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1.
A new Schiff base, N,N′-bis-(2-hydroxy-5-bromobenzyl)-2-hydroxy-1,3-diiminopropane, has been synthesized for the very sensitive
determination of iron(III) and iron(II) in natural water samples. It enabled a very selective and rapid method for iron determination
to be developed. The method has also been applied to total iron determination in sediment samples. In the preconcentration
system, the Schiff base reagent is mixed with the samples and chelates containing iron(III). The complexes are then adsorbed
on silica gel within a column system. Elution of the adsorbed chelate from the silica gel was performed with a small volume
of acetone containing 2.5% nitric acid. The iron is measured off-line by flame atomic absorption spectrometry. The method
can be applied to the preconcentration, separation and speciation of iron. The effects of parameters such as pH, sample flow
rate, eluent flow rate, foreign ions and ligand concentration have been investigated. The effect of humic acid that can produce
complexes with metal ions in natural systems has also been investigated. The results obtained indicate that the method is
not affected by the presence of up to 10 ppm humic acid, which would be a very high concentration to be present in natural
systems. The solid phase extraction method developed has been applied to the determination of iron in both natural water samples
and sediment samples. The LOD was found to be 0.17 mg L−1 when no preconcentration was used, although preconcentration factors of 100 could be achieved. The recovery values for spiked
samples were between 100 and 104%. The results were compared statistically with those from the standard 1,10 phenanthroline
method used for iron speciation in water systems. A Student’s t-test indicated no significant difference between the two methods. In addition, this method was applied to the analysis of
a certified sediment sample, LGC 6156. Generally, a 10-fold preconcentration factor was required for the analysis of natural
water samples. 相似文献
2.
A series of new ionic binuclear Pd(II) complexes supported by water‐soluble bis(α‐diimine) ligands were prepared and employed as catalysts for the palladium‐catalyzed Suzuki reaction in aqueous media. The binuclear nature of the complexes increased the reaction rate, while electronic and steric modification of the ligand frameworks had a remarkable influence upon the catalytic activity of the palladium complexes. The catalysts were shown to be homogeneous through mercury poisoning experiments and complexes could be recycled more than 10 times without loss of catalytic activity. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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4.
A novel amperometric hydrogen peroxide biosensor based on pyrrole-PAMAM dendrimer modified gold electrode 总被引:1,自引:0,他引:1
Horseradish peroxidase (HRP) was immobilized into an electrochemically prepared copolymer of pyrrole–PAMAM (PAMAM; polyamidoamine) dendrimers for the construction of amperometric hydrogen peroxide biosensor. First, second, and third generation amidoamine–pyrrole dendrons having branched amine periphery and focal pyrrole functionality were synthesized via divergent pathway. Pyrrole dendrimers were covalently attached onto the electrode surface and polymerized by electrochemical copolymerization with pyrrole monomer. The synthesized dendrimers and copolymers have been characterized by FTIR-ATR and NMR. These copolymers have been utilized as conducting films for amperometric hydrogen peroxide sensing. The HRP retains its bioactivity after immobilization into the dendronized pyrrole-copolymers. Amperometric response was measured as a function of concentration of hydrogen peroxide, at fixed potential of +0.35 V vs. Ag/AgCl in a phosphate buffered saline (pH 7.5). The effect of pH and temperature of the medium, storage, and reusability properties were investigated. The results indicate an efficient immobilization of enzyme onto the PAMAM type dendrimer modified surface containing pyrrole monomer, which leads to high enzyme loading, and increased lifetime stability of the electrode. 相似文献
5.
David J. Lunn Emre H. Discekici Javier Read de Alaniz Will R. Gutekunst Craig J. Hawker 《Journal of polymer science. Part A, Polymer chemistry》2017,55(18):2903-2914
The development of “controlled” and “living” polymerization processes with high end-group fidelity has enabled an unprecedented range of polymeric materials with specific chain-end functionality to be prepared. This highlight provides an overview of available strategies and evaluation of recent approaches for the chain-end functionalization of polymers prepared through controlled chain-growth polymerizations. As a tribute to Professor Robert B. Grubbs on the occasion of his 75th birthday, we also take this opportunity to highlight methods for the chain-end modification of polymers prepared by ring-opening metathesis polymerization within the broader context of functional group tolerant, living polymerizations. Finally, we focus attention toward new directions in polymer chain-end modifications, describing existing gaps in current strategies, and detailing recently reported protocols that show significant improvements over traditional methods. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2903–2914 相似文献
6.
Grooming uniform all‐to‐all traffic in optical (SONET) rings with grooming ratio C requires the determination of a decomposition of the complete graph into subgraphs each having at most C edges. The drop cost of such a grooming is the total number of vertices of nonzero degree in these subgraphs, and the grooming is optimal when the drop cost is minimum. The determination of optimal C‐groomings has been considered for , and completely solved for . For , it has been shown that the lower bound for the drop cost of an optimal C‐grooming can be attained for almost all orders with 5 exceptions and 308 possible exceptions. For , there are infinitely many unsettled orders; especially the case is far from complete. In this paper, we show that the lower bound for the drop cost of a 6‐grooming can be attained for almost all orders by reducing the 308 possible exceptions to 3, and that the lower bound for the drop cost of a 7‐grooming can be attained for almost all orders with seven exceptions and 16 possible exceptions. Moreover, for the unsettled orders, we give upper bounds for the minimum drop costs. 相似文献
7.
