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1.
Addition of functionalized zinc-copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X-ray diffraction analysis. 相似文献
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3.
Iradj Ouveysi Andrew Wirth Annie Yeh Osman Oğuz 《Annals of Operations Research》2003,124(1-4):285-293
We consider the problem of providing a minimum cost multi-service network subject to one link failure scenarios. We assume our network is fully meshed and demand is satisfied by using direct or two hop-paths. We provide a large scale linear programming formulation and propose and test two effective heuristics. 相似文献
4.
Ching-Cherng Sun You-Nian Lin Shih-Po Yeh Wei-Chia Su Yuh Ouyang 《Optics & Laser Technology》2002,34(7):523-526
High longitudinal selectivity of the shifting multiplexing with spherical reference wave is proposed and demonstrated. A simplified method based on wave optics is used for calculating the selectivity, and the result fits well the experimental measurement. Under the paraxial condition, a simple formula for the longitudinal selectivity is introduced. With use of an object lens with effective NA=0.817, we obtain that an FWHM of selectivity is as small as 1 μm. 相似文献
5.
The Wiener (Sum of All Distances) Index for three out of the four classes of hexagonal models or regular planar hex-patterns used to model graphite and similar structures have been known for a few years. In this paper we find the Wiener Index for the Crown or Beehive hexagonal model. 相似文献
6.
Chien Lun Hung Yi Sheng Yeh 《International Journal of Infrared and Millimeter Waves》2003,24(12):2025-2041
Coaxial cavities are used in high power gyrotrons as the beam-wave interaction structure. Much research has been devoted to their mode selective properties. A coaxial cavity lacks a sharp boundary at its open end, so it has some physical features that can only be observed using a spectral model, such as frequency-dependent field profiles and mode overlapping effects. These properties are important since cold tests are usually conducted in the frequency domain. This study applies the incident/reflected wave boundary condition to the wave equation of a weakly irregular coaxial waveguide. The resistivity of the wall is considered in the analysis. Calculations reveal that the fixed-position spectrum yields an uncertain resonant frequency and quality factor. Although the maximum-field spectrum can uniquely determine the properties of the coaxial cavity, the resonant frequency obtained using the maximum-field spectral model is inconsistent with that obtained using the temporal model. The field-energy spectrum explains the low Q nature of the coaxial cavity. Moreover, resonant frequencies evaluated using the field-energy spectrum agree precisely with those evaluated using the temporal model. 相似文献
7.
Jia‐Yuh Sheu Yeh‐Long Chen Cherng‐Chyi Tzeng Shu‐Lin Hsu Kuo‐Chang Fang Tai‐Chi Wang 《Helvetica chimica acta》2003,86(7):2481-2489
Certain 1‐ethyl‐ and 1‐aryl‐6‐fluoro‐1,4‐dihydroquinol‐4‐one derivatives were synthesized and evaluated for antimycobacterial and cytotoxic activities. Preliminary results indicated that, for 1‐aryl‐6‐fluoroquinolones, both 7‐(piperazin‐1‐yl)‐ and 7‐(4‐methylpiperazin‐1‐yl) derivatives, 9b and 11a , are able to completely inhibit the growth of M. tuberculosis at a concentration of 6.25 μg/ml, while the 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl] derivative 13 exhibits only 31% growth inhibition at the same concentration. For 1‐ethyl‐6‐fluoroquinolones, both 7‐[4‐(2‐oxopropyl)piperazin‐1‐yl]‐ and 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl]‐derivatives, 2a and 2b , respectively, show complete inhibition, while their 2‐iminoethyl and substituted phenyl counterparts 3a and 2c are less active. In addition, the 6,8‐difluoro derivative was a more‐favorable inhibitor than its 6‐fluoro counterpart ( 2b vs. 2d ). These results deserve full attention especially because 2a, 2b, 9b , and 11a are non‐cytotoxic at a concentration of 100 μM . Furthermore, compound 9b proved to be a potent anti‐TB agent with selective index (SI)>40 and an EC90 value of 5.75 μg/ml. 相似文献
8.
It is known that there exists an equivalence relation between the adjacency matrix of graph theory and the Hückel matrix of Hückel molecular orbital theory. This paper presents some useful methods which allow us to systematically find eigenvalues and eigenvectors of various classes of graphs without calculating characteristic polynomials. Results obtained from this study give insight into the topological studies of molecular orbitals.Dedicated to Professor Frank Harary on the occasion of his 70th birthday. 相似文献
9.
复合载荷下圆底扁球壳非线性稳定性 总被引:3,自引:2,他引:1
本文采用半解析方法研究在中心分布载荷及中心集中力联合作用下,圆底扁球壳的非线性稳定性问题.避免了求近似解析解时繁重的人工计算,而p-W_m特征关系仍可由显式表达. 相似文献
10.
We prepared two vinyl copolymers P1 and P2 containing pendant distyrylbenzene and aromatic 1,3,4‐oxadiazole derivatives, respectively, from their precursor poly(styrene‐ran‐4‐vinylbenzyl chloride) (Mw = 11,400, PDI = 1.18), which had been prepared by the controlled radical polymerization (RAFT). Two main chain polymers containing similar isolated distyrylbenzene ( P3) and aromatic 1,3,4‐oxadiazole ( P4 ) chromophores were also synthesized for comparative study. The resulted copolymers ( P1 – P4 ) are soluble in common organic solvents and are basically amorphous materials with 5% weight‐loss temperature higher than 360 °C. The PL spectral results reveal that the architecture of P1 prevents the formation of inter‐ or intramolecular interaction. The HOMO and LUMO levels of P2 , estimated from cyclic voltammetric data, are ?5.96 and ?3.81 eV, respectively, which are much lower than those of P1 (?5.12 and ?3.11 eV). The emission of blend from P1 and P2 are contributed mainly from distyrylbenzene fluorophore (~450 nm) owing to efficient energy transfer. Moreover, the blend exhibits three kinds of redox behavior depending on their weight ratios. The luminance and current efficiency of the EL device lpar;ITO/PEDOT/ MEH ‐ PPV + P2 /Al) are 503 cd/m2 and 0.11 cd/A, which can be improved to 1285 cd/m2 and 0.44 cd/A, respectively, as the weight ratio of P2 increases from 0 to 20%. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5362–5377, 2006 相似文献