全文获取类型
收费全文 | 593篇 |
免费 | 16篇 |
国内免费 | 2篇 |
专业分类
化学 | 386篇 |
晶体学 | 3篇 |
力学 | 12篇 |
数学 | 100篇 |
物理学 | 110篇 |
出版年
2023年 | 3篇 |
2022年 | 12篇 |
2021年 | 18篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 8篇 |
2017年 | 8篇 |
2016年 | 22篇 |
2015年 | 13篇 |
2014年 | 27篇 |
2013年 | 29篇 |
2012年 | 38篇 |
2011年 | 38篇 |
2010年 | 22篇 |
2009年 | 22篇 |
2008年 | 35篇 |
2007年 | 38篇 |
2006年 | 33篇 |
2005年 | 33篇 |
2004年 | 31篇 |
2003年 | 17篇 |
2002年 | 13篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 9篇 |
1995年 | 9篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 13篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1921年 | 1篇 |
排序方式: 共有611条查询结果,搜索用时 15 毫秒
1.
For a given two-dimensional surface μ, we studi invariants for oriented links in μ×[0,1] which generalize the two-variable
HOMFLY polynomials when μ is the 2-disk. These invariants are connected to multiparameter quantum groups whose special properties
are discussed.
Si studiano gli invarianti dei nodi in spazi del tipo μ×[0,1], dove μ è una superficie. Questi invarianti generalizzano gli
invarianti di HOMFLY.
(Conferenza tenuta dal Prof. P. Cotta-Ramusino il 16 maggio 1991) 相似文献
(Conferenza tenuta dal Prof. P. Cotta-Ramusino il 16 maggio 1991) 相似文献
2.
Maria Benedetta Fadda Nicoletta Curreli Raffaello Pompei Antonio Rescigno Augusto Rinaldi Enrico Sanjust 《Applied biochemistry and biotechnology》1994,44(3):263-270
A highly active thermostable β-glucosidase was purified to homogeneity from a strain ofTrichoderma sp. The enzyme was an extracellular glycoprotein and showed hydrolytic activity toward several β-glucosides.
Cellobiose was found to be the substrate of choice for this enzyme. This finding could suggest future technological applications
of the purified protein. 相似文献
3.
We consider a class of non-linear mixed integer programs with n integer variables and k continuous variables. Solving instances from this class to optimality is an NP-hard problem. We show that for the cases with
k=1 and k=2, every optimal solution is integral. In contrast to this, for every k≥3 there exist instances where every optimal solution takes non-integral values.
Received: August 2001 / Accepted: January 2002?Published online March 27, 2002 相似文献
4.
C. A. Rinaldi J. C. Ferrero S. I. Lane E. V. Oexler 《Journal of Chemical Sciences》1991,103(3):465-469
The IR multiphoton dissociation of CF3I has been studied in the presence of isobutane and with isobutane and Ar and CO2 as inert gases. The dependence of the reaction probability P(Φ) with fluence (ϕ) is confirmed. Modeling of the experimental results shows that for the energy transfer processes the average energy transferred
per collision 〈†E〉d varies with (ϕ). 相似文献
5.
Monwar M Oh SJ Rinaldi PL McCord EF Hutchinson RA Buback MM Latz H 《Analytical and bioanalytical chemistry》2004,378(6):1414-1427
Poly(n-butylacrylate-co-carbon monoxide-co-ethylene) (polyEBC) samples prepared from 13C-labeled monomer, n-butyl acrylate, were characterized using two dimensional (2D) pulsed field gradient (PFG) 750 MHz NMR spectroscopy. To elucidate the complex structure of the terpolymer, 2D-1H/13C-heteronuclear single quantum coherence (HSQC) and heteronuclear multiple bond correlation (HMBC) experiments were conducted by selectively exciting the enhanced resonances in the spectra of two polymer samples, one polymer resulting from synthesis with 1-13C-n-butylacrylate monomer and a second polymer obtained from a synthesis with 2-13C-n-butylacrylate monomer. High-resolution 2D-NMR combined with 13C-labeling of the polymer greatly simplifies the 2D-NMR spectra, selectively enhances the weak peaks from low occurrence B-centered triad structures, and aids in their resonance assignments. In all experiments, the sample temperature was 120 degrees C, to ensure a homogeneous solution and sufficient molecular mobility. Electronic Supplementary Material: Supplementary material (1D 13C NMR spectra of the 13C-labeled and unlabeled polymers) is available in the online version of this article at http://dx.doi.org/100.1007/s00216-003-2402-3. 相似文献
6.
Giovannelli Tommaso Liuzzi Giampaolo Lucidi Stefano Rinaldi Francesco 《Computational Optimization and Applications》2022,82(2):293-327
Computational Optimization and Applications - In this paper, mixed-integer nonsmooth constrained optimization problems are considered, where objective/constraint functions are available only as the... 相似文献
7.
Gloria Rinaldi 《Results in Mathematics》1996,29(1-2):149-152
Using a transformation tecnique for designs introduced in [1], I construct a class of arcs embeddeable in the Hall plane and in the dual of the Hall plane of order q proving also their completeness in the unital of Grüning. Math. Subj. Class.: 51A35 Non Desarguesian affine and projective planes. 51E22 Blocking sets, ovals, k-arcs. 相似文献
8.
The impedance of the cell Au/HClO4-5.5 H2O/Au was investigated in the frequency range 1 to 105 Hz between 4.2 and 300 K. The analysis of the data enables an evaluation of important electrolyte properties such as conductivity and dielectric constant in a wide range of temperatures, predominantly in the solid state of the electrolyte HClO4-5.5 H2O (Tf = 228 K). The double layer capacity of the gold electrodes was also determined; it shows a qualitatively similar result compared with previous measurements. In the solid state, the ionic conductivity exhibits two distinct activation energies of 0.37 and 0.54 eV corresponding to the two phases present in HClO4-5.5 H2O above and below 170 K. Below 120 K the activation energy becomes very small and tends to zero around 80 K indicating possible tunneling processes in the rigid H2O structure. At about the same temperature the dielectric constant reaches its low temperature limit with a value ∞ ≈ 11 which is considerably higher than the value of pure ice of ∞ ≈ 3. 相似文献
9.
The model of Onsager in which a polar molecule undergoes a reaction field due to the polarization of the molecular surroundings is used to evaluate by a S.C.F. calculation (CNDO/2 approximation) the modifications of a molecular structure in the liquid state.Application to water molecule and to three polar dimers for values of the dielectric constant varying between 3 and 78, shows that most of geometric parameters and dipoles moments vary of few per cent when the molecule is inserted in a liquid. In the liquid state dipole moments do not depend very much on the dielectric constant but energies and relative stabilities of isomers are strongly dependent on the medium.[/p] 相似文献
10.
The self-consistent reaction field model developed previously by the authors in the case of single center multipole expansion of the electronic structure of the solute has been extended to the case of a distributed multipole expansion. Three different expansions have been tested and two of them have proved to be rapidly convergent. The performances of the code are illustrated by the density functional theory treatment of few test systems: guanine, cytosine, and cytosine hydrated with one and three water molecules. A robust fast computer code has been tested to get the electronic structure, the electrostatic contribution to the solute-solvent free energy of interaction, and the optimized molecular geometry in solution. 相似文献