全文获取类型
收费全文 | 871篇 |
免费 | 13篇 |
国内免费 | 2篇 |
专业分类
化学 | 638篇 |
晶体学 | 3篇 |
力学 | 26篇 |
数学 | 139篇 |
物理学 | 80篇 |
出版年
2022年 | 22篇 |
2021年 | 25篇 |
2020年 | 15篇 |
2019年 | 17篇 |
2018年 | 21篇 |
2017年 | 6篇 |
2016年 | 23篇 |
2015年 | 18篇 |
2014年 | 20篇 |
2013年 | 59篇 |
2012年 | 43篇 |
2011年 | 57篇 |
2010年 | 43篇 |
2009年 | 32篇 |
2008年 | 57篇 |
2007年 | 43篇 |
2006年 | 44篇 |
2005年 | 41篇 |
2004年 | 41篇 |
2003年 | 39篇 |
2002年 | 18篇 |
2001年 | 11篇 |
2000年 | 17篇 |
1999年 | 16篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 13篇 |
1995年 | 11篇 |
1994年 | 3篇 |
1993年 | 9篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1975年 | 3篇 |
1966年 | 2篇 |
1958年 | 2篇 |
1954年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有886条查询结果,搜索用时 15 毫秒
1.
2.
3.
Glass fragments dating from the seventh and eighth century AD were excavated in the Crypta Balbi in Rome. They were studied to detect agents involved in colour development and opacification. Reflectance spectra recorded on powdered samples revealed the contribution of Fe(II), Fe(III), Mn(III), Cu(II), and Co(II) ions in determining colour hues. The effect of the Mn/Fe atomic ratio on glass colour is discussed. It is apparent that medieval glassmakers in Italy could obtain a wide range of colours by exploiting the presence of iron and manganese as contaminants of sand and flux and controlling the amount of oxygen let into the furnace. X-ray diffraction and scanning electron microscopy coupled with energy-dispersive X-ray analysis were used to study opaque fragments. The presence of calcium antimonate was detected in white, blue, and blue-green fragments, and elemental copper was detected in a red glass. 相似文献
4.
Pucci V Bugamelli F Mandrioli R Ferranti A Kenndler E Raggi MA 《Biomedical chromatography : BMC》2004,18(1):37-44
An accurate and precise high-performance liquid chromatographic method using diode array detection for the determination of the novel antiepileptic, Levetiracetam, has been developed. Three clean-up procedures for the analysis of Levetiracetam in human plasma were implemented and evaluated, namely solid-phase extraction, deproteinization by addition of organic solvents and formation of insoluble salts. Adenosine was used as the internal standard for all three sample pretreatment procedures. Among the several cartridges used for solid-phase extraction, the hydrophilic-lypophilic balance (Oasis) HLB) phase provides the best extraction yield of Levetiracetam, together with high precision. With the two other clean-up procedures involving plasma deproteinization by addition of methanol or zinc sulphate, lower sensitivity and precision of the assays were obtained. However, they are cheaper and faster when compared with the solid-phase extraction procedure. 相似文献
5.
G. Piccitto R. Pucci N. H. March A. Grassi 《International journal of quantum chemistry》1989,36(4):525-531
The derivative of the electron–electron potential energy Uee with respect to internuclear separation R is studied for light homonuclear diatomic molecules at equilibrium. It is readily related to nuclear–nuclear potential energy Unn, the force constant K, and the electron–nuclear potential energy Uen. An approximate expression, based on the simplest form of density functional theory, is then used to eliminate dUen/dR|Re. The result thus obtained for dUee/dR|Re transcends an earlier proposal of Kryachko by including a term 2/3ReK, with K the force constant. Numerical tests at SCF–RHF level are presented for nine homonuclear diatomic molecules. 相似文献
6.
Alessandra LattanziLiliana R. Orelli Patrizia BaroneAntonio Massa Patrizia IanneceArrigo Scettri 《Tetrahedron letters》2003,44(7):1333-1337
A mild and practical procedure of Horner-Wadsworth-Emmons olefination promoted by lithium hydroxide and α-cyano phosphonates has been set up for the synthesis of α,β-unsaturated nitriles. The reaction conditions are tolerated by functionalized ketones and the exclusive formation of E-γ-hydroxy α,β-unsaturated nitriles has been observed. 相似文献
7.