Xiaoge Qu Laura Rowe Emre Dikici Mark Ensor Sylvia Daunert 《Analytical and bioanalytical chemistry》2014,406(23):5639-5643
Bioluminescent labels can be especially useful for in vivo and live animal studies due to the negligible bioluminescence background in cells and most animals, and the non-toxicity of bioluminescent reporter systems. Significant thermal stability of bioluminescent labels is essential, however, due to the longitudinal nature and physiological temperature conditions of many bioluminescent-based studies. To improve the thermostability of the bioluminescent protein aequorin, we employed random and rational mutagenesis strategies to create two thermostable double mutants, S32T/E156V and M36I/E146K, and a particularly thermostable quadruple mutant, S32T/E156V/Q168R/L170I. The double aequorin mutants, S32T/E156V and M36I/E146K, retained 4 and 2.75 times more of their initial bioluminescence activity than wild-type aequorin during thermostability studies at 37 °C. Moreover, the quadruple aequorin mutant, S32T/E156V/Q168R/L170I, exhibited more thermostability at a variety of temperatures than either double mutant alone, producing the most thermostable aequorin mutant identified thus far. 相似文献
8.
A Complete Solution to Spectrum Problem for Five‐Vertex Graphs with Application to Traffic Grooming in Optical Networks
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A G‐design of order n is a decomposition of the complete graph on n vertices into edge‐disjoint subgraphs isomorphic to G. Grooming uniform all‐to‐all traffic in optical ring networks with grooming ratio C requires the determination of graph decompositions of the complete graph on n vertices into subgraphs each having at most C edges. The drop cost of such a grooming is the total number of vertices of nonzero degree in these subgraphs, and the grooming is optimal when the drop cost is minimum. The existence spectrum problem of G‐designs for five‐vertex graphs is a long standing problem posed by Bermond, Huang, Rosa and Sotteau in 1980, which is closely related to traffic groomings in optical networks. Although considerable progress has been made over the past 30 years, the existence problems for such G‐designs and their related traffic groomings in optical networks are far from complete. In this paper, we first give a complete solution to this spectrum problem for five‐vertex graphs by eliminating all the undetermined possible exceptions. Then, we determine almost completely the minimum drop cost of 8‐groomings for all orders n by reducing the 37 possible exceptions to 8. Finally, we show the minimum possible drop cost of 9‐groomings for all orders n is realizable with 14 exceptions and 12 possible exceptions. 相似文献
9.
Nesrin Karaali Serdar Aydin Nimet Baltas Emre Mentese 《Journal of heterocyclic chemistry》2020,57(4):1806-1815
A new series of 5,6-dimethyl-2-phenyl-1H-benzimidazole derivatives was synthesized. The antioxidant activities of the synthesized compounds were determined according to the cupric reducing antioxidant capacity (CUPRAC), ABTS, and DPPH assays. Many of the target compounds showed good antioxidant activity. Among these compounds, it has been determined that the carbothioamide and 1,2,4-triazole derivatives had a very good antioxidant capacity. Also, all compounds were screened for in vitro inhibitory activity against Jack bean urease. Among the synthesized molecules, the starting compound, acetate, and acetohydrazide derivatives (with IC50 values 12.02, 11.40, and 8.04 μg/mL, respectively) had a higher inhibitory effect on urease and exhibited a lower IC50 values than acetohydroxamic acid (IC50: 20.50 μg/mL) and thiourea (IC50: 14.04 μg/mL) as a reference inhibitors. 相似文献
10.
Tong Wu Xiao Wang Ahmet Emrehan Emre Jinchen Fan Yulin Min Qunjie Xu Shigang Sun 《Journal of Energy Chemistry》2021,(4):48-54
Electrocatalysts for ethanol oxidation reaction(EOR)are generally limited by their poor durability because of the catalyst poisoning induced by the reaction intermediate carbon monoxide(CO).Therefore,the rapid oxidation removal of CO intermediates is crucial to the durability of EOR-based catalysts.Herein,in order to effectively avoiding the catalyst CO poisoning and improve the durability,the graphene-nickel nitride hybrids(AG-Ni3N)were designed for supporting palladium nanoparticles(Pd/AG-Ni3N)and then used for ethanol electrooxidation.The density functional theory(DFT)calculations demonstrated the introduction of AG-Ni3N depresses the CO absorption and simultaneously promotes the adsorption of OH species for CO oxidation removal.The fabricated Pd/AG-Ni3N catalyst distinctively exhibits excellent electroactivity with the mass catalytic activity of 3499.5 m A mg-1 on EOR in alkaline media,which is around 5.24 times higher than Pd/C(commercial catalyst).Notably,the Pd/AG-Ni3N hybrids display excellent stability and durability after chronoamperometric measurements with a total operation time of 150,000 s. 相似文献