MARINE PROTECTED AREAS IN THE HIGH SEAS AND THEIR IMPACT ON INTERNATIONAL FISHING AGREEMENTS

Abstract Marine protected areas (MPAs) are gaining momentum as tools within fisheries management. Although many studies have been conducted to their use and potential, only few authors have considered their use in the High Seas. In this paper, we investigate the effects of fish growth enhancing MPAs on the formation of regional fisheries management organisations (RFMOs) for highly migratory fish stocks. We argue that in absence of enforcement MPAs constitute a weakest‐link public good, which can only be realized if everyone agrees. We combine this notion with a game theoretic model of RFMO formation to derive potentially stable RFMOs with and without MPAs. We find that MPAs generally increase the parameter range over which RFMOs are stable, and that they increase stability in a number of cases as compared to the case without MPAs. They do not necessarily induce a fully cooperative solution among all fishing nations. In summary, results of this paper suggest a positive role for MPAs in the High Seas.     

MECHANISMS FOR LUMINOL-AUGMENTED CHEMILUMINESCENCE FROM NEUTROPHILS INDUCED BY LEUKOTRIENE B4 AND N-FORMYL-METHIONYL-LEUCYL-PHENYLALANINE

Neutrophils stimulated with formyl-methionyl-leucyl-phenylalanine (fMLP) or leukotriene B4 (LTB4) generated kinetically distinctive luminol augmented chemiluminescence (LCL). Inhibitors of .O2- [superoxide-dismutase (SOD) or tiron], H2O2 (catalase), myeloperoxidase, MPO, (NaN3), HOCl (taurine) and .OH (mannitol) hampered LCL dose-dependently with similar characteristics for both stimuli. In cell free systems it was found that .O2- (generated in the xanthine/xanthine-oxidase reaction) or H2O2 produced LCL. Superoxide dismutase inhibited .O2- -induced LCL dose dependently. The MPO + H2O2 system, which generated more pronounced LCL than either component alone, was inhibited by catalase and taurine but not by SOD. When neutrophils, treated with luminol, but where extracellular luminol had been removed, were stimulated with fMLP or LTB4, they produced less than 2% of the LCL where luminol was present in the medium. When neutrophil LCL and superoxide formation by the cytochrome C method were assessed in parallel experiments, in all instances the peak LCL response coincided with the linear phase in that response. Thus, LCL, induced by LTB4 and the corresponding fMLP peak, are extracellular events with similar chemical backgrounds, closely related to generation of reactive oxygen species. Consequently, the kinetical differences in LCL between fMLP and LTB4 suggest that LTB4, by yet unknown mechanisms, activates the NADPH oxidase more rapidly than fMLP.     

High resolution FTIR spectra and analysis of the ν11 fundamental and of the ν2 + ν11, ν5 + ν12 and ν7 + ν16 combination bands of 12C6D6

We report results from measurements of the high resolution FTIR spectrum for the fully deuterated benzene molecule C₆D₆ in the range 450–3500 cm^?1. Accurate spectroscopic constants have been obtained for the fundamental vibration ν₁₁ at 496.208 cm^?1 and improved ground state constants have been deduced from a fit of ground state combination differences. The J structure of the combination parallel bands ν₂ + ν₁₁ (at 2798.1 cm^?1), ν₅ + ν₁₂ (1802.5 cm_?1) and ν₇, + ν₁₆ (2619.3 cm^?1) of C₆D₆ has been analysed as well, from which improved values of the band origin and of the B and D _j constants of the excited states have been obtained. The strongest hot bands accompanying these parallel transitions have been assigned by means of the anharmonic force field calculated by Maslen et al. [1992, J. chem. Phys., 97, 4233]. In particular (ν₁₁ + ν₁₆) ? ν₁₆ is assigned to the band at 492.4 cm^?1 even though its shape is typical of a perpendicular transition (PAPE). New values for the ν₅, ν₁₂ and ν₁₆ band origins are determined from the band origins of combination bands and from calculated anharmonic constants. Numerous anharmonic constants are derived from the assignment of hot band and combination transitions.     

31P and 13C chemical shielding tensors in the phosphoenolpyruvate moiety from rotary resonance recoupling 13C and 31P MAS and single crystal 31P NMR

A ³¹P and ¹³C NMR study of powder and single crystal samples of two phosphoenolpyruvate (PEP) compounds, the tris-ammonium salt monohydrate (NH₄)₃(PEP)·H₂O (1), and the mono-ammonium-salt (NH₄)(H₂PEP) (2) is presented. The P chemical shielding tensors in 1 are measured by ³¹P single crystal NMR on four minuscule samples and assigned without ambiguity by exploiting the orientation-dependent ³¹P-³¹p dipolar splittings of the resonance lines. The orientation of the ³¹P chemical shielding tensor is discussed in terms of the C_2v — and C₃-type distortions of the phosphate PO₄-coordination sphere. From ¹³C MAS NMR experiments with ³¹P rotary resonance recoupling on polycrystalline powder samples the orientations of the ³¹P chemical shielding tensors in 1 and 2 are obtained, for 1 in very good agreement with the ³¹P single crystal NMR results. Only some of the orientational parameters of the three ¹³C chemical shielding tensors in the PEP moiety of 1 could be derived from ¹³C MAS NMR experiments with ³¹P rotary resonance recoupling.     

CLEANING A RIVER: AN ANALYSIS OF VOLUNTARY JOINT ACTION

Abstract River pollution creates negative externalities to downstream water users. In this paper, we analyze how voluntary joint action of water users can improve pollution abatement when optimal treatment cannot be enforced. We model a transboundary pollution game with a unidirectional pollutant flow. Players are identical except for their location along the river. We find that, surprisingly, the location of coalition members has no impact on coalition stability. Location does, however, affect overall welfare. The more upstream the members of the coalition are, the higher is the overall welfare because the positive externalities of cleaning accrue to a larger number of downstream water users.     

利用双膜系介质镜谐振腔产生30fs锁模脉冲

本文通过计算机叠代法,分析计算了一般所用的λ_m/4单膜系介质腔镜的色散,发现用这种腔镜难以补偿腔内脉冲的正啁啾.设计了一种双膜系介质镜,它具有补偿正啁啾所需的合适色散量φ(ω)=1.3×10~(-28)sec~2,用它代替一般腔镜,结果在没有附加任何其它色散元件情况下,直接从简单的碰撞锁模染料激光器获得30fs的脉冲输出.     

Grand Equilibrium: vapour-liquid equilibria by a new molecular simulation method

A new molecular simulation method for the calculation of vapour-liquid equilibria of mixtures is presented. In this method, the independent thermodynamic variables are temperature and liquid composition. In the first step, one isobaric isothermal simulation for the liquid phase is performed, in which the chemical potentials of all components and their derivatives with respect to the pressure, i.e. the partial molar volumes, are calculated. From these results, first-order Taylor series expansions for the chemical potentials as functions of the pressure μ _i (p) at constant liquid composition are determined. This information is needed, as the specified pressure in the liquid will generally not be equal to the equilibrium pressure, which has to be found in the course of a vapour simulation. In the second step, one pseudo grand canonical simulation for the vapour phase is performed, where the chemical potentials are set according to the instantaneous pressure p ^v using the previously determined function μ _i (p ^v). In this way, results for the vapour pressure and vapour composition are achieved which are consistent for the given temperature and liquid composition. The new method is applied to the pure Lennard-Jones fluid, a binary and a ternary mixture of Lennard-Jones spheres, and shows very good agreement with corresponding data from the literature.     

COMPARISION OF NUMERICAL SCHEMES IN LARGE-EDDY SIMULATION OF THE TEMPORAL MIXING LAYER

A posteriori tests of large-eddy simulations for the temporal mixing layer are performed using a variety of numerical methods in conjunction with the dynamic mixed subgrid model for the turbulent stress tensor. The results of the large-eddy simulations are compared with filtered direct numerical simulation (DNS) results. Five numerical methods are considered. The cell vertex scheme (A) is a weighted second-order central difference. The transverse weighting is shown to be necessary, since the standard second-order central difference (A′) gives rise to instabilities. By analogy, a new weighted fourth-order central difference (B) is constructed in order to overcome the instability in simulations with the standard fourth-order central method (B′). Furthermore, a spectral scheme (C) is tested. Simulations using these schemes have been performed for the case where the filter width equals the grid size (I) and the case where the filter width equals twice the grid size (II). The filtered DNS results are best approximated in case II for each of the numerical methods A, B and C. The deviations from the filtered DNS data are decomposed into modelling error effects and discretization error effects. In case I the absolute modelling error effects are smaller than in case II owing to the smaller filter width, whereas the discretization error effects are larger, since the flow field contains more small-scale contributions. In case I scheme A is preferred over scheme B, whereas in case II the situation is the reverse. In both cases the spectral scheme C provides the most accurate results but at the expense of a considerably increased computational cost. For the prediction of some quantities the discretization errors are observed to eliminate the modelling errors to some extent and give rise to reduced total errors.     

Multi-dimensional 1H NMR nuclear Overhauser spectroscopy under magic angle spinning: theory and application to elastomers

The process of cross-relaxation between different protons (nuclear Overhauser effect) is investigated in soft solids by 2- and 3-dimensional NMR under the conditions of fast magic-angle spinning. The cross-relaxation rates are found to depend weakly on fast motions in the Larmor frequency range and strongly on slow motions of the order of the spinning frequency W _R. Explicit expressions for the W _R dependent cross-relaxation rates are derived for different motional models. These findings were tested experimentally on elastomers, i.e., on a cross-linking series of styrene-butadiene rubbers where the cross-relaxation was studied as a function of W _R. Short mixing times as are required for extracting the relaxation rates could be realized conveniently using a pulsed magnetic-field gradient for coherence pathway selection. As in solution NMR, relative couplings between chemically resolved spins can be determined from the peak intensities. By combining cross-relaxation measurements with T ₁ measurements, the distribution of correlation times can be probed for slow and fast timescales, respectively. Only the former were found to depend on the crosslink density.