Tarozzi A Marchesi A Hrelia S Angeloni C Andrisano V Fiori J Cantelli-Forti G Hrelia P 《Photochemistry and photobiology》2005,81(3):623-629
Ultraviolet-A (UVA) radiation causes significant oxidative stress because it leads to the generation of reactive oxygen species (ROS), leading to extensive cellular damage and eventual cell death either by apoptosis or necrosis. We evaluated the protective effects of cyanidin-3-O-beta-glucopyranoside (C-3-G) against UVA-induced apoptosis and DNA fragmentation in a human keratinocyte cell line (HaCaT). Treatment of HaCaT cells with C-3-G before UVA irradiation inhibited the formation of apoptotic cells (61%) and DNA fragmentation (54%). We also investigated antioxidant properties of C-3-G in HaCaT cells against ROS formation at apoptotic doses of UVA; C-3-G inhibited hydrogen peroxide (H2O2) release (an indicator of cellular ROS formation) after UVA irradiation. Further confirmation of the potential of C-3-G to counteract UVA-induced ROS formation comes from our demonstration of its ability to enhance the resistance of HaCaT cells to the apoptotic effects of both H2O2 and the superoxide anion (O2*-), two ROS involved in UVA-oxidative stress. Furthermore, in terms of Trolox Equivalent Antioxidant Activity, C-3-G treatment led to a greater increase in antioxidant activity in the membrane-enriched fraction than in the cytosol (55% vs 19%). The protective effects against UVA-induced ROS formation can be attributed to the higher membrane levels of C-3-G incorporation. These encouraging in vitro results support further research into C-3-G (and other anthocyanins) as novel agents for skin photoprotection. 相似文献
8.
The guest-induced synthesis of a molecular box from methylaquacobaloxime and 1,4-phenylenebisboronic acid, with pyrazine (pz) as guest, is described. The resulting supramolecular species was characterized by X-ray structural analysis, 1H and 13C NMR spectroscopy, and low-resolution electrospray ionization (ES) mass spectrometry. The assembly was monitored by a time dependent 1H NMR experiment, which showed that the guest thermodynamically drives the assembly of the host. The effectiveness of pyrazine in this role arises from its having both the correct geometry and a sufficiently low pKa value. Several other ditopic ligands were tested, but none led to formation of an analogous product. However, a second supramolecular species was formed in the case of ethylenediamine (en). X-ray structural analysis and 1H and 13C spectroscopy revealed that this is closely related to the first, with a phenyl side removed and the pz bridge substituted by the en bridge. 相似文献
9.
This survey critically discusses high-concentration-capacity (HCC) headspace (HS) techniques applied to sample the volatile fraction of matrices of interest in the flavors and fragrance fields. In particular, the advantages, limits, and fields of application of HS solid-phase microextraction (SPME), high-capacity HS sorptive extraction (HSSE) and HS solid-phase dynamic extraction (SPDE) are evaluated. These techniques are discussed in view of the peculiar characteristic of HCC-HS techniques, from the standpoint that these techniques are a bridge between static (S-HS) and dynamic HS (D-HS) because they are as simple, fast, easy to automate, and reliable as S-HS, yet afford analyte concentration factors comparable to those of D-HS. Moreover, the different degree of their development is a consequence of the different times in which they were introduced into the market, because the potential of HS-SPME is now well known, having been introduced approximately 12 years ago, but that of HSSE has still to be fully explored, and HS-SPDE still has to be investigated because it is very recent. 相似文献
10.
The lactonisation of ethylene 1,1-dioxy 2-methyl 3-oxo cyclopentane-2 propionic acid has been affected by a new method whose mechanism is discussed. The formation of a β-diketone and other products by isomerisation of the enol lactone has been avoided. The enol lactone is an important intermediate in the total synthesis of steroids and has been prepared with a good yield by the new method. 相似文献