全文获取类型
收费全文 | 500篇 |
免费 | 17篇 |
国内免费 | 2篇 |
专业分类
化学 | 365篇 |
晶体学 | 5篇 |
力学 | 19篇 |
数学 | 31篇 |
物理学 | 99篇 |
出版年
2022年 | 17篇 |
2021年 | 25篇 |
2020年 | 19篇 |
2019年 | 13篇 |
2018年 | 22篇 |
2017年 | 11篇 |
2016年 | 16篇 |
2015年 | 5篇 |
2014年 | 25篇 |
2013年 | 74篇 |
2012年 | 16篇 |
2011年 | 18篇 |
2010年 | 14篇 |
2009年 | 14篇 |
2008年 | 14篇 |
2007年 | 10篇 |
2006年 | 14篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 9篇 |
2001年 | 8篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1994年 | 4篇 |
1993年 | 9篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1988年 | 9篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1972年 | 5篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1968年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有519条查询结果,搜索用时 17 毫秒
1.
Pyrolysis of α-phenylacetanilide resulted in migration of the benzyl group to the o and p positions of the aniline nucleus and formation of CO, NH3, toluene benzaldehyde, dibenzyl, trans stilbene, aniline, 9 phenylacridine and 2,3 diphenyl-indole. With o-toluidine as a solvent the previous products were accompanied by 2,3 diphenyl-7-methylindole and 4 amino 3 methyl diphenylmethane. With isoqumoline 1 benzyl isoquinoline and 1,1' bi-isoquinolyl were also obtained.It is concluded that the pyrolysis of phenylacetanilide depends on the homolytic fission of the amide C-N bond into anilino and phenylacetyl free radicals followed by the interaction of the primary and secondary formed radicals with the rearrangement products and solvent nuclei. 相似文献
2.
Summary Extraction of scandium and calcium radioactivities with 1% HDEHP in benzene from nitric acid solution was investigated. The effect of potassium titanium oxalate concentration on the extraction from 1.5M nitric acid was studied. From the data obtained, two procedures based on batch solvent extraction and extraction chromatography were developed for separation and production of radioscandium from a neutron-irradiated potassium titanium oxalate target. The radiochemical purity of the separated scandium radioactivities was more than 98%.
Zusammenfassung Die Extraktion der Aktivitäten des Scandiums und Calciums aus salpetersaurer Lösung mit 1% Diäthylhexylphosphorsäure in Benzol wurde untersucht. Der Einfluß der Kalium-Titanoxalat-Konzentration auf die Extraktion aus 1,5-m Salpetersäure wurde geprüft. Auf Grund der Ergebnisse wurden zwei Verfahren zur Trennung und Gewinnung von Radio-Scandium aus einem neutronenbestrahlten Kalium-Titanoxalat-Target ausgearbeitet, die auf einmaliger Extraktion mit dem Lösungsmittel bzw. auf Extraktionschromatographie beruhen. Die radiochemische Reinheit der Sc-Aktivitäten war besser als 98%.相似文献
3.
Extraction of nitric, perchloric, and hydrochloric acid by N,N-dibutyl diethyl carbamyl phosphonate in carbon tetrachloride was investigated. The data obtained are treated in terms of stepwise neutralization of the acid with the formation of species y · HA and y · 2HA in the organic phase, where y stands for the extractant and HA for the acid. The equilibrium constants, K?1 and K?2 for nitric acid were found to equal 0.24 ± 0.02 and 0.017 ± 0.005, respectively. In case of HClO4 and HCl K?1 were found to equal 0.031 ± 0.003 and 0.0039 ± 0.0005, respectively. A third phase was observed when extraction of HClO4 was performed using acid concentration higher than 3.5 molar. The preference for partition of different acids was discussed on the light of the competition of the proton between the acid anion, water and the basic extractant as well as the degree of the ionization of different acids. 相似文献
4.
A new route has been developed for the micro-determination of227Ac in geological materials by neutron activation. The method is based on intense neutron irradiation of the analysed samples followed by separation and α-spectrometric determination of228Th, the β-decay product of the 6.1 hrs228Ac isotope formed. Two alternatives are considered for analysis related to the origin of the analysed matrix. The high sensitivity of the method is documented by the determination of 10?17 g227Ac/g sample. The method is successfully applied for age determination of five uranium containing materials and old uranium glass from Bohemia, CSSR. 相似文献
5.
