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1.
我们用最近研制成功的LMA型低频力学谱测试系统对NiTi合金马氏体相进行了在很大频率范围内(0.003~1Hz)的低频等温力学谱和温度谱的测量.我们研究的形状记忆合金NiTi(Ni50.2at%)试样长34mm,直径1mm细丝.经一定热处理,分别在333K.343K和353K做了内耗随频率的变化的测量。实验表明:频率越小,内耗越大,也就是内耗随频率减少而增大。同时我们采用阶梯升温的方法在八个温度下每个温度测量三种频率(1Hz,0.1Hz,0.01Hz)的内耗,结果清楚地表明:不同频率下,内耗峰都出现在372K(99℃)。而且频率越低,峰高越高。这是具有相变峰的特点:相变峰的峰温不随测量频率不同而变化,相变峰高度随频率减少而增大。我们还测量了在1Hz与0.5Hz频率下内耗随温度的变化。本文用马氏体相的位错理论初步讨论了上述实验结果。 相似文献
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Arikainen EO Boden N Bushby RJ Lozman OR Vinter JG Wood A 《Angewandte Chemie (International ed. in English)》2000,39(13):2333-2336
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A series of trinuclear metal clusters MS4(M'PPh3)2(M'PPh3) (M = Mo, W; M' = Cu, Ag, Au) have been studied using the density functional theory (DFT) method. The static polarizabilities and hyperpolarizabilities of the model clusters have been calculated using the finite-field (F-F) method. The model clusters, divided into two groups, are alike in the structure of two fragments of rhombic units M-(mu-S)2-M' (M = Mo, W; M' = Cu, Ag, Au), perpendicular to each other, which are joined by sharing the bridge metal M. It is the charge transfer from one of these moieties to the other in these characteristic sulfido-transitional metal cores that is responsible for the polarizabilities and hyperpolarizabilities. This kind of electronic delocalization, different from that of the planar pi-system, is interesting and warrants further investigation. The structural effects on properties are important. In these models, considerable third-order nonlinearities are exhibited. The element substitution effect of Mo and W is weak, while that of Cu and Ag is relatively substantial. An overall order is gamma xxxx(Mo-Ag) > gamma xxxx(W-Ag) > gamma xxxx(Mo-Au) > gamma xxxx(W-Au) > gamma xxxx (Mo-Cu) > gamma xxxx(W-Cu) and gamma av(Mo-Ag) approximately gamma av(W-Ag) > gamma av(Mo-Au) approximately gamma av(W-Au) approximately gamma av (Mo-Cu) approximately gamma av(W-Cu). 相似文献
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A new ternary polar intermetallic, Ca(18)Li(5)In(25.07), was obtained from high-temperature reactions of the elements in welded Nb tubes. Its crystal structure, established by single-crystal X-ray diffraction, was found to crystallize in the orthorhombic space group Cmmm (No. 65). Unit cell parameters are a = 9.9151(6) A, b = 26.432(2) A, and c = 10.2116(6) A; Z = 2. The structure of Ca(18)Li(5)In(25.07) features two distinct types of indium anionic layers. An "electron-deficient" layer is made up of Li-centered In(12) icosahedra that are interconnected by bridging planar In(4) units and In atoms. A second In(3)(5-) layer is an electron-precise Zintl layer formed by fused four-, five-, and six-membered rings of three- and four-bonded indium atoms. The two distinct layers are alternately stacked and linked into a complex three-dimensional network. Vacancies are observed to occur only at the In(12) icosahedral and the bridging indium units within the "electron-deficient" layers. Magnetic property measurements indicate that Ca(18)Li(5)In(25.07) exhibits temperature-independent paramagnetism consistent with metallic behavior. Band structure calculations were performed to elucidate the role of defects and vacancies in the electronic structure of the electron-deficient "metallic" Zintl phase. 相似文献