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1.
A DOUBLE-TEMPERATURE-GRADIENT TECHNIQUE FOR THE GROWTH OF PURE C60 SINGLE CRYSTALS FROM THE VAPOR PHASE 总被引:1,自引:0,他引:1 下载免费PDF全文
Pure C60 single crystals were grown by a sublimation-condensation method in an evacuated dosed quartz tube situated in a double-temperature-gradient furnace. Large C60 single crystals, up to a size of 0.6 mm×1.0 mm×2.0 mm with quite smooth and shiny faces, were obtained. X-ray diffraction, electron diffraction and X-ray morphology were carried out and showed that the quality of large C60 single crystals grown by the double-temperature-gradient technique is excellent. In this paper the experimental results of the growth of large C60 single crystals are reported and the morphological and structural characterizations are discussed in detail. 相似文献
2.
利用扫描电子显微镜(SEM)、高分辨透射电子显微镜(HRTEM)和扫描隧道显微镜(STM),对布基管和布基洋葱的形貌、结构、生长机理进行了研究。结果表明采用垂直下落武装置制备布基管具有较大的产率,TEM的观察得到了布基管各种部位的横截面TEM象,报道了几种特殊结构的布基管和布基洋葱,分析了造成布基管形貌变化的原因,提出了布基管和布基洋葱生长过程的模板作用,提出在无定形石墨和布基管之间存在过渡态结构的观点,STM的研究结构获得了椅式布基管表面的原子象。 相似文献
3.
利用STS测量并结合扫描隧道显微镜(STM)扫描图象,给出一组沿石墨单晶表面原子分辨的STM图象上某一线段各点处的扫描隧道谱.d(lnI)/d(lnV)~eV由测量谱给出的样品表面EF附近局域态密度分布与由体能带结构计算得到的结果在一定程度上相符合,将各条曲线中EF附近的态密度峰能量对相应的空间位置作图,给出石墨表面EF附近能态密度在测量区域内实空间的变化。通过对表面不等价A,B类原子处局域电子结构的分析并利用简单模型进行计算,给出了与实验
关键词: 相似文献
4.
The electronic structure and vibrational spectrum of the C60 film condensed on a 2H- MoS2(0001) surface have been investigated by X-ray photoelectron spectroscopy (XPS), ul-traviolet photoelectron spectroscopy (UPS), Auger electron spectroscopy (AES) and infrared high-resolution electron-energy-loss spectroscopy (HREELS). AES analysis showed that at low energy side of the main transition, C60 contains a total of three peaks just like that of graphite. However, the energy position of the KLL main Auger transition of C60 looks like that of diamond, indicating that the hybridization of the carbon atoms in C60 is not strictly in sp2- bonded state but that the curvature of the molecular surface introduces some sp2pz- bonded character into the molecular orbitals. XPS showed that the C 1s binding energy in C60 was 285.0eV, and its main line was very symmetric and offered no indication of more than a single carbon species. In UPS measurement the valence band spectrum of C60 within 10eV below the Fermi level (EF) shows a very distinct five-band structure that character-izes the electronic structure of the C60 molecule. HREEL results showed that the spectrum obtained from the C60 film has very rich vibrational structure. At least, four distinct main loss peaks can be identified below 200 meV. The most intense loss was recorded at 66 meV, and relatively less intense losses were recorded at 95, 164 and 197meV at a primary energy of electron beam EP = 2.0eV. The other energy-loss peaks at 46, 136, 157 and 186meV in HREEL spectrum are rather weak. These results have been compared to infrared spectrum data of the crystalline solid C60 taken from recent literatures. 相似文献
5.
The electronic structure and vibrational spectrum of the C60 film condensed on a 2H- MoS2(0001) surface have been investigated by X-ray photoelectron spectroscopy (XPS), ul-traviolet photoelectron spectroscopy (UPS), Auger electron spectroscopy (AES) and infrared high-resolution electron-energy-loss spectroscopy (HREELS). AES analysis showed that at low energy side of the main transition, C60 contains a total of three peaks just like that of graphite. However, the energy position of the KLL main Auger transition of C60 looks like that of diamond, indicating that the hybridization of the carbon atoms in C60 is not strictly in sp2- bonded state but that the curvature of the molecular surface introduces some sp2pz- bonded character into the molecular orbitals. XPS showed that the C 1s binding energy in C60 was 285.0eV, and its main line was very symmetric and offered no indication of more than a single carbon species. In UPS measurement the valence band spectrum of C60 within 10eV below the Fermi level (EF) shows a very distinct five-band structure that character-izes the electronic structure of the C60 molecule. HREEL results showed that the spectrum obtained from the C60 film has very rich vibrational structure. At least, four distinct main loss peaks can be identified below 200 meV. The most intense loss was recorded at 66 meV, and relatively less intense losses were recorded at 95, 164 and 197meV at a primary energy of electron beam EP = 2.0eV. The other energy-loss peaks at 46, 136, 157 and 186meV in HREEL spectrum are rather weak. These results have been compared to infrared spectrum data of the crystalline solid C60 taken from recent literatures. 相似文献
6.
The distribution, morphology and structure of carbon nanotubes and buckyonions produced from an arc discharge were investigated by means of scanning electron mi-croscopy and high-resolution transmission electron microscopy, The nanotubes and nanoonions were found to be located mainly near the porous region of the core in the deposited rods and the transition region between the growth ring-shaped graphite sheets. The tube bundles grew freely from carbon particles. Apart from the straight-line tubes, curved and bent tubes were also found. Studies on the structure of them showed that the carbon atomic sheets in the nanotubes displayed a stepped bending. Transverse sectional study predicted a helical structure of the carbon atomic sheets. In addition, the relationship between the number of pentagonal rings and cone angle at the tips of the tubes, as well as the mechanism of the formation of the steplike structure, were discussed. 相似文献
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8.
A DOUBLE-TEMPERATURE-GRADIENT TECHNIQUE FOR THE GROWTH OF PURE C60 SINGLE CRYSTALS FROM THE VAPOR PHASE 下载免费PDF全文
Pure C60 single crystals were grown by a sublimation-condensation method in an evacuated dosed quartz tube situated in a double-temperature-gradient furnace. Large C60 single crystals, up to a size of 0.6 mm×1.0 mm×2.0 mm with quite smooth and shiny faces, were obtained. X-ray diffraction, electron diffraction and X-ray morphology were carried out and showed that the quality of large C60 single crystals grown by the double-temperature-gradient technique is excellent. In this paper the experimental results of the growth of large C60 single crystals are reported and the morphological and structural characterizations are discussed in detail. 相似文献
9.
A Novel Reactive Gas Source and Its Application to Carbon Nanotube Film Deposition 总被引:1,自引:0,他引:1 下载免费PDF全文
Generally, gaseous discharge at pressure higher than 10 kPa will collapse to filamentary form or streamer, which will produce a non-uniform treatment on the sample surface. Thus, atmospheric pressure glow discharge (APGD) is developed, However the realization of the APGD is not obvious, it needs special conditions. We propose a new concept to solve the non-uniformity problem. By using a grid electrode and putting the sample downstream of the discharge plasma, the streamers, instead of striking on sample surface, will strike on the grid, and the neutral active species produced in the discharge diffuse out to reach the sample surface uniformly. Finally, a carbon nanotube (CNT) film was produced to test this new concept. 相似文献
10.