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1.
Jacques Darriet Marc Drillon Gérard Villeneuve Paul Hagenmuller 《Journal of solid state chemistry》1976,19(3):213-220
The cationic ordering in the oxides which crystallize with the 6H structure gives rise to Ru5+Ru5+ pairs in (Ru2O9) clusters. The magnetic properties have been analyzed on the basis of the Heisenberg-Dirac-Van Vleck model: The d electrons are localized on each Ru5+ ion and interact strongly through antiferromagnetic exchange. The susceptibility curves agree with the H.D.V.V. model. The values of the exchange integrals have been determined by fitting the experimental values. 相似文献
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Etourneau J Ammar A Villesuzanne A Villeneuve G Chevalier B Whangbo MH 《Inorganic chemistry》2003,42(14):4242-4244
Electrical resistivity, magnetic susceptibility, and electron paramagnetic resonance measurements were carried out for cubic hexaboride KB(6), which is one electron short of completely filling its conduction band. It is found that KB(6) is not metallic and has localized spins. KB(6) exhibits a highly unusual hysteresis in the magnetic susceptibility below 100 K, which suggests that it undergoes a slow relaxation process. 相似文献
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R.S. Marjoribanks M.C. Richardson J. Delettrez S. Letzring W. Seka D.M. Villeneuve 《Optics Communications》1982,44(2):113-116
Preliminary experiments using an X-ray streak filter spectrometer employing a Au/CsI bifurcated photocathode to investigate the X-ray history of UV (350 nm) laser produced plasmas are reported. Novel use of the streak spectrometer permits a direct and precise fiducial record of the laser pulse to be made from specularly scattered laser light, in true streak time relative to the X-ray record. Initial data indicates a constant 700 eV temperature during the laser pulse; time-resolved particulars are compared to simulations made by the design code LILAC. 相似文献
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Dorin Dusciac Jean-Noël Chazalviel François Ozanam Philippe Allongue Catherine Henry de Villeneuve 《Surface science》2007,601(18):3961-3964
Direct grafting of organic monolayers on Si is of prime interest in order to give specific properties to a silicon surface. However, for microelectronics applications, this possibility is hampered by the limited stability of the grafted layers. It has been previously established that alkyl layers attached to Si surfaces through Si-C bonds become unstable at 250-300 °C, by desorption of alkenes. Changing the nature of the bonding to the surface might allow one to circumvent this desorption pathway and increase the layer stability. In our work, decanol and decyl aldehyde are reacted with the Si(1 1 1)-H surface at ∼100 °C during 20 h in order to obtain alkoxy monolayers. FTIR measurements performed in ATR geometry show that the grafted molecule surface coverage is on the order of 33% after reaction with decanol and 50% after reaction with decyl aldehyde. Characterization by AFM essentially reveals that the morphology of the grafted surfaces is unaffected as compared to that of Si-H surfaces. However, the edges of the terraces at alcohol-grafted surfaces exhibit some pitting, probably due to the presence of water in the grafting liquid. Thermal stability studies show that alkoxy chains progressively disappear from the Si surface between 200 and 400 °C. From the CH2/CH3 ratio in the CH region (2760-3070 cm−1), it appears that the chains undergo progressive dissociation by C-C bond breaking before their complete disappearance from the surface. Therefore, the thermal behaviour of alkoxy monolayers appears quite distinct from that of alkyl monolayers that tend to leave the surface in a much narrower temperature range (250-350 °C), essentially via breaking of the Si-C bonds. 相似文献
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Fleischer A Wörner HJ Arissian L Liu LR Meckel M Rippert A Dörner R Villeneuve DM Corkum PB Staudte A 《Physical review letters》2011,107(11):113003
We study electron correlation in sequential double ionization of noble gas atoms and HCl in intense, femtosecond laser pulses. We measure the photoelectron angular distributions of Ne+ relative to the first electron in a pump-probe experiment with 8 fs, 800 nm, circularly polarized laser pulses at a peak intensity of a few 10(15) W/cm2. Using a linear-linear pump-probe setup, we further study He, Ar, and HCl. We find a clear angular correlation between the two ionization steps in the sequential double ionization intensity regime. 相似文献
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Fernando P. Carvalho Jean-Pierre Villeneuve Chantal Cattini 《Trends in analytical chemistry : TRAC》1999,18(11):1005-664
A seaweed sample (Fucus sp.) was prepared, homogenised and distributed to laboratories worldwide as the IAEA-140 intercomparison material for the analysis of organochlorine compounds and petroleum hydrocarbons. A total of 80 laboratories from 51 countries reported results for this sample. The data sets reported by laboratories were evaluated statistically and the mean concentration values could be computed with 95% confidence limits for a large number of analytes. The accuracy of the analytical performance of each laboratory has been introduced by using Z-scores. The spread of results reported generally indicates that the accurate determination of many persistent organic pollutants, such as hexachlorobenzene, lindane, Aroclors or fluoranthene, is still difficult for many laboratories. The final results of this intercomparison exercise enable individual participants to assess their performance and, where necessary, to introduce appropriate modifications in their analytical procedures. Furthermore, as a series of statistical criteria was fulfilled for a number of compounds, the sample IAEA-140 can now be used as a reference material for quality control in the determination of chlorinated compounds and petroleum hydrocarbons in environmental samples. 相似文献
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M. Horvat L. Liang S. Azemard V. Mandić J.-P. Villeneuve M. Coquery 《Analytical and bioanalytical chemistry》1997,358(3):411-418
Due to the increased demand for new reference materials certified for total and methylmercury (MeHg) a sample of mussel homogenate (IAEA-142) has been prepared. Thirteen experienced laboratories reported results for total Hg of which 9 laboratories also reported results for MeHg content. Laboratories reporting MeHg results used various isolation techniques (solvent extraction, saponification, acid leaching, ion-exchange separation, and distillation) and detection systems (cold vapour atomic absorption spectrometry (CV AAS), cold vapour atomic fluorescence spectrometry (CV AFS), gas chromatography with electron capture detector (GC/ECD) and HPLC with CV AAS detector). In the case of total Hg, most of the laboratories used acid digestion, only two used alkaline dissolution, followed either by CV AAS or CV AFS. One laboratory used neutron activation analyses with radiochemical separation. The data received were in good agreement. The value for total Hg was certified to be 126 ng/g, with a 95% confidence interval from 119 to 132 ng/g. For MeHg the certified value of 47 ng/g expressed as Hg was assigned, with a 95% confidence interval from 43 to 51 ng/g. Stability testing has shown that both total and MeHg are stable if samples are stored in a dry and dark place at room temperature. The sample is now available as a certified reference material and is, in particular, useful for quality control measurements of Hg and MeHg in mussel samples at low concentration levels. 相似文献