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1.
A set of exact conditions is compiled for the purpose of developing and testing approximations for the exchange-correlation energy as a functional of the electron density. Special emphasis is placed upon recently developed density-scaling relationships. Commonly used generalized gradient approximations are compared against several of these conditions. A direct tabular comparison of these functionals (not of calculated properties) with one another is also made. © 1994 John Wiley & Sons, Inc. 相似文献
2.
V. S. Bilanych I. I. Makauz T. D. Mel’nichenko I. M. Rizak V. M. Rizak 《Physics of the Solid State》2006,48(11):2060-2064
The internal friction in Ge x As40 ? x S60 glasses is investigated in the temperature range 100 K-T g at infralow frequencies (10?3?10?1 Hz). It is shown that the concentration dependence of the internal friction of these materials changes as a result of the transformation of the dominant kinetic unit in dissipative processes of the relaxation and nonrelaxation types. It is established tha the change in the mechanism of internal friction in the Ge x As40 ? x S60 glasses leads to a jump in the activation energy of the α relaxation and to a local minimum in the frequency factor τ0. 相似文献
3.
V. T. Astrelin A. V. Burdakov V. S. Koidan K. I. Mekler P. I. Mel’nikov V. V. Postupaev M. A. Shcheglov 《Journal of Experimental and Theoretical Physics》1998,86(3):489-500
This paper presents the results of experiments on two-stage heating of a dense plasma by a relativistic electron beam in the
GOL-3 facility. A dense plasma with a length of about a meter and a hydrogen density up to 1017 cm−3 was created in the main plasma, whose density was 1015 cm−3. In the process of interacting with the plasma, the electron beam (1 MeV, 40 kA, 4 μs) imparts its energy to the electrons of the main plasma through collective effects. The heated electrons, as they disperse
along the magnetic field lines, in turn reach the region of dense plasma and impart their energy to it by pairwise collisions.
Estimates based on experimental data are given for the parameters of the flux of hot plasma electrons, the energy released
in the dense plasma, and the energy balance of the beam-plasma system. The paper discusses the dynamics of the plasma, which
is inhomogeneous in density and temperature, including the appearance of pressure waves.
Zh. éksp. Teor. Fiz. 113, 897–917 (March 1998) 相似文献
4.
A. A. Kurskaya S. V. Mel’khanova S. M. Pimenova N. V. Yashin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(11):1754-1756
The energies of combustion and standard enthalpies of formation of 1-nitrospiro[2.3]hexane, 7-nitrodispiro[3.0.3.1]nonane, and 1,1-dinitrocyclopropane were determined experimentally. 相似文献
5.
6.
Jesús Valdés-Martínez Ruben A. Toscano Roberto Salcedo Raymundo Cea-Olivares Adrian Meléndez 《Monatshefte für Chemie / Chemical Monthly》1990,121(8-9):641-647
Summary The crystal and molecular structure of salicylaldehyde semicarbazone was obtained by single crystal X-ray diffraction. The O atom of the semicarbazone fragment isanti to the N atom of the hydrazinic group. The distribution of bond lengths in the semicarbazone fragment indicates delocalization of the -electrons. The crystal structure is stabilized by intra- and intermolecular hydrogen bonds.
Semicarbazone und Thiosemicarbazone, 12. Mitt.: Die Kristallstruktur des Salicylaldehyd-Semicarbazons
Zusammenfassung Die Kristallstruktur und die molekulare Struktur des Salicylaldehyd-Semicarbazons wurde über Einkristall-Röntgenstreuung ermittelt. Das O-Atom des Semicarbazonteils stehtanti zum N-Atom der Hydrazin-Gruppierung. Die Bindungslängen in der Semicarbazoneinheit zeigen eine Delokalisierung der -Elektronen an. Die Geometrie der Verbindung wird durch stabilisierende intra- und intermolekulare Wasserstoffbrückenbindungen bestimmt.相似文献
7.
Klára Melánová Ludvík Bene? Vítzslav Zima Jan Svoboda 《Journal of inclusion phenomena and macrocyclic chemistry》2005,51(1):97-101
The intercalates of Naphthol Yellow S, Tropaeolin 000, and Tropaeolin 00 were prepared by heating [Zn0.67Al0.33(OH)2](CO3)0.165 · 0.5H2O with acidic forms of the dye solutions in an open reaction vessel. The intercalates were characterized by chemical and thermal analysis, X-ray powder diffraction and UV–VIS spectroscopy. A possible arrangement of the dye molecules in the intercalates was suggested on the basis of their chemical compositions and interlayer distances, by taking into account van der Waals dimensions of the guest molecules and by assuming that the structure of the host layers is not changed during the intercalation process. 相似文献
8.
Ludvík Beneš Klára Melánová Vítězslav Zima Jaroslava Kalousová Jiří Votinský 《Journal of inclusion phenomena and macrocyclic chemistry》1998,31(3):275-286
Recent knowledge of the kinetics and intercalation mechanisms are summarized and accompanied by examples of intercalation reactions of water and ethanol into anhydrous vanadyl phosphate and redox intercalation of alkali metal cations into vanadyl phosphate dihydrate. Three possible mechanisms of intercalation are presented which are based on: (i) a concept of exfoliation of layers; (ii) the formation of stages and randomly stacked layers; (iii) co-existence of intercalated and non-intercalated parts of crystals of the host separated by an advancing phase boundary. The corresponding kinetic curves are ascribed to mechanisms (ii) and (iii). 相似文献
9.
I. A. Bashmakov V. A. Dorosinets V. K. Ksenevich A. A. Mel’nikov F. N. Kaputskii 《Russian Journal of Applied Chemistry》2007,80(2):285-289
A new procedure was developed for preparing carbon films with magnetic metal nanoparticles by thermolysis of a polymer precursor. The conditions for preparing carbon films with required surface concentration of the metal nanoparticles and hence with dielectric or metallic properties were determined. 相似文献
10.
An ab initio molecular orbital calculation has been carried out for three different conformations of 1,3 propanediol, one of which permits intramolecular H-bond studied by ab initio quantum mechanical methods. The ΔE for H-bonding formation is compated to be 0.9 kcal/mole and the charge redistributions and molecular orbital energy changes are compared to those found in intermolecular H-bonds. 相似文献