Femtosecond relaxation dynamics of surface plasmon-polaritons in the vicinity of fano-type resonance

Temporal modification of femtosecond laser pulses reflected from planar periodic metal nanostructures with resonant excitation of surface plasmon-polaritons is experimentally studied. Spectral time-resolved measurements of the second-order cross-correlation function performed with the pulse duration comparable with the surface plasmon-polariton relaxation time (about 100 fs) show the strong spectral dependence of the envelope of the reflected femtosecond pulse described by Fano-resonance parameters.     

Theory of self-induced separation of a turbulent boundary layer

Plane steady flow is considered in the case of an incompressible fluid in the neighborhood of the separation point of a turbulent boundary layer. It is shown that separation takes place in a region which lies at some small distance downstream from the region of interaction.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 51–60, May–June, 1987.     

Femtosecond relaxation dynamics of surface plasmon-polaritons in the vicinity of fano-type resonance

JETP Letters - Temporal modification of femtosecond laser pulses reflected from planar periodic metal nanostructures with resonant excitation of surface plasmon-polaritons is experimentally...     

New classes of integral functionals for which the integral representation of lower semicontinuous envelopes is valid

M.A. Sychev has recently shown that conditions necessary and sufficient for the lower semicontinuity of integral functionals with p-coercive integrands are W^1,p-quasi-convexity and the so-called matching condition (M). Condition (M) is so general that there is the conjecture that is always holds in the case of continuous integrands. The paper develops relaxation theory (construction of lower semicontinuous envelopes) under the assumption that condition (M) holds. It turns out that, in this case, the theory has very good structure. Applications of general relaxation theory to particular cases, including the theory of strong materials, are also discussed.     

Variational field theory from the point of view of direct methods

In this paper we show that the classical field theory ofWeierstrass–Hilbert can be strengthen on applying direct methods. Concretely, given a field of extremals and an extremal that is an element of the field, we can show that the latter gives minimum in the class of Lipschitz functions with the same boundary data and with the graphs in the set covered by the field. We suggest the two proofs: a modern one (exploiting Tonelli’s Theorem on lower semicontinuity of integral functionals with respect to the weak convergence of admissible functions in W ^1,1) and the one based only on arguments available already in the 19th century.     

The effect of simple electrolytes on coagulation of hydrosols of monodisperse negatively charged detonation nanodiamond

The influence of the concentration of potassium and barium chlorides on the aggregation stability of a hydrosol of monodisperse negatively charged detonation nanodiamond with particle sizes of 4?5 nm obtained by annealing of its agglomerates in air has been studied by turbidimetry. The experimental results have been discussed within the classical and generalized Derjaguin?Landau?Verwey?Overbeek theories. The analysis of the pair interaction potentials calculated for ultradispersed particles of detonation nanodiamond has led to the conclusion that the coagulation occurs by the barrier mechanism in the primary potential minimum. It has been assumed that the structural component of the interparticle interaction energy contributes to the total balance of the surface forces.     

Filled latex composites with high dielectric constant, based on dispersed ferroelectrics

The possibility of controlling the physicochemical properties of suspensions and the electrical properties of filled latex composites containing dispersed ferroelectrics was examined. The use of ferroelectrics as fillers allows preparation of polymeric composites with high dielectric constant ? and low dielectric loss, used, e.g., for the development of dielectric functional layers of electroluminescence light sources.     

Photochromism of 1′,3′,3′-trimethyl-6-piperidinospiro [indoline-2′,3-3H-naphth [2,1-b][1,4]-oxazine]

The effect of the piperidine substituent on the spectral and photochromic properties of spiro(indoline-naphthoxazines) (SINO) in different solvents is studied. The introduction of this substituent into the naphthoxazine fragment of SINO results in the appearance of fluorescence of the initial formA of SINO at low temperatures. This fluorescence gradually disappears as the temperature increases. The temperature and concentration dependences of the spectral parameters of photoinduced formB of SINO make it possible to assume thatB molecules aggregate in non-polar solvents. In all solvents studied, form B, unlike the photoinduced form of the non-substituted spiro naphthoxazine, is stabilized as a bipolar ion with a positive charge on the nitrogen atom of the piperidine substituent. The increase in the rate of thermal decolorization as the medium polarity increases is explained.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 684–688, April, 1995.The authors are grateful to the Belarus' Foundation for Basic Research for financial support of this work.     

Features of the photochromic behavior of spiroanthrooxazine in solutions

The photochromic properties of 1,3,3-trimethylspiro[indolin-2,3-3H-anthraceno[2,1-b][1,4]-oxazine] (SAO) in solutions of different polarity [n-BuOH and petroleum ether (PETh)] were studied. It was established that the quantum yield of the photocoloration AB and the energy of activation of the thermal decolorization E_a in the PETh depend on the temperature; this is not the case in n-BuOH. The luminescence properties of SAO were investigated. It was found that the spectrum of the excitation of the luminescence in PETh depends on the temperature. These features, as well as the slower thermal decolorization of the colored form of SAO in PETh by comparison with the solutions in n-BuOH, are explained by the presence of dimers of the SAO molecules in nonpolar media in the temperature range investigated (77–300 K), whereas the SAO molecules already occur in the monomeric state at 150 K in the polar n-BuOH.N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977 Moscow. Branch of the Institute of the Physics of Solids and Semiconductors, Academy of Sciences of Belarus, 211177 Vitebsk. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 93–98, January, 1992.