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1.
LetK be a quadratic Geld, and letR(N) be the number of integer ideals inK with norm at most AT. Letx with conductork be the quadratic character associated withK. Then |R(N)−NL(1,x)|⩽Bk
50/73
N
23/73(logN)461/146 forN ≥Ak, whereA andB are constants. ForN ≥Ak
c,C
sufficiently large, the factork
50/73 may be replaced by (d(k))4/73
k
46/73.
Dedicated to the memory of Professor K G Ramanathan 相似文献
2.
The reaction of two amidoximes 4 with ethyl orthoacetate in the presence of an acid catalyst gave triazine N-oxides 7 . A mechanism via a Beckmann rearrangement to a carbodiimide, followed by reaction with amidoxime and the ortho ester, is proposed. 相似文献
3.
4.
Watt A Thomsen E Meredith P Rubinsztein-Dunlop H 《Chemical communications (Cambridge, England)》2004,(20):2334-2335
We report a simple one pot process for the preparation of lead sulfide (PbS) nanocrystals in the conjugated polymer poly (2-methoxy-5-(2'ethyl-hexyloxy)-p-phenylene vinylene)(MEH-PPV), and we demonstrate electronic coupling between the two components. 相似文献
5.
Infrared spectra have been obtained in gas and crystalline phases for CH3NO2, CD3NO2, and CHD2NO2. A few Raman liquid measurements have also been made. The crystal spectra show the methyl group to be locked in conformation I, with isolated CH stretching frequencies 3065 (ν∥CH) and 3000 (ν⊥CH), respectively. In the gas phase, the bands due to νaCH3 and νaCD3 are split, the splitting being compatible with isolated frequencies of 3065 (ν∥CH) and 3006 (ν⊥CH) cm?1, respectively. These indicate a variation of 0.006 Å in bond length during internal rotation. The gas phase infrared band at 3028.7 cm?1 and the Raman liquid band at 3024 cm?1 in the spectra of CHD2NO2 represent averages of the frequencies during internal rotation. All calculations are performed with a potential function involving variations both in diagonal bond stretching, and in off-diagonal stretching interaction constants, proportional to cos2π, where π is the internal rotation angle.In the Appendix, vibrational assignments below 1600 cm?1 are examined. Product rule considerations and intensity changes upon deuteration lead to a conflict with the infrared gas phase band contour over the assignment of the rCD3 mode at 884 cm?1. This and other features in the gas phase spectra may arise from the internal rotation. 相似文献
6.
The Claisen rearrangement of α-(thioalkoxy)-esters provided access to substituted trans-1, 6-dimethylbicyclo[4.3.0]non-2-enes characteristic of the CD rings of the cucurbitanes. 相似文献
7.
In connection with studies leading to the total synthesis of taxodione1 (1), we required the tricyclic enone 3. We have previously described2 an AB→ABC approach to this intermediate which was flawed by a low yield in the penultimate closure of the C ring (2→3). We now wish to report an alternate synthesis of 3 which involves a BC→ABC approach for the construction of this tricyclic system. 相似文献
8.
A procedure for the conversion of 2-methoxy-ethoxymethyl (MEM) ethers to carboxylic esters employed ferric chloride (0.4 equivalents) and a carboxylic anhydride (14 equivalents) and exhibited selectivity for the MEM ether functionality in the presence of benzyl ethers. 相似文献
9.
Many antibiotics of the anthracycline family1 possess structures for which 3-methoxyphthalic anhydride (1) would be a suitable synthon2 in a total synthesis. A classic synthesis of (1) has employed 3-nitrophthalic acid3 but, in our hands, proceeded in low overall yield. Recent syntheses have utilized the Diels Alder reaction of dimethyl acetylenedicarboxylate (2) with 1-methoxy-1,3-cyclohexadiene,4 1,4-diacetoxybutadiene,5 2-acetoxyfuran,6 2-methoxyfuran7 or furan8 to obtain 3-hydroxyphthalic acid or a derivative. We now wish to report a convenient Diels-Alder synthesis of (1) from 3-methoxy-2-pyrone (3). 相似文献
10.
Agus R. Poerwoprajitno Dr. Lucy Gloag Dr. John Watt Steffen Cychy Dr. Soshan Cheong Dr. Priyank V. Kumar Dr. Tania M. Benedetti Chen Deng Dr. Kuang-Hsu Wu Dr. Christopher E. Marjo Dr. Dale L. Huber Dr. Martin Muhler Prof. Dr. J. Justin Gooding Prof. Dr. Wolfgang Schuhmann Prof. Dr. Da-Wei Wang Prof. Dr. Richard D. Tilley 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(36):15615-15620