Mechanism for resonant O electron stimulated desorption from condensed O2. Non-adiabatic transitions and dynamics

Absolute kinetic energy distributions and yields associated with ground state ³P and excited state ¹D oxygen atoms have been obtained for O⁻ anion electron stimulated desorption from condensed O₂ in the electron energy range 6–15 eV. The observed yields are understood as resulting essentially from dissociative electron attachment reactions via the two lowest ²Σ⁺_g O⁻₂ resonance states through adiabatic and non-adiabatic transitions to the limits O⁻(²P) + O(³P) and O⁻(²P) + O(¹D). The kinetic energy distributions show the prominent role of electron multiple collision processes and post-dissociation interactions of the O⁻ anions in the condensed phase.     

Reaction and scattering in cold electron collisions

Experimental data are presented for the scattering of electrons by CCl4 between 8 and 200 meV impact energy. These results are used in conjunction with data for the reactive process, yielding Cl-, to study the low energy behavior of a system which simultaneously displays both reactive and elastic scattering channels. Phase shifts are derived and illustrate how channel competition develops as the energy falls. This behavior and the involvement of vibronic effects at impact energies above approximately 30 meV pose a challenge to theory.     

Positive-ionization decay of the carbon k-shell excited negative-ion resonance in co

The resonant state CO-(Cls)^-1 (2pπ)². first reported by King has been observed to decay by multiple Auger effect in all the positive-ionization channels of CO. The relative abundances for the resonant formation of CO⁺. CO²⁺. C⁺. O⁺, C²⁺ ions have been measured. the decay to neutral states by normal Auger transitions is observed in the (O- + C⁺ ion-pair formation.     

Virtual state scattering with cold electrons: para-xylene and para-difluorobenzene

The scattering of electrons with kinetic energies down to a few meV by para-xylene and para-difluorobenzene has been observed experimentally with an electron beam energy resolution of 0.95 to 1.5 meV (full width half maximum). At low electron energies the collisions can be considered as cold scattering events because the de Broglie wavelength of the electron is considerably larger than the target dimensions. The scattering cross sections measured rise rapidly at low energy due to virtual state scattering. The nature of this scattering process is discussed using s- and p-wave phase shifts derived from the experimental data. Scattering lengths are derived of, respectively, -9.5+/-0.5 and -8.0+/-0.5 a.u. for para-xylene and para-difluorobenzene. The virtual state effect is interpreted in terms of nuclear diabatic and partially adiabatic models, involving the electronic and vibronic symmetries of the unoccupied orbitals in the target species. The concept of direct and indirect virtual state scattering is introduced, through which the present species, in common with carbon dioxide and benzene, scatter through an indirect virtual state process, whereas other species, such as perfluorobenzene, scatter through a direct process.     

Interaction of a laser with a qubit in thermal motion and its application to robust and efficient readout

We present a detailed theoretical and experimental study on the optical control of a trapped-ion qubit subject to thermally induced fluctuations of the Rabi frequency. The coupling fluctuations are caused by thermal excitation on three harmonic oscillator modes. We develop an effective Maxwell–Boltzmann theory which leads to a replacement of several quantized oscillator modes by an effective continuous probability distribution function for the Rabi frequency. The model is experimentally verified for driving the quadrupole transition with resonant square pulses. This allows for the determination of the ion temperature with an accuracy of better than 2% of the temperature pertaining to the Doppler cooling limit T _D over a range from 0.5T _D to 5T _D . The theory is then applied successfully to model experimental data for rapid adiabatic passage (RAP) pulses. We apply the model and the obtained experimental parameters to elucidate the robustness and efficiency of the RAP process by means of numerical simulations.     

Rotational excitation of H2O by cold electrons

Experimental data are presented for the scattering of electrons by H2O between 17 and 250 meV impact energy. These results are used in conjunction with a generally applicable method, based on a quantum defect theory approach to electron-polar molecule collisions, to derive the first set of data for state-to-state rotationally inelastic scattering cross sections based on experimental values.