全文获取类型
收费全文 | 2115篇 |
免费 | 94篇 |
国内免费 | 9篇 |
专业分类
化学 | 1769篇 |
晶体学 | 16篇 |
力学 | 29篇 |
数学 | 69篇 |
物理学 | 335篇 |
出版年
2023年 | 8篇 |
2022年 | 14篇 |
2021年 | 22篇 |
2020年 | 31篇 |
2019年 | 35篇 |
2018年 | 29篇 |
2017年 | 23篇 |
2016年 | 54篇 |
2015年 | 47篇 |
2014年 | 55篇 |
2013年 | 88篇 |
2012年 | 106篇 |
2011年 | 170篇 |
2010年 | 74篇 |
2009年 | 86篇 |
2008年 | 169篇 |
2007年 | 153篇 |
2006年 | 147篇 |
2005年 | 129篇 |
2004年 | 121篇 |
2003年 | 101篇 |
2002年 | 87篇 |
2001年 | 20篇 |
2000年 | 29篇 |
1999年 | 31篇 |
1998年 | 25篇 |
1997年 | 23篇 |
1996年 | 25篇 |
1995年 | 13篇 |
1994年 | 18篇 |
1993年 | 15篇 |
1992年 | 14篇 |
1991年 | 10篇 |
1990年 | 13篇 |
1989年 | 10篇 |
1988年 | 10篇 |
1987年 | 14篇 |
1986年 | 8篇 |
1985年 | 19篇 |
1984年 | 26篇 |
1983年 | 13篇 |
1982年 | 24篇 |
1981年 | 18篇 |
1980年 | 9篇 |
1979年 | 12篇 |
1978年 | 9篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1975年 | 10篇 |
1973年 | 15篇 |
排序方式: 共有2218条查询结果,搜索用时 15 毫秒
1.
Mitsuki Yamashita Yuna Kawasumi Yuki Tachibana Dr. Shinnosuke Horiuchi Dr. Koji Yamamoto Prof. Tetsuro Murahashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(5):1212-1216
Although small cyclic- and open-chain unsaturated hydrocarbon anions such as cyclopentadienide and open-chain pentadienide are used as the strongly electron-donating auxiliary ligands for metal complexes, more extended π-conjugated unsaturated hydrocarbon anions have rarely been used in coordination chemistry, despite their potential ability to serve as the multiply bridging π-ligands for metal clusters. This work reports isolation of metal chain clusters bearing the multi-dentate, open-chain extended unsaturated hydrocarbon anion ligands. The extended open-chain π-conjugated polyenyl ligands could effectively stabilize oxidized palladium chains, including an unprecedented [Pd4]4+ chain. 相似文献
2.
Surface texturing has been recognized as an effective means to improve the tribological performances of sliding surfaces. Usually, generation additional hydrodynamic pressure to increase the load carrying capacity is regarded as the most significant effect of surface texture. In the case of silicon carbide sliding against identical material in water, the experimental results indicate that surface texture is also helpful to improve the running-in progress to smooth the contact surfaces, showing another reason to result in low friction. Based on the consideration of enhancing the generation of hydrodynamic pressure and improving running-in progress, a surface texture pattern, which was combined with large (circle, 350 μm in diameter) and small (rectangular, 40 μm in length) dimples, was designed to maximize the texture effect on the load carrying capacity of SiC surfaces sliding in water. The friction coefficient of such textured surface was evaluated and compared with that of untextured and those only with large or small dimples only. The friction reduction mechanisms of the patterns with different dimples in size are discussed. 相似文献
3.
R. Bairava Ganesh Hitoshi Matsuo Takahiro Kawamura Yoshihiro Kangawa Koji Arafune Yoshio Ohshita Masafumi Yamaguchi Koichi Kakimoto 《Journal of Crystal Growth》2008,310(11):2697-2701
Multicrystalline silicon was grown by unidirectional solidification method using the accelerated crucible rotation technique. The application of the accelerated crucible rotation technique in unidirectional solidification method induced growth striations across the axial direction of the grown crystal. This striation pattern was observed from carbon concentration distribution, obtained by using Fourier transform infrared spectroscopy. The generated striation pattern was found to be weak and discontinuous. Some striations were absent, probably due to back melting, caused during each crucible rotation. From the growth striations and applied time period in crucible rotation, the growth rate was estimated by using Fourier transformation analysis. 相似文献
4.
