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排序方式: 共有156条查询结果,搜索用时 15 毫秒
1.
A simple experimental technique using an instrumented pin was developed for the measurement of the load-contact variation in a clearance-fit, pin-loaded hole. The method is applicable to both conducting and nonconducting materials. 相似文献
2.
Nanocrystalline CuFe2O4 and CuFe2O4/xSnO2 nanocomposites (x=0, 1, 5 wt%) have been successfully synthesized by one-pot reaction of urea-nitrate combustion method. The transmission electron microscope study reveals that the particle size of the as synthesized CuFe2O4 and CuFe2O4/5 wt%SnO2 are 10 and 20 nm, respectively. The SnO2 coating on the nanocrystalline CuFe2O4 was confirmed from HRTEM studies. The resultant products were sintered at 1100 °C and characterized by XRD and SQUID for compound formation and magnetic studies, respectively. The X-ray diffraction pattern shows the well-defined sharp peak that confirms the phase pure compound formation of tetragonal CuFe2O4. The zero field cooled (ZFC) and field cooled (FC) magnetization was performed using SQUID magnetometer from 2 to 350 K and the magnetic hysteresis measurement was carried out to study the magnetic properties of nanocomposites. 相似文献
3.
Cover Picture: A new topological insulator built from quasi one‐dimensional atomic ribbons (Phys. Status Solidi RRL 2/2015) 下载免费PDF全文
4.
Lancaster T Blundell SJ Andreica D Janoschek M Roessli B Gvasaliya SN Conder K Pomjakushina E Brooks ML Baker PJ Prabhakaran D Hayes W Pratt FL 《Physical review letters》2007,98(19):197203
The ferroelectromagnet YMnO3 consists of weakly coupled triangular layers of S=2 spins. Below T(N) approximately equal to 70 K muon-spin relaxation data show two oscillatory relaxing signals due to magnetic order, with no purely relaxing signals resolvable (which would require different coexisting spin distributions). The transition temperature T(N) increases with applied hydrostatic pressure, even though the ordered moment decreases. These results suggest that pressure increases both the exchange coupling between the layers and the frustration within the layers. 相似文献
5.
Ehrke H Tobey RI Wall S Cavill SA Först M Khanna V Garl T Stojanovic N Prabhakaran D Boothroyd AT Gensch M Mirone A Reutler P Revcolevschi A Dhesi SS Cavalleri A 《Physical review letters》2011,106(21):217401
We used ultrafast resonant soft x-ray diffraction to probe the picosecond dynamics of spin and orbital order in La(0.5)Sr(1.5)MnO(4) after photoexcitation with a femtosecond pulse of 1.5 eV radiation. Complete melting of antiferromagnetic spin order is evidenced by the disappearance of a (1/4,1/4,1/2) diffraction peak. On the other hand, the (1/4,1/4,0) diffraction peak, reflecting orbital order, is only partially reduced. We interpret the results as evidence of destabilization in the short-range exchange pattern with no significant relaxation of the long-range Jahn-Teller distortions. Cluster calculations are used to analyze different possible magnetically ordered states in the long-lived metastable phase. Nonthermal coupling between light and magnetism emerges as a primary aspect of photoinduced phase transitions in manganites. 相似文献
6.
Conformationally rigid aromatic amino acids as potential building blocks for abiotic foldamers 总被引:1,自引:0,他引:1
Ramesh VV Roy A Vijayadas KN Kendhale AM Prabhakaran P Gonnade R Puranik VG Sanjayan GJ 《Organic & biomolecular chemistry》2011,9(2):367-369
This communication describes the development of conformationally constrained unnatural aromatic amino acids, constructed on rigid backbone wherein the carboxyl and amino groups project in two dimensions (planes) on the aromatic framework. Such a feature offers the possibility of design and development of conformationally ordered synthetic oligomers with intriguing structural architectures distinct from those classically observed. Furthermore, such amino acids will have the potential to extend the conformational space available for foldamer design with diverse backbone conformation and structural architectures. 相似文献
7.
