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1.
Watanabe Sou Senzaki Tatsuya Shibata Atsuhiro Nomura Kazunori Takeuchi Masayuki Nakatani Kiyoharu Matsuura Haruaki Horiuchi Yusuke Arai Tsuyoshi 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(3):1273-1277
Journal of Radioanalytical and Nuclear Chemistry - Extraction chromatography flow-sheet employing octyl(phenyl)-N,N-diisobutylcarbonoylmethylphosphine oxide and bis(2-ethylhexyl) hydrogen phosphate... 相似文献
2.
Direct Addition of Amides to Glycals Enabled by Solvation‐Insusceptible 2‐Haloazolium Salt Catalysis
Yuya Nakatsuji Yusuke Kobayashi Yoshiji Takemoto 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(40):14253-14257
The direct 2‐deoxyglycosylation of nucleophiles with glycals leads to biologically and pharmacologically important 2‐deoxysugar compounds. Although the direct addition of hydroxyl and sulfonamide groups have been well developed, the direct 2‐deoxyglycosylation of amide groups has not been reported to date. Herein, we show the first direct 2‐deoxyglycosylation of amide groups using a newly designed Brønsted acid catalyst under mild conditions. Through mechanistic investigations, we discovered that the amide group can inhibit acid catalysts, and the inhibition has made the 2‐deoxyglycosylation reaction difficult. Diffusion‐ordered two‐dimensional NMR spectroscopy analysis implied that the 2‐chloroazolium salt catalyst was less likely to form aggregates with amides in comparison to other acid catalysts. The chlorine atom and the extended π‐scaffold of the catalyst played a crucial role for this phenomenon. This relative insusceptibility to inhibition by amides is more responsible for the catalytic activity than the strength of the acidity. 相似文献
3.
Guangrui Chen Yuxing Yan Dr. Jie Wang Prof. Yong Sik Ok Guiyuan Zhong Prof. Bu Yuan Guan Prof. Yusuke Yamauchi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(44):19831-19836
Mesoporous core–shell nanostructures with controllable ultra-large open channels in their nanoshells are of great interest. However, soft template-directed cooperative assembly to mesoporous nanoshells with highly accessible pores larger than 30 nm, or even above 50 nm into macroporous range, remains a significant challenge. Herein we report a general approach for precisely tailored coating of hierarchically macro-/mesoporous polymer and carbon shells, possessing highly accessible radial channels with extremely wide pore size distribution from ca. 10 nm to ca. 200 nm, on diverse functional materials. This strategy creates opportunities to tailor the interfacial assembly of irregular mesostructured nanounits on core materials and generate various core–shell nanomaterials with controllable pore architectures. The obtained Fe,N-doped macro-/mesoporous carbon nanoshells show enhanced electrochemical performance for the oxygen reduction reaction in alkaline condition. 相似文献
4.
5.
The potential of an N-Troc-protected sialic acid donor, equipped with phenylsulfenyl functionality as a leaving group, has been explored. As a result, the entitled donor was proven to be highly reactive and to have broad applicability toward the synthesis of variant sialo-glycans, which have N-glycolyl, de-N-acetyl, 1,5-lactam and 8-O-sulfo sialic acid analogs. 相似文献
6.
S.N. Abdulmadjid M.M. Suliyanti K.H. Kurniawan T.J. Lie M. Pardede R. Hedwig K. Kagawa M.O. Tjia 《Applied physics. B, Lasers and optics》2006,82(1):161-166
We report in this paper the results of an experimental study on hydrogen analysis of solid samples in high pressure helium
ambient gas employing the basic scheme of laser induced breakdown spectroscopy (LIBS). It is shown that the metastable excited
state of helium atom can be utilized to induce delayed excitation of the ablated hydrogen atoms, and thereby avoid the Stark
broadening effect as well as overcoming the undesirable mismatch effect, which are responsible for inefficient excitation
respectively. It is further demonstrated that for samples of high boiling-point materials such as zircaloy, successful hydrogen
analysis can be achieved by a newly introduced double excitation technique employing single laser realized in a modified configuration
of the conventional LIBS method.
PACS 51-52 相似文献
7.
The pulse lasers, YAG-, CO2-, and N2-lasers, are examined for use in the cleaning of glass. Cleaning is found to be due to the evaporation and sputtering of stains on the glass by the heat energy of the laser light. Only the N2 laser can be used for the cleaning of the exit surface of the glass (the opposite side to the laser). A laser with a high peak power of about 106J/s and short-pulse duration below 100 ns is found to be necessary in practice. 相似文献
8.
(Triisopropylsilyl)acetaldehyde dimethyl acetal (TIPS-ADMA) was synthesized from chlorotriisopropylsilane in three steps. Cyclic and acyclic 1,2-diols can be transformed to (triisopropylsilyl)ethylidene acetals (TIPS-AA). Removal of the acetal by LiBF4 regenerates the starting diol in excellent yield even in the presence of an acetonide of 1,2-diol. The TIPS-AA group can survive under the deprotection conditions of the acetonide in acetic acid at 80 °C. Selective protection of 2,3- and 4,6-diols for O-methyl d-mannoside with TIPS-ADMA and selective deprotection of the acetals have been achieved. 相似文献
9.
The simultaneous removal of NO? and soot particulates in an oxidizing atmosphere is desirable for the aftertreatment of diesel exhausts. After briefly reviewing the development of catalysts for reactions involving carbons, our recent studies on the simultaneous NO?–soot removal using perovskite-related and spinel-type oxides are described. 相似文献
10.
Masafumi Unno Hiroyuki Murakami Satoshi Kagawa Hideyuki Matsumoto 《Silicon Chemistry》2007,3(3-4):195-198
Two new silanols bearing very bulky silyl groups, (i-Pr3
Si)3SiOH and (t − BuMe2Si)3SiOH were prepared by peracidoxidation of their respective silanes. The X − ray crystallographic analysis revealed that (t − BuMe2Si)3 SiOH forms a dimeric structure with hydrogen bonding, while (i − Pr3 Si)3 SiOH exists as a monomer in the crystal. The effects of the size of the substituents as well as the reactivity of these silanols
are discussed. 相似文献