Yoshio Suzuki Noriyuki Tanji Chikako Ikeda Aki Honda Kenji Ookubo Daniel Citterio Suzuki Koji 《Analytical sciences》2004,20(3):475-482
Novel labeling reagents, called MS probes, which possess a positively charged quaternary amine moiety and can transform a neutral analyte into a charged compound by simply mixing with the analyte and allowing the mixture to stand from several minutes to 30 min at room temperature or while heating to 50 degrees C, were designed and synthesized for the highly sensitive detection of carbonyl, alcohol, carboxylic acid and primary amine samples by electrospray ionization mass spectrometry (ESI-MS). The positively charged products can be detected with high sensitivity in an ESI-MS system, which is the most popular liquid MS instrument. All of the labeled products showed a remarkably large increase in the molecular-ion peak abundance detection sensitivity of over 500-fold at picomolar concentration levels compared to that of unlabeled analytes in an ESI-MS system. These MS probes, used together with liquid MS detection, are widely applicable as a convenient method for the highly sensitive detection of less than picomolar levels of analytes, and therefore greatly enhance the power of ESI-MS analysis. 相似文献
5.
In order to change the ion-exchange selectivity of anion-exchange resin, the surface of a gel-type anion exchange resin was modified with anionic polyelectrolyte, polystyrenesulfonic acid. Using this modified resin, the ion-exchange rate of nitrate was little decreased, but that of sulfate was evidently decreased. It is considered that the ion-exchange reaction of the multivalent anion is suppressed by the greater electrostatic repulsive force against the modification layer than that against the monovalent anion. Thus, this modified resin may be suitable for the selective separation of monovalent anions. The influence of the modified condition on the ion-exchange rate was examined. Furthermore, this modified resin was used to separate nitrate ions from sulfate ions in the aqueous solution. 相似文献
6.
7.
The paper presents the first report on χ(2) polarization induced in molecular glass of conjugated compound by all-optical poling. Transparent thin film of molecular glass of 1,4-bis[2-[4-[N,N-di(p-tolyl)amino]phenyl]vinyl]benzene (BTAPVB) was prepared using a spin-cast technique. Dipolar as well as octupolar components in BTAPVB contributed to the formation of photoinduced χ(2) polarization. Growth rate of χ(2) polarization has good linear relation with Eω4E2ω, which suggested that the simultaneous processes of two-photon (ω + 2ω) and three-photon (ω + ω + ω) excitation on the same electronic level contributed to the formation of photoinduced χ(2) polarization. 相似文献
8.
Koji Hasegawa 《Communications in Mathematical Physics》1997,187(2):289-325
For Belavin's elliptic quantum R-matrix, we construct an L-operator as a set of difference operators acting on functions on
the type A weight space. According to the fundamental relation RLL=LLR, taking the trace of the L-operator gives a set of commuting difference operators. We show that for the above mentioned L-operator
this approach gives Macdonald type operators with elliptic theta function coefficient, actually equivalent to Ruijsenaars'
operators. The relationship between the difference L-operator and Krichever's Lax matrix is given, and an explicit formula
for elliptic commuting differential operators is derived. We also study the invariant subspace for the system which is spanned
by symmetric theta functions on the weight space.
Received: 27 December 1995 / Accepted: 11 November 1996 相似文献
9.
Abstract— Irradiation of near-UV light in the presence of FeCl3 caused oxidation of adenosine with concomitant reduction of Fe(III) under either aerobic or anaerobic atmosphere. Major photoproducts were adenine and adenosine-5'-aldehyde, showing that oxidation took place mostly at the ribose moiety of adenosine. Detailed study showed that the reaction proceeded by the light absorption due to Fe(III) at 300-350 nm. 相似文献
10.
A simple and rapid method for the analysis of trace amounts of gold(III), palladium(II), and platinum(IV) by the combined use of graphite furnace atomic absorption spectrometry and anion-exchange separation was proposed, and successfully applied to the rapid determination of metals in industrial waste solutions obtained from the final process of noble-metal recovery factories, because noble metals can be selectively and quantitatively separated to a high degree by using a small column containing only a 0.7 g-portion of a common anion-exchange resin and a dilute thiourea solution. 相似文献