排序方式: 共有31条查询结果,搜索用时 0 毫秒
1.
2.
3.
CM Silva MF Duarte ML Mira MH Florêncio K Versluis AJ Heck 《Rapid communications in mass spectrometry : RCM》1999,13(12):1098-1103
Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
4.
D. A. H. Ament J. J. Nuño-Ballesteros B. Oréfice-Okamoto J. N. Tomazella 《Bulletin of the Brazilian Mathematical Society》2016,47(3):955-970
Given an analytic function germ f: (X, 0) → C on an isolated determinantal singularity or on a reduced curve, we present formulas relating the local Euler obstruction of f to the vanishing Euler characteristic of the fiber X ∩ f-1(0) and to the Milnor number of f. Restricting ourselves to the case where X is a complete intersection, we obtain an easy way to calculate the local Euler obstruction of f as the difference between the dimension of two algebras. 相似文献
5.
6.
7.
The chemical states of iron in near-shore and deep-sea sediments were investigated by means of57Fe Mössbauer spectroscopy using selective and chemical leachings. The Fe2+/Fe3+ ratios of deep-sea sediments were much smaller than those of near-shore sediments, while the total contents of iron in the former were much higher than those in the latter. This is principally due to the high content of hydrogenous ferric oxyhydroxide in deep-sea sediments. Also, in the aluminosilicate fraction, the Fe2+/Fe3+ ratios of deep-sea sediments were smaller than those of near-shore sediments. This is probably attributed to the difference in the silicate mineral composition between deep-sea and near-shore sediments. X-ray reflections of clay minerals normalized to those of feldspars and quartz were more intense in deep-sea sediments than in near-shore sediments. 相似文献
8.
9.
The dispersion of the elusive elementary excitations of orbital ordered systems, orbitons, has escaped detection so far. The recent advances in resonant inelastic x-ray scattering (RIXS) techniques have made it, in principle, a powerful new probe of orbiton dynamics. We compute the detailed traces that orbitons leave in RIXS for an e{g} orbital ordered system, using the ultrashort core-hole lifetime expansion for RIXS. We observe that both single- and double-orbiton excitations are allowed, where the former, at lower energy, have sharper features. The rich energy- and momentum-dependent intensity variations that we observe make clear that RIXS is an ideal method to identify and map out orbiton dispersions. 相似文献
10.
Kevin Ament Daniel R. Wagner Frederieke E. Meij Friedrich E. Wagner Josef Breu 《无机化学与普通化学杂志》2020,646(14):1110-1115
Maghemite (γ-Fe2O3) is a metastable iron oxide phase and usually undergoes fast phase transition to hematite at elevated temperatures (>350 °C). Maghemite nanoparticles were synthesized by the polyol method and then intercalated into a highly swollen (>100 nm separation) nematic phase of hectorite. A composite of maghemite nanoparticles sandwiched between nanosheets of synthetic hectorite was obtained. The confinement of the nanoparticles hampered Ostwald ripening up to 700 °C and consequently the phase transition to hematite is suppressed. Only above 700 °C γ-Fe2O3 nanoparticles started to grow and undergo phase transition to α-F2O3. The structure and the phase transition of the composite was evaluated using X-ray diffraction, TEM, SEM, physisorption, TGA/DSC, and Mößbauer spectroscopy. 相似文献