇 |
1988年 | 214篇 |
1987年 | 207篇 |
1986年 | 201篇 |
1985年 | 287篇 |
1984年 | 314篇 |
1983年 | 221篇 |
1982年 | 255篇 |
1981年 | 209篇 |
1980年 | 232篇 |
1979年 | 207篇 |
1978年 | 175篇 |
1977年 | 216篇 |
1976年 | 185篇 |
1975年 | 162篇 |
1974年 | 137篇 |
1973年 | 157篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Padavattan Govindaswamy Patrick J. Carroll Yurij A. Mozharivskyj Mohan Rao Kollipara 《Journal of Chemical Sciences》2006,118(4):319-326
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl2(κ1-P-PPh2Py)]3 and [(η5-C5Me5) IrCl2(ϰ1-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+
5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+
6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+
8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3 and [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+
7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+
8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as
analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3, [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+
6 are established by single-crystal X-ray diffraction methods 相似文献
2.
3.
4.
5.
Christiane Albrecht 《Analytical and bioanalytical chemistry》2008,390(5):1223-1224
6.
7.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
8.
Howard Robinson 《Acta Analytica》2005,20(3):7-10
Nicholas Nathan tries to resist the current version of the causal argument for sense-data in two ways. First he suggests that,
on what he considers to be the correct re-construction of the argument, it equivocates on the sense of proximate cause. Second
he defends a form of disjunctivism, by claiming that there might be an extra mechanism involved in producing veridical hallucination,
that is not present in perception. I argue that Nathan’s reconstruction of the argument is not the appropriate one, and that,
properly interpreted, the argument does not equivocate on proximate cause. Furthermore, I claim that his postulation of a
modified mechanism for hallucinations is implausibly ad hoc. 相似文献
9.
Jocelyn Sabatier Serge Poullain Patrick Latteux Jean Luc Thomas Alain Oustaloup 《Nonlinear dynamics》2004,38(1-2):383-400
Robust speed control of a low damped electromechanical system with backlash is studied, controlled load angular speed being not measured. The proposed control strategy combines a Luenberger observer (load angular speed and load torque disturbance estimations) and a robust CRONE controller. The observer provides estimation of the load angular speed and of the disturbance torque applied on the load. Through the computation of only three independent parameters (as many as a PID controller), the CRONE controller permits to ensure the robust speed control of the load in spite of plant parametric variations and speed observation errors. The proposed control strategy is applied to a four mass experimental test bench. 相似文献
10.