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排序方式: 共有252条查询结果,搜索用时 15 毫秒
1.
A. Baeza M. Fernández M. Herranz F. Legarda C. Miró A. Salas 《Journal of Radioanalytical and Nuclear Chemistry》2004,260(2):321-326
We studied the effectiveness of potable water treatment processes that consist of the stages of coagulation-flocculation-decantation,
using iron-based coagulants, in eliminating gamma-emitting man-made radioisotopes of cesium, strontium, and americium from
two natural waters with different degrees of mineralization. The resulting decontamination was found to depend on the chemical
behavior of each of the radionuclides considered, on the pH at which the process of coagulation is carried out, and on the
concentration of the other stable cations present.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
2.
Koji Yagi Veronica Garcia Ma. E. Rivas Javier Salas Andres Camargo Takeo Tabata 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(1-2):179-184
Some crown ethers were found to show significant antifungal activity against some wood-decay fungi, phytopathogenic fungi and eumycetes,Trichophytons for dermatomycosis. Their toxicity was evaluated by the paper disc method as well as by determining the values of ED50, i.e., the concentration which inhibits the mycelium growth by 50%. The fungi examined areTyromyces palustris, Picnoporous coccineus, Coriolous versicolor, Pyricularia filamentosa, Fusarium sp., Trichophyton rubrum, Trichophyton sp., etc. Among the 26 crown ethers tested, 3,5-di-t-butyl-benzo-15-crown-5 showed relatively high activity, the highest ED50 value of which being 8 M or 3 ppm. Other alkylbenzocrown ethers, dicyclohexyl crown ethers and Kryptofix 22DD also showed considerable activity. On the other hand, unsubstituted crown ethers, benzocrown ethers with a polar substituent, Kryptofix 222B and Kryptofix 221 were inactive. 相似文献
3.
Chemotherapeutic drugs for cancer treatment have been traditionally originated by the isolation of natural products from different environmental niches, by chemical synthesis or by a combination of both approaches thus generating semisynthetic drugs. In the last years, a number of gene clusters from several antitumor biosynthetic pathways, mainly produced by actinomycetes and belonging to the polyketides family, are being characterized. Genetic manipulation of these antitumor biosynthetic pathways will offer in the near future an alternative for the generation of novel antitumor derivatives and thus complementing current methods for obtaining novel anticancer drugs. Novel antitumor derivatives have been produced by targetted gene disruption and heterologous expression of single (or a few) gene(s) in another hosts or by combining genes from different, but structurally related, biosynthetic pathways ("combinatorial biosynthesis"). These strategies take advantage from the "relaxed substrate specificity" that characterize secondary metabolism enzymes. 相似文献
4.
Mohammad Abul‐Haj Miguel Quirs Juan M. Salas 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):934-935
The title compound, [Ni(NCS)2(C5H4N4O)2(H2O)2], crystallizes in the triclinic space group P. The molecular unit contains two neutral molecules of 4,5‐dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidin‐5‐one (5HtpO) coordinated through the N atom in position 3, two thiocyanate ligands coordinated through their N atoms and two water molecules completing an octahedral environment around the NiII ion, which lies on a centre of inversion. The structure is stabilized by hydrogen bonding. Distances in the coordination sphere are Ni—N3(5HtpO) 2.132 (2), Ni—O(water) 2.085 (2) and Ni—N(thiocyanato) 2.040 (2) Å. 相似文献
5.
The impact of blood on liver metabolite profiling – a combined metabolomic and proteomic approach 下载免费PDF全文
Saray Ly‐Verdú Alexander Schaefer Melanie Kahle Thomas Groeger Susanne Neschen Jose M. Arteaga‐Salas Marius Ueffing Martin Hrabe de Angelis Ralf Zimmermann 《Biomedical chromatography : BMC》2014,28(2):231-240
Metabolomics has entered the well‐established omic sciences as it is an indispensable information resource to achieve a global picture of biological systems. The aim of the present study was to estimate the influence of blood removal from mice liver as part of sample preparation for metabolomic and proteomic studies. For this purpose, perfused mice liver tissue (i.e. with blood removed) and unperfused mice liver tissue (i.e. containing blood) were compared by two‐dimensional gas chromatography time of flight mass spectrometry (GC × GC‐TOFMS) for the metabolomic part, and by liquid chromatography tandem mass spectrometry (LC‐MS/MS) for the proteomic part. Our data showed significant differences between the unperfused and perfused liver tissue samples. Furthermore, we also observed an overlap of blood and tissue metabolite profiles in our data, suggesting that the perfusion of liver tissue prior to analysis is beneficial for an accurate metabolic profile of this organ. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
6.
