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1.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
2.
Richard Kotek Kyeong Pang Ben Schmidt Alan Tonelli 《Journal of Polymer Science.Polymer Physics》2004,42(23):4247-4254
Poly(ethylene isophthalate) (PEI) was synthesized for this research with essentially a condensation polymerization of isophthalic acid and ethylene glycol catalyzed by zinc acetate and antimony trioxide. Several samples were obtained, and their characteristics were observed and compared with poly(ethylene terephthalate) (PET). The synthesized PEI samples were chemically identified by 1H NMR. Thermal analysis with differential scanning calorimetry (DSC) yielded results that indicate the samples were primarily amorphous, with a glass‐transition temperature of 55–60 °C. Molecular weights of these PEI samples were also obtained through intrinsic viscosity measurements (Mark–Houwink equation). Molecular weights varied with conditions of the polymerization, and the highest molecular weight achieved was 21,000 g/mol. Finally, the diffusion coefficient, solubility, and permeability of CO2 gas in PEI were measured and found to be substantially lower than in PET, as anticipated from their isomeric chemical structures. This is because in PET the phenyl rings are substituted in the para (1,4) positions, which allows for their facile flipping, effectively permitting gases to pass through. However, the meta‐substituted phenyl rings in PEI do not permit such ring flipping, and thus PEI may be more suitable for barrier applications. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4247–4254, 2004 相似文献
3.
Haishan Bu Yanwan Pang Dandan Song Tongyin Yu T. M. Voll George Czornyj B. Wunderlich 《Journal of Polymer Science.Polymer Physics》1991,29(2):139-152
Various approaches to the preparation and verification of single-molecule single crystals are discussed for polyethylene and poly (oxyethylene). Analytic tools are electron microscopy, electron diffraction, and differential scanning calorimetry. The main difficulty in producing a single-molecule single crystal is to keep crystals from joining during growth. 相似文献
4.
Numerical analysis for stochastic age-dependent population equations with Poisson jumps 总被引:1,自引:0,他引:1
In this paper, stochastic age-dependent population equations with Poisson jumps are considered. In general, most of stochastic age-dependent population equations with jumps do not have explicit solutions, thus numerical approximation schemes are invaluable tools for exploring their properties. The main purpose of this paper is to develop a numerical Euler scheme and show the convergence of the numerical approximation solution to the true solution. 相似文献
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In this paper, we give an application ofUV-decomposition method of convex programming to multiobjective programming, and offer a new algorithm for solving semi-infinite multiobjective programming. Finally, the superlinear convergence of the algorithm is proved. 相似文献
7.
Inexact Newton methods for the nonlinear complementarity problem 总被引:2,自引:0,他引:2
Jong-Shi Pang 《Mathematical Programming》1986,36(1):54-71
An exact Newton method for solving a nonlinear complementarity problem consists of solving a sequence of linear complementarity
subproblems. For problems of large size, solving the subproblems exactly can be very expensive. In this paper we study inexact
Newton methods for solving the nonlinear, complementarity problem. In such an inexact method, the subproblems are solved only
up to a certain degree of accuracy. The necessary accuracies that are needed to preserve the nice features of the exact Newton
method are established and analyzed. We also discuss some extensions as well as an application.
This research was based on work supported by the National Science Foundation under grant ECS-8407240. 相似文献
8.
Introduction and Applications of a Generalized Intermediate Entangled State Representation 下载免费PDF全文
We introduce a generalized intermediate entangled state representation |β〉Λ to study the energy spectrum of an electron in a uniform magnetic field and a harmonic potential through algebraic calculatiOn. We find that the degeneracy of the energy levels is disappeared due to the existence of the additional potential. We make it clear that the eigenfunction is just the expression of eigenvector, defined in n Fock space, in |β〉Λ representation. 相似文献
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