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1.
Nataliia Yu. Strutynska Marina A. Bondarenko Ivan V. Ogorodnyk Igor V. Zatovsky Nikolay S. Slobodyanik Vyacheslav N. Baumer Anna N. Puzan 《Crystal Research and Technology》2015,50(7):549-555
The interaction in the molten system Rb2O‐P2O5‐TiO2‐NiO was investigated at different molar ratios Rb/P = 0.5‐1.3, fixed Ti/P = 0.15, Ti/Ni = 1.0 at temperature range 1073–953 K. The conditions of formation of complex phosphates RbTi2(PO4)3, Rb2Ni0.5Ti1.5(PO4)3 and RbNiPO4 have been determined. The new phosphate Rb2Ni0.5Ti1.5(PO4)3 (space group P213, a = 9.9386(2) Å) has been obtained and investigated by the single crystal X‐ray diffraction and FTIR‐spectroscopy. It has langbeinite‐like structure, that is built up from mixed (Ni/Ti)O6‐octahedra and РО4‐tetrahedra. Rubidium atoms are located in closed cavities of 3D‐framework. 相似文献
2.
Igor V. Zatovsky Nataliya Yu. Strutynska Nikolay S. Slobodyanik Oleg V. Shishkin 《Journal of solid state chemistry》2011,184(3):705-711
The crystallization of complex phosphates from the melts of Cs2O-P2O5-CaO-MIII2O3 (MIII—Al, Fe, Cr) systems have been investigated at fixed value Cs/P molar ratios equal to 0.7, 1.0 and 1.3 and Са/Р=0.2 and Ca/МIII=1. The fields of crystallization of CsCaP3O9, β-Ca2P2O7, Cs2CaP2O7, Cs3CaFe(P2O7)2, Ca9MIII(PO4)7 (MIII—Fe, Cr), Cs0.63Ca9.63Fe0.37(PO4)7 and CsCa10(PO4)7 were determined. Obtained phosphates were investigated using powder X-ray diffraction and FTIR spectroscopy. Novel whitlockite-related phases CsCa10(PO4)7 and Cs0.63Ca9.63Fe0.37(PO4)7 have been characterized by single crystal X-ray diffraction: space group R3c, a=10.5536(5) and 10.5221(4) Å, с=37.2283(19) and 37.2405(17) Å, respectively. 相似文献
3.
Nataliya Yu. Strutynska Vyacheslav N. Baumer Igor V. Zatovsky Artem A. Babaryk Nikolay S. Slobodyanik 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(4):i39-i41
The complex phosphate tricaesium calcium iron bis(diphosphate), Cs3CaFe(P2O7)2, has been prepared by the flux method. Isolated [FeO5] and [CaO6] polyhedra are linked by two types of P2O7 groups into a three‐dimensional framework. The latter is penetrated by hexagonal channels along the a axis where three Cs atoms are located. Calculations of caesium Voronoi–Dirichlet polyhedra give coordination schemes for the three Cs atoms as [8 + 3], [9 + 1] and [9 + 4]. The structure includes features of both two‐ and three‐dimensional frameworks of caesium double pyrophosphates. 相似文献
4.
Igor V. Zatovsky Nikolay S. Slobodyanik V. I. Ivanenko Yu. S. Oseledchik V. Yu. Letsenko Tetiana I. Ushchapivska 《Crystal Research and Technology》2016,51(2):178-182
Solid solutions KTi1‐XHfXOPO4 (х = 0.008 – 0.107) possessing the KTiOPO4 structure, have been synthesized in molten system K2O‐P2O5‐TiO2‐HfF4. The crystal growth experiment of Hf‐doped KTP crystal has been reported. The X‐ray powder diffraction data and chemical analysis are also presented. It has been shown that KTiOPO4 crystal structure slightly changes when Hf incorporates into the framework. Transmission/absorption spectra of KTi0.974Hf0.026OPO4 crystals have been recorded. The incorporation of Hf ions shifts the optical absorption edge in the UV‐visible spectrum towards the long‐wavelength region with absorption near 387 nm. 相似文献
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6.
V. I. Ivanenko I. V. Zatovsky N. S. Slobodyanik P. G. Nagornyi V. N. Baumer 《Crystal Research and Technology》2008,43(4):355-361
Zirconium‐doped KTiOPO4 (KTP) crystals were grown using a high temperature flux method in the K2O‐P2O5‐TiO2‐ZrF4 system. The dopant content in the single crystals with general composition KTi1‐xZrxOPO4 (where x = 0 – 0.026) strongly depends on zirconium concentration in the homogeneous melts. AES‐ICP method and X‐ray fluorescence analysis were used to determine the composition of the obtained crystals. Phase analyses of the products were performed using the powder XRD. The structures of KTiOPO4 containing different quantities of Zr were refined on the basis of single crystal XRD data. Applying ZrF4 precursor for zirconium injection into the flux allowed growing the zirconium‐doped KTP crystals at 930–750°C. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
7.