J. Salas 《Journal of statistical physics》1995,80(5-6):1309-1326
A method for computing low-temperature series for renormalized operators in the two-dimensional Ising model is proposed. These series are applied to the study of the properties of the truncated renormalized Hamiltonians when we start at very low temperature and zero field. The truncated Hamiltonians for majority rule, Kadanoff transformation, and decimation for 2×2 blocks depend on the how we approach the first-order phase-transition line. The renormalization group transformations are multivalued and discontinuous at this first-order transition line when restricted to some finite-dimensional interaction space. 相似文献
7.
Héctor N. Salas 《Journal of Mathematical Analysis and Applications》2011,374(1):106-117
Let E be a separable Fréchet space. The operators T1,…,Tm are disjoint hypercyclic if there exists x∈E such that the orbit of (x,…,x) under (T1,…,Tm) is dense in E×?×E. We show that every separable Banach space E admits an m-tuple of bounded linear operators which are disjoint hypercyclic. If, in addition, its dual E∗ is separable, then they can be constructed such that are also disjoint hypercyclic. 相似文献
8.
We prove that theq-state Potts antiferromagnet on a lattice of maximum coordination numberr exhibits exponential decay of correlations uniformly at all temperatures (including zero temperature) wheneverq>2r. We also prove slightly better bounds for several two-dimensional lattices: square lattice (exponential decay forq7), triangular lattice (q11), hexagonal lattice (q4), and Kagomé lattice (q6). The proofs are based on the Dobrushin uniqueness theorem. 相似文献
9.
In this paper,a new approach is devoted to find novel analytical and approximate solutions to the damped quadratic nonlinear Helmholtz equation(HE)in terms of the Weiersrtrass elliptic function.The exact solution for undamped HE(integrable case)and approximate/semi-analytical solution to the damped HE(non-integrable case)are given for any arbitrary initial conditions.As a special case,the necessary and sufficient condition for the integrability of the damped HE using an elementary approach is reported.In general,a new ansatz is suggested to find a semi-analytical solution to the non-integrable case in the form of Weierstrass elliptic function.In addition,the relation between the Weierstrass and Jacobian elliptic functions solutions to the integrable case will be derived in details.Also,we will make a comparison between the semi-analytical solution and the approximate numerical solutions via using Runge-Kutta fourth-order method,finite difference method,and homotopy perturbation method for the first-two approximations.Furthermore,the maximum distance errors between the approximate/semi-analytical solution and the approximate numerical solutions will be estimated.As real applications,the obtained solutions will be devoted to describe the characteristics behavior of the oscillations in RLC series circuits and in various plasma models such as electronegative complex plasma model. 相似文献
10.
The aim of the present work is to characterize the pigments present in the kernel of four native maize varieties related to the races Arrocillo, Cónico, Peruano, and Purepecha to determine their possible use as natural dyes. Total anthocyanin content is determined by a conventional spectrophotometric method, and anthocyanin analysis is done by high-performance liquid chromatography. The stability of the pigment at pH is also evaluated. The four maize samples contained anthocyanin in both the pericarp and aleurone layer. Total anthocyanin content among samples ranged from 54 mg/100 g of sample to 115 mg/100 g of sample. Anthocyanin profiles are almost the same among the four samples. Differences are observed only in the relative percentage of each anthocyanin. The anthocyanins identified are cyanidin-3-glucoside, pelargonidin- 3-glucoside, peonidin-3-glucoside, cyanidin-3-(6" malonylglucoside), and cyanidin-3-(3",6"-dimalonylglucoside). Anthocyanin extracts showed similar behavior in solutions with different pH. From pH 1-6 lambdamax values are maintained almost constant; however, above this pH value, a marked increase is observed in the bathochromic shifts, but the bluish color did not continue to change above pH 8. 相似文献