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1.
G A van't Klooster F M Woutersen-van Nijnanten H J Kolker J Noordhoek A S van Miert 《Journal of chromatography. A》1992,579(1):158-164
Ethylmorphine N-demethylation is used as a marker pathway in studies of rat cytochrome P450 3A and 2C11 biotransformations. At present, microsomal activities are generally measured by a colorimetric determination of the formed formaldehyde. In the present study, a high-performance liquid chromatographic method of separating and quantifying both the N-demethylated (norethylmorphine) and the O-de-ethylated (morphine) metabolites is described. Either samples are extracted with ethyl acetate or proteins are precipitated with zinc sulphate-barium hydroxide. Separation is achieved on a CN reversed-phase column, using a mobile phase of phosphate buffer (pH 4.5)-acetonitrile (90:10, v/v). At a flow-rate of 1.5 ml/min, the analysis time is 30 min. The limit of detection (ultraviolet, 210 nm) for ethylmorphine and its metabolites is 0.5 micrograms/ml. 相似文献
2.
David Hoff 《Journal of Mathematical Fluid Mechanics》2005,7(3):315-338
We prove the global existence of weak solutions of the Navier–Stokes equations of compressible flow in a half-space with the boundary condition proposed by Navier: the velocity on the boundary is proportional to the tangential component of the stress. This boundary condition allows for the determination of the scalar function in the Helmholtz decomposition of the acceleration density, which in turn is crucial in obtaining pointwise bounds for the density. Initial data and solutions are small in energy-norm with nonnegative densities having arbitrarily large sup-norm. These results generalize previous results for solutions in the whole space and are the first for solutions in this intermediate regularity class in a region with a boundary. 相似文献
3.
A data set of 29 experimentally determined Newby shifts in rare-earth nuclei is examined for the reliability of each values.
Using this data set, Newby shifts are obtained which are free from the Coriolis and the particle-particle coupling effects.
These new empirical values help resolve the failure of a recently proposed rule for the sign of the Newby shift in the {5/2[413]p − 5/2[642]n} configuration of160Tb and the {5/2[402]p − 5/2[512]n} configuration of174Lu. Also the Newby shifts are significantly modified in two other cases namely the {1/2[411]p − 1/2[521]n} configuration in168Tm and the {1/2[541]p − 1/2[521]n} configuration in172Lu. Only marginal changes are seen in the rest of the cases in the rare-earth nuclei. 相似文献
4.
We describe a modification of transverse pore gradient gel electrophoresis in which pore size is regulated by crosslinker proportion (%C) rather than by total monomer concentration (%T). We electrophoresed plasma lipoprotein [a] transversely across linear N,N'-methylenebisacrylamide gradients and measured mobility as a function of %C. This method allows for the simultaneous assessment of pore sizes generated over a wide range of crosslinker proportions. 相似文献
5.
The heats of reaction of tolueneMo(CO)3 with a series of phosphines and phosphites have been measured by solution calorimetry. The order of stability toward formation of fac-(PR3)3Mo(CO)3 in THF solution is: P(OCH3)3s> PMe3 > PnBu3 > PMe2Ph> PEt3 > triphos> P(OPh)3 > PMePh2 > PPh3 > PCl3 and spans a range of 25 kcal/mol reflecting individual bond strength differences up to 8 kcal/mol. The bulky phosphines PCy3 and PtBu3 react with tolueneMo(CO)3 in THF, but 30–40 kcal/mol less heat is evolved in these reactions than with the other phosphines and phosphites. The coordinately unsaturated five-coordinate complexes (PR3)2Mo(CO)3 are proposed as the reaction products. The importance of both steric and electronic factors in the Mo---P bond is discussed. 相似文献
6.
Reaction of HMo(CO)3C5H5 and Sn(C5H5)2 produces the tin hydride HSn[Mo(CO)3C5H5]3 (I). Reaction of I with CCl4, CHCl3, or CH2Cl2 gives ClSn[Mo(CO)3C5H5]3 (II). With hydrogen chloride the hydride I reacts to produce the dichloride Cl2Sn[Mo(CO)3C5H5]2. The first step in this reaction is cleavage of the SnH bond to produce the chloride II. The hydride I reacts with acetic acid to produce the diacetate (CH3COO)2Sn[Mo(CO)3C5H5]2. 相似文献
7.
J AliaMatysik C Soede-Huijbregts M Baldus J Raap J Lugtenburg P Gast H J van Gorkom A J Hoff H J de Groot 《Journal of the American Chemical Society》2001,123(20):4803-4809
Low-temperature 15N and 13C CP/MAS (cross-polarization/magic angle spinning) NMR has been used to analyze BChl-histidine interactions and the electronic structure of histidine residues in the light-harvesting complex II (LH2) of Rhodopseudomonas acidophila. The histidines were selectively labeled at both or one of the two nitrogen sites of the imidazole ring. The resonances of histidine nitrogens that are interacting with B850 BChl a have been assigned. Specific 15N labeling confirmed that it is the tau-nitrogen of histidines which is ligated to Mg2+ of B850 BChl molecules (beta-His30, alpha-His31). The pi-nitrogens of these Mg2+-bound histidines were found to be protonated and may be involved in hydrogen bond interactions. Comparison of the 2-D MAS NMR homonuclear (13C-13C) dipolar correlation spectrum of [13C6,15N3]-histidines in the LH2 complex with model systems in the solid state reveals two different classes of electronic structures from the histidines in the LH2. In terms of the 13C isotropic shifts, one corresponds to the neutral form of histidine and the other resembles a positively charged histidine species. 15N-13C double-CP/MAS NMR data provide evidence that the electronic structure of the histidines in the neutral BChl a/His complexes resembles the positive charge character form. While the Mg...15N isotropic shift confirms a partial positive charge transfer, its anisotropy is essentially of the lone pair type. This provides evidence that the hybridization structure corresponding to the neutral form of the imidazole is capable of "buffering" a significant amount of positive charge. 相似文献
8.
Belz J Cousins RD Diwan MV Eckhause M Ecklund KM Hancock AD Highland VL Hoff C Hoffmann GW Irwin GM Kane JR Kettell SH Klein JR Kuang Y Lang K Martin R May M McDonough J Molzon WR Riley PJ Ritchie JL Schwartz AJ Trandafir A Ware B Welsh RE White SN Witkowski MT Wojcicki SG Worm S 《Physical review letters》1996,76(18):3277-3280
9.
I. Alfter E. Bodenstedt B. Hamer J. van den Hoff W. Knichel H. Münning S. Piel R. Sajok J. Schüth 《Zeitschrift für Physik A Hadrons and Nuclei》1993,345(3):273-283
Theg-factors of the four lowest states of the ground state rotational band of158Dy have been determined asg(2 1 + )=+0.362(23),g(4 1 su+ )=+0.340(20),g(6 1 su+ )=+0.207(36) andg(8 1 su+ )=+0.21(11). Theg-factors of the 2+ and 4+ states were measured by the IPAC method with radioactive samples of 2.4 h158Er in external magnetic fields. To investigate the higher states, for the first time an on-line γ—γ IPAC experiment was performed with the reaction156Gd(α, 2n)158Dy by use of the static hyperfine field of DyGd. 相似文献
10.
Calculations on a system consisting of three electron spins and one nuclear spin are presented and their implications for bacterial photosynthesis discussed. Comparison with experimental measurements of electron spin polarization in pre-reduced photosynthetic reaction centres leads to conclusion that the exchange interaction within the primary radical pair is positive and less than 0.8 mT when the g values of the photoinduced radicals are taken to be those measured for the isolated radical species. 相似文献