Vattoly J. MajoJaya Prabhakaran J.John MannJ.S. Dileep Kumar 《Tetrahedron letters》2003,44(47):8535-8537
A novel and convergent palladium catalyzed synthesis of 2-arylbenzothiazoles has been investigated. The key step in the synthesis is a Suzuki biaryl coupling of 2-bromobenzothiazole with aryl boronic acids to provide a variety of 2-arylbenzothiazole derivatives in good yield. The synthetic utility of this methodology is demonstrated by the synthesis of 2-(4-aminophenyl)-6-methoxybenzothiazole, a PET probe precursor for the in vivo imaging of Alzheimer's disease. 相似文献
8.
A new heterocyclic Schiff bases, 6‐methyl/8methyl‐2‐oxo‐1,2‐dihydroquinoline‐3‐carboxaldehyde semicarbazones (H2‐6MOQsc‐H) ( H 2 L 1 ) and (H2‐8MOQsc‐H) ( H 2 L 2 ) and their corresponding copper(II) complexes [CuCl2(H2‐6MOQsc‐H)].3H2O ( 1 ), [CuCl2(H2‐8MOQsc‐H)].3H2O ( 2 ), [CuNO3(H2‐6MOQsc‐H)(H2O)].NO3 ( 3 ) and [CuNO3(H2‐8MOQsc‐H)(H2O)].NO3 ( 4 ) have been synthesized and characterized by various physicochemical techniques. The single crystal X‐ray diffraction and spectral data revealed that all of the complexes ( 1‐4 ), the ligands coordinated to the Cu(II) ion in a neutral manner via ONO donor atoms and all the complexes exhibited distorted squarepyramidal geometry. The consequence of electronegativity and ring size of nitrogen heterocyclic moiety of ONO donor type of copper(II) chelates on nucleic acid interaction and albumin binding was investigated by in vitro experiments. The interaction of compounds with calf‐thymus DNA (CT‐DNA) has been explored by absorption and emission titration, which exposed those ligands/complexes, could bind with CT‐DNA through electrostatic interaction. The results of gel electrophoresis proved the ability of complexes ( 1‐4 ) to cleave the pBR322 plasmid DNA. The interaction of serum albumin (BSA) was investigated by UV‐Vis, fluorescence, synchronous and three dimensional fluorescence spectra. In addition, radical scavenging activity, antifungal activity and cytotoxicity of the newly synthesized compounds were also evaluated. From the results of in vitro studies, it is seen that complex 3 has more potential as compared with other complexes and ligands. 相似文献
9.
M. Parthibavarman S. Sathishkumar S. Prabhakaran M. Jayashree R. BoopathiRaja 《Journal of the Iranian Chemical Society》2018,15(12):2789-2801
The paper investigates the structural, optical and photocatalytic activity of large surface area single crystalline copper (Cu) doped SnO2 nanorods (NRs) synthesized by a novel one-step microwave irradiation method. Powder X-ray diffraction (XRD) analysis confirms that both pure and Cu doped SnO2 are tetragonal rutile type structure (space group P42/mnm) formed during the microwave process within 10 min without any post annealing treatment. Transmission electron microscopy (TEM) reveals that the as synthesized Cu doped SnO2 samples exhibited rod-like shape and the length was less than 80 nm and diameter was about few nanometers. Typical selected-area electron diffraction (SAED) pattern indicates that, the growth direction of Cu–SnO2 nanorod is along [110] direction. The variety of phonon interaction in the pure and Cu doped SnO2 is observed by Raman spectroscopy. Electron paramagnetic resonance and X-ray photoelectron spectroscopy (XPS) confirms that the presence of copper and tin as Cu2+ and Sn4+ in state, respectively. The photocatalytic activity was monitored via the degradation of methylene blue (MB) and Rhodamine B (RhB) dyes and the Cu–SnO2 showed better photocatalytic activity than that of pure SnO2. This could be attributed to the effective electron–hole separation by surface modification. 相似文献
10.
An efficient improved procedure for the synthesis of beta-acetamido carbonyl compounds is developed by a cobalt(II) chloride-catalyzed three-component coupling protocol. The procedure is also amenable to the synthesis of gamma-lactams by a three-component coupling reaction with use of 2-carbomethoxybenzaldehyde. The beta-acetamido carbonyl compounds derived from 2-carbomethoxybenzaldehyde are useful intermediates as they can be transformed to the corresponding gamma-lactams on treatment with base. 相似文献