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1.
Europium (Eu+) ions were confined in a Paul trap and detected by non-destructive method. Storage time of Eu+ ions achieved in vacuum was improved by orders of magnitude employing buffer gas cooling. The experimentally detected signal
was fitted to the ion response signal and the total number of ions trapped was estimated. It is found that the peak signal
amplitude as well as the product of FWHM and the peak signal amplitude is proportional to the total number of trapped ions.
The trapped ion secular frequency was swept at different rates and its effect on the absorption line profile was studied both
experimentally and theoretically. 相似文献
2.
3.
Summary A column chromatography was developed using a nonionic, polar adsorbent resin Amberlite XAD-7 for routine radiochemical separation of 67Ga from Zn and Cu. 7M HCl was found to be the optimum concentration for adsorption of 67Ga and elution of both Zn and Cu. Distilled water was used for elution of 67Ga from the column. The optimum flow rate of the solutions on to the column was 5 ml/min. The concentrations of Zn and Cu in the final product (30 ml), measured by a polarography method, were 2.0 and 0.5 ppm, respectively. A solvent extraction method, using diisopropyl ether/7M HCl system was also tested to perform the same separation and a comparison between the two methods was made. The radiochemical chromatographic separation system is simple in design and easy to operate for separations in a hot cell. 相似文献
4.
Muhammad Tariq Saqib Ali Muhammad Nawaz Tahir Nasir Khalid Jafir Hussain Shirazi 《Journal of the Iranian Chemical Society》2014,11(3):839-846
A series of six organotin(IV) carboxylates [Me2SnL2] (1), [n-Bu2SnL2] (2), [n-Oct2SnL2] (3), [Me3SnL] (4), n-Bu3SnL (5) and [Ph3SnL] (6), where L = 3-(4-cyanophenyl) acrylic acid have been synthesized and characterized by elemental analysis, FT-IR and NMR (1H, 13C). The complex (4) was also analyzed by single crystal X-ray analysis which showed distorted trigonal bipyramidal geometry with polymeric bridging behavior. The complexes 1–6 were screened for antimicrobial activities and cytotoxicity. The results showed significant activity with few exceptions. The catalytic activity of complexes was assessed in transesterification reaction of Brassica campestris oil (triglycerides) to produce biodiesel (fatty acid methyl esters). The results showed that triorganotin(IV) complexes exhibited good catalytic activity than their di-analogues. 相似文献
5.
Rahim Hekmatshoar Akram Rezaei S. Y. Shirazi Beheshtiha 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):2491-2496
Synthesis of substituted coumarin-3-carboxylic acid via Knoevenagel condensation of meldrum's acid with ortho-hydroxyaryl aldehydes in solventless system is described. 相似文献
6.
Fernando Castañeda Paul Silva M. Teresa Garland Ata Shirazi Clifford A. Bunton 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):2152-2168
The phosphonium ylidic diesters, methyl and ethyl isopropyl and, methyl and ethyl t-butyl triphenylphosphoranylidene malonates, 1a,b and 2a,b , respectively, have the syn-anti conformation in solution, as in the crystal, and the bulkier alkoxy group is oriented towards phosphorus. The 1 H NMR spectra show that in 1a,b , the isopropyl group is oriented towards the face of a phenyl group, consistent with π shielding in the 1 H signals, and examination of the 1 H coupled 13 C NMR spectra allows assignment of the acyl carbon signals. Computed bond lengths and angles for isolated molecules are similar to those in the crystal, and the geometry and the NMR spectra indicate extensive ylidic resonance. Estimated partial atomic charges on the ester oxygens are more negative when they are oriented towards, rather than away from, phosphorus. 相似文献
7.
Farnoush Mousavizadeh Seyed Yahya Shirazi Beheshtiha Reyhaneh Rahnamafar 《合成通讯》2014,44(10):1483-1491
A facile protocol for the one-pot, multicomponent reaction of indole, 4-hydroxycoumarin, and aromatic aldehydes was developed using copper octoate as an inexpensive, commercially available, and efficient catalyst. This highly selective reaction eliminates the formation of homodimeric by-products (bisindoles and biscoumarins) and selectively results in the formation of heterodimeric adducts containing both indole and coumarin heterocycles. 相似文献
8.
P Kelle H Schneider C Raschke H Shirazi 《The Journal of the Operational Research Society》2013,64(3):313-325
Since highway improvement project selection requires screening thousands of road segments with respect to crashes for further analysis and final project selection, we provide a two-step project selection methodology and describe an application case to demonstrate its advantages. In the first step of the proposed methodology, we will use odds against observing a given crash count, injury count, run-off road count and so on as measures of risk and a multi-criteria pre-selection technique with the objective to decrease the number of prospective improvement locations. In the second step, the final project selection is accomplished based on a composite efficiency measure of estimated cost, benefit and hazard assessment (odds) under budget constraints. To demonstrate the two-step methodology, we will analyze 4 years of accident data at 23?000 locations where the final projects are selected out of several hundred of potential locations. 相似文献
9.
Shirazi Muhammad Faizan Wijesinghe Ruchire Eranga Ravichandran Naresh Kumar Kim Pilun Jeon Mansik Kim Jeehyun 《Optical Review》2017,24(2):219-225
Optical Review - A dual-path handheld system is proposed for cornea and retina imaging using spectral domain optical coherence tomography. The handheld sample arm is designed to acquire two images... 相似文献
10.
This work is an investigation on the roots of chaotic attitudinal motion in a class of asymmetrical gyrostat satellites. The result shows that for a class of Kelvin type gyrostat satellite, there is an equivalent rigid spinning satellite with the same attitude dynamics. Finding some constants of motion and eliminating the cyclic coordinates, the rotational kinetic energy is changed to a quadratic form and using Jordan canonical form of the associated inertia tensor and transforming the coordinate system, the Hamiltonian has been changed to those of a rigid satellite. The Hamiltonian has been split into integrable and non-integrable parts. Using Deprit canonical transformation and Andoyer variables the integrable part has been reduced to a one-dimensional form. The reduced Hamiltonian shows that the regular dynamics of the satellite can be chaotic, under the influence of gravitational effects. To demonstrate various attitudinal dynamics of the satellite, a second-order Poincaré map is employed. This research shows firstly, that the attitudinal dynamics of Kelvin type gyrostat satellites and rigid satellites follow the same dynamical patterns, secondly, for non-linear analysis of dynamics of gyrostat satellite based on the perturbation methods, there is a preferable form for Hamiltonian of the system in the near-integrable fashion and thirdly the chaotic motion is originated from the gravitational field effects that can be suppressed by increasing the attitudinal energy of the satellite in comparison with the translational energy. 相似文献