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排序方式: 共有285条查询结果,搜索用时 31 毫秒
1.
F. M. Bautista J. M. Campelo A. Garcia D. Luna J. M. Marinas A. A. Romero M. R. Urbano 《Reaction Kinetics and Catalysis Letters》1997,62(1):47-54
The vapor-phase catalytic alkylation of phenol with methanol and dimethyl carbonate on a series of differently prepared CrPO4 (Cr/P=1) and CrPO4-AlPO4 (CrAIP) catalysts, has been studied at different temperatures (473–673 K). The reaction is first order in phenol, giving
a mixture of O- and C-alkylated products (C-alkylation taking place preferentially at theortho-position). Moreover, dimethyl carbonate is a better methylating agent than methanol. 相似文献
2.
Carlos Cativiela Jos Ma Fraile Jos I. García Jos A. Mayoral Juan M. Campelo Diego Luna Jos M. Marinas 《Tetrahedron: Asymmetry》1993,4(12):2507-2512
Reactions of cyclopentadiene with several chiral acrylates are studied and compared with the same reactions catalysed by Zn(II)-exchanged K10 montmorillonite. In general, amorphous AlPO4 is a more efficient catalyst than the clay. In particular, the reaction of cyclopentadiene with (−)-8-phenylmenthyl acrylate leads to 74% diastereomeric excess (d.e.) in methylene chloride at low temperatures. This result constitutes the highest asymmetric induction described to date for a solid-catalysed asymmetric Diels-Alder reaction. When the reactions are carried out in the absence of a solvent a noticeable decrease in selectivity is observed, probably due to an extensive competition of the non-catalysed reaction. 相似文献
3.
[reaction: see text] A lipase-catalyzed double monoaminolysis of dimethyl malonate by (+/-)-trans-cyclopentane-1,2-diamine allows the sequential resolution of the latter compound, affording an enantiopure bis(amidoester), which is subsequently transformed into an optically active polyamine. As an alternative, both enantiomers of the diamine can be obtained from enantiopure (+)- or (-)-2-aminocyclopentanol, prepared by enzymatic resolution. 相似文献
4.
J. M. Campelo A. Garcia D. Luna J. M. Marinas 《Reaction Kinetics and Catalysis Letters》1984,26(1-2):73-77
Electron donor and acceptor properties of AlPO4 and AlPO4–SiO2 (2080 wt. %) supported rhodium catalysts have been studied. It was observed that the effect of metal deposition on both electron acceptor and donor properties depend on the support and precipitation agent. AlPO4 supported rhodium showed better acoeptor than donor properties, while for Rh/AlPO4–SiO2, the acceptor properties were superior. However, the effect of metal on the redox properties is slight.
AlPO4 QlPO4 SiO2 (2080 .%). ]ye . AlPO4 , , Rh/AlPO4–SiO2 . , - .相似文献
5.
A. Blanco J. M. Campelo A. Garcia D. Luna J. M. Marinas M. S. Moreno 《Reaction Kinetics and Catalysis Letters》1989,38(2):223-228
The effects of surface dehydration on textural properties, crystallinity and the structure of AlPO4–ZrO2 (weight ratio AlPO4/ZrO2=3) systems precipitated with ethylene oxide have been studied by N2 adsorption and XRD measurements. The increase in calcination temperature in the range 773–1273 K decreases the textural parameters as a consequence of AlPO4 crystallization to the tridymite form.
, AlPO4–ZrO2 ( AlPO4/ZrO2=3), , N2 - . 773 1273 , AlPO4 .相似文献
6.
In the present work, the nonisothermal imbibition process in a porous medium was numerically analyzed using a non-Darcian model for the momentum equation and energy equations for the wetting and dry zones. In order to show the thermal character of the problem, we assume initially that the porous medium is found at a uniform temperature T0 and suddenly begins the imbibition process into the porous medium with a penetrating fluid at temperature T1. The physical influence of nondimensional parameters such as Peclet number, Pe, effective heat capacity number, beta(w), porous Reynolds number, Re(p), and the inertial coefficient of the porous medium, F, serve us to evaluate the position and velocity of the imbibition front as well as temperature profiles in both zones. In particular, for values of Re(p)F/beta(w)>1, we recover a type of nonisothermal Washburn law. The numerical predictions show that the imbibition front and the temperature fields strongly depend on the above nondimensional parameters, revealing a clear deviation of the simple Washburn law. 相似文献
7.
Carmen Luna Concepción Lloreda Juan F. Almagro Bello Jaime Botella Maria J. Orts Ana Gozalbo 《Mikrochimica acta》2004,145(1-4):121-127
Non-metallic inclusions in steel are formed due to interactions between liquid steel and its environment in the melting shop (refractories and slags). Particles not trapped in the slag remain in the cast steel, impairing steel properties in service. Inclusion composition varies and certified standards covering the whole compositional range are unavailable.The present study describes the preparation of a set of homogeneous, glassy and crystalline standards with a wide compositional range for use in analysing non-metallic steel inclusions. For this, materials were designed based on knowledge of the compositional range of interest in the Al2O3–SiO2–CaO–MgO–CaF2 system, which is the matrix of the most frequent steel inclusions. The composition and microstructural homogeneity of the reference materials was verified. 相似文献
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10.
Carlyle T. B. Menezes Erilson C. Barros Raquel D. Rufino Juliana M. Luna Leonie A. Sarubbo 《Applied biochemistry and biotechnology》2011,163(4):540-546
Dissolved air flotation (DAF) is a well-established separation process employing micro bubbles as a carrier phase. The application
of this technique in the treatment of acid mine drainage, using three yeast biosurfactants as alternative collectors, is hereby
analyzed. Batch studies were carried out in a 50-cm high acrylic column with an external diameter of 2.5 cm. High percentages
(above 94%) of heavy metals Fe(III) and Mn(II) were removed by the biosurfactants isolated from Candida lipolytica and Candida sphaerica and the values were found to be similar to those obtained with the use of the synthetic sodium oleate surfactant. The DAF
operation with both surfactant and biosurfactants, achieved acceptable turbidity values, in accordance with Brazilian standard
limits. The best ones were obtained by the biosurfactant from C. lipolytica, which reached 4.8 NTU. The results obtained with a laboratory synthetic effluent were also satisfactory. The biosurfactants
removed almost the same percentages of iron, while the removal percentages of manganese were slightly higher compared with
those obtained in the acid mine drainage effluent. They showed that the use of low-cost biosurfactants as collectors in the
DAF process is a promising technology for the mining industries. 相似文献