Synergistic extraction of samarium with TTA(HA) and TPPO or TOPO (B) mixtures were investigated. The extracted complex was proved to have the general formula SmA3 · 2B. A graphical determination for the formation constants of these complexes gave the values 3.9 × 1013 and 8.2 × 1010 for SmA3 · 2TOPO and SmA3 · 2TPPO in benzene, respectively. 相似文献
6.
The extraction of radio-mercury(II) by PTTDT was investigated as function of diluent, hydrochloric acid concentration, extractant
concentration and certain foreign compounds in the aqueous phase. The extraction was found to be quantitative when chloroform
was used as diluent and at low HCl or high PTTDT concentrations. Neither the presence of boric acid, nor several metal salts
(NaF, CuSO4, ZnSO4 or Na2SO4) had any effect on the E%. The presence of chloride or bromide lowers the E% considerably. A radiochemical procedure was
developed to pre-concentrate mercury from artifical sea water using an organic: aqueous phase ratio of 1∶100. 相似文献
7.
H. F. Aly 《Journal of Radioanalytical and Nuclear Chemistry》1976,30(2):425-431
The concept of using paper chromatography on papers impregnated with liquid anion or cation exchangers is extended to the
separation of trace elements through filtration on filter papers loaded with suitable extractant. The uptake of uranium, thorium
and lanthanum from HCl and HNO3 media of different molarities by a filter paper treated with tri-octyl amine (TOA) is investigated. The effect of the different
parameters on the uptake of the studied elements is experimented. A simple and fast radiochemical procedure is developed for
the separation of La, Th and U from each other. 相似文献
8.
N. El-Said A. S. Mekhael S. M. Khalifa H. F. Aly 《Journal of Radioanalytical and Nuclear Chemistry》1996,208(1):257-270
In this work Strontium was separated selectively form, Pd2+, Ni2+ and Ca3+ using anionic resins of Amberlite type IRA-900 and IRA-410 from nitrate medium. The Separation of strontium by strongly basic anion exchangers IRA-410 and IRA-900 from simulated waste containing, Sr2+, Eu3+, Ce3+, Pd2+, Rh3+, Ru3+, VO2 2+, Fe3+, Cr3+, Ni2+, Al3+, Ca2+, and Cs+, in K2SO4/nitrate medium which adsorbed as strontium sulphate complex was achieved through ligand- ligan exchange. The elution of strontium carried out via “loading” the column with a solution of 0.03N EDTA in presence of 0.1N NaNO3 at pH7 where Sr2+ has low Kd value. An inductively Coubled Plasma — Optical Emission Spectrometry (ICP — OES) of ARL type model 3520, was used for elemental analysis. 相似文献
9.
The infrared absorption spectra of 12 lanthanide acetylacetonate complexes were measured in the region 400–2000 cm?1 and discussed. Assignments of the bands especially those due to metal-oxygen (M—O), C=O and C=C stretching vibration is given. It is found that the band at 530 ± 5 cm?1 is due mainly to Ln—O stretching vibration. In the carbonyl region, it is confirmed that the band at lower frequency is a C=C stretching vibration while that at higher frequency is due to C=O stretching vibration. Integral intensities for the M—O, C=O and C=C stretching vibrations were calculated in KB1 and CHCl3 solutions. The variation of the intensities of the M—O bands witn complexed cation were discussed in terms of crystal field stabilization energy (CFSE). 相似文献
10.
Sorption of uranium by non-living water hyacinth roots 总被引:1,自引:0,他引:1
S. Shawky M. Abdel Geleel Ashraf Aly 《Journal of Radioanalytical and Nuclear Chemistry》2005,265(1):81-84
Summary Many studies have shown that water hyacinth (Eichhornia crassipes) roots can be used to accumulate high concentrations of organic as well as inorganic pollutants. They are currently used to remediate aquatic environments and aqueous solutions. In the present study, sorption of uranium from aqueous solutions by using dried roots of water hyacinth has been investigated. The sorption of uranium was examined as a function of initial concentration, pH, weight of roots and contact time. Five different concentrations 20, 40, 60, 80, and 100 μg . ml-1 were used. Sorption proves to be very rapid and depend on pH, weight of roots and concentration of uranium. Maximum sorption capacity of water hyacinth roots was 64,000 U6+ μg/g. The sorption of uranium by water hyacinth roots follows a Langmuir isotherm. 相似文献