V.V. Nosenko I.P. Vorona S.S. Ishchenko N.P. Baran I.V. Zatovsky N.A. Gorodilova V.Yu. Povarchuk 《Radiation measurements》2012,47(10):970-973
Effect of pre-annealing of synthetic hydroxyapatite (HAP) on properties of γ- and UV- induced NO32- centers was studied by electron paramagnetic resonance (EPR). Nitrate-containing hydroxyapatite powders ((N)HAP)) and the powders with an admixture of carbonate and nitrate ions ((C,N)HAP) were annealed in the temperature range Tann = 20 °C ? 600 °C before irradiation. It was found that pre-annealing of (N)HAP samples changes the parameters of NO32- centers while no changes took place in (C,N)HAP. Moreover, at the pre-annealing temperatures Tann > 200 °C two new NO32- centers were observed in (N)HAP samples; they are characterized by larger value of A⊥ (3.67 and 4.41 mT) as compared to the known centers. It was also found that the dependence of NO32- centers amount on Tann is non-monotonous in both types of samples. Presumably this is caused by the escape of water molecules from HAP during the annealing and essential modification of the defect subsystem of HAP. 相似文献
8.
Ivan V. Ogorodnyk Igor V. Zatovsky Vyacheslav N. Baumer 《Journal of solid state chemistry》2006,179(11):3461-3466
New complex phosphates of the general formula K2M0.5Ti1.5(PO4)3 (M=Mn, Co) have been obtained from the melting mixture of KPO3, K4P2O7, TiO2 and CoCO3·mCo(OH)2 or Mn(H2PO4)2 by means of a flux technique. The synthesized phosphates have been characterized by the single-crystal X-ray diffraction and the FTIR-spectroscopy. The compounds crystallize in the cubic system with the space group P213 and cell parameters a=9.9030(14) Å for K2Mn0.5Ti1.5(PO4)3 and a=9.8445(12) Å for K2Co0.5Ti1.5(PO4)3. Both phosphates are isostructural with the langbeinite mineral and contain four formula unit K2M0.5Ti1.5(PO4)3 per unit cell. The structure can be described using [M2(PO4)3] framework composed of two [MO6] octahedra interlinked via three [PO4] tetrahedra. The Curie-Weiss-type behavior is observed in the magnetic susceptibility. 相似文献
9.
Junzhi Li Junming Cao Xifei Li Junhua Hu Yaohui Zhang Hirbod Maleki Kheimeh Sari Chunxiao Lv IgorVZatovsky Wei Han 《Journal of Energy Chemistry》2021,(4):420-427
The carbon materials as anode electrodes have been widely studied for potassium ion batteries(PIBs).However,the large size of potassium ions prevents their intercalation/deintercalation,resulting in poor storage behaviors.Herein,a novel design of N/S codoped hierarchical carbonaceous fibers(NSHCF)formed from nanosheets self-assembled by catalyzing Aspergillus niger with Sn is reported.The asprepared NSHCF at 600℃(NSHCF-600)exhibits a high reversible capacity of 345.4 m Ah g-1 at 0.1 A g-1 after 100 cycles and an excellent rate performance of 124.5 m Ah g-1 at 2 A g-1.The excellent potassium storage performance can be ascribed to the N/S dual-doping,which enlarges interlayer spacing(0.404 nm)and introduces more defects.The larger interlayer spacing and higher pyridinic N active sites can promote K ions diffusion and storage.In addition,the ex situ transmission electron microscopy reveals the high reversibility of potassiation/depotassiation process and structural stability. 相似文献
10.
Ivan V. Ogorodnyk Igor V. Zatovsky Vyacheslav N. Baumer 《Journal of solid state chemistry》2006,179(12):3681-3687
The single crystals of caesium magnesium titanium (IV) tri-oxo-tetrakis-diphosphate bis-monophosphate, Cs3.70Mg0.60Ti2.78(TiO)3(P2O7)4(PO4)2, crystallize in sp. gr. P-1 (No. 2) with cell parameters a=6.3245(4), b=9.5470(4), c=15.1892(9) Å, α=72.760(4), β=85.689(5), γ=73.717(4), z=1. The titled compound possesses a three-dimensional tunnel structure built by the corner-sharing of distorted [TiO6] octahedra, [Ti2O11] bioctahedra, [PO4] monophosphate and [P2O7] pyrophosphate groups. The Cs+ cations are located in the tunnels. The partial substitution of Ti positions with Mg atoms is observed. The negative charge of the framework is balanced by Cs cations and Mg atoms leading to pronounced concurrency and orientation disorder in the [P2O7] groups, which coordinate both. 相似文献