STUDY ON THE EPOXY RESIN TOUGHENED BY HYDROXY-TERMINATED BUTADIENE-ACRYLONITRILE COPOLYMER

Toughened epoxy resin with excellent properties was obtained by adding organic acid anhydride curing agent and hydroxy-terminated butadiene-acrylonitrile copolymer (HTBN), which is cheaper than CTBN. The anhydride reacts with both epoxy groups on epoxy resin and hydroxyl groups on HTBN. As a result the soft long chains of HTBN and the rigid chain of epoxy resin form one network, giving the resin toughness. Two-phase structure of the toughened resin was observed by SEM and TEM.     

液-液-液微萃取-高效液相色谱法测定人血浆中的局部麻醉剂

建立了液-液-液微萃取与高效液相色谱联用技术同时测定人血浆中3种局部麻醉剂利多卡因、布比卡因和丁卡因的方法。考察了萃取时间、料液pH值和搅拌速度的影响,取佳萃取条件为萃取溶剂为200μL苯,接受相为1.0μL 0.2 mol/L HC l,搅拌速度为250 r/m in,萃取时间为45 m in。在该条件下,获得了高的富集因子(大于305倍)。方法的线性范围为:利多卡因和布比卡因0.025~5 mg/L,丁卡因0.05~5 mg/L,相关系数大于0.996;检出限依次为0.005、0.015和0.025 mg/L;相对标准偏差小于5%。该方法能有效地去除血浆中复杂基体的干扰,萃取效率高,有机溶剂消耗少,是一种有效、灵敏的同时测定血浆中利多卡因、布比卡因和丁卡因的方法。     

应用改良BP网络于多组分药物定量分析

ＢＰ网络自身学习速度慢的缺点，影响了其在多组分同时定量分析中的应用，为此，本文从误差函数、传递函数和网络参数等方面应用Ｆａｈｌｌｍａｎ和Ｃａｔｅｒ等所提修改方案改了Ｂ Ｐ网络，并将其应用于甲硝唑、先锋霉素、氯纱和氨卞四组分混合药物的同时定量分析，实验证明，在不损害网络预测精度的前提下，学习速度有了较大的提高。     

硅铁中硅、铝、磷的联合测定

采用一次称样、熔样,盐酸酸化后蒸至湿盐状,聚乙二醇聚合后过滤,形成残渣和滤下液。残渣用于以比色法测定硅含量,滤下液则用来分别测定铝(分光光度法)和磷(比色法)。该样品处理方式简化了分析步骤,降低了分析成本,硅、铝、磷的加标回收率在98.9%~103%之间,测定结果的相对标准偏差为0.18%~4.52%(n=6),标准样品的测定值与证书值一致。该方法可满足日常分析要求,特别适用于中小型实验室对硅铁样品质量的监控。     

Small-molecule fluorescent probes for the detection of carbon dioxide

This review summarizes the design principles, recognition mechanisms, properties and functions of various kinds of small-molecule fluorescent probes for the detection of carbon dioxide     

Interaction of the antimicrobial peptide dicynthaurin with membrane phospholipids at the air-liquid interface

This paper reports the first study on the interaction of the antimicrobial peptide dicynthaurin with 1,2-dipalmitoyl-glycerophosphatidyl-glycerol investigated in monolayers at the air-liquid interface. The influence of the peptide on the two-dimensional phase behavior of the negatively charged lipid was elucidated by means of pressure-area isotherm measurements, fluorescence microscopy, and grazing incidence X-ray diffraction measurements. The pure peptide forms a stable monolayer at the air-liquid interface up to 30 mN/m as shown for both the monomeric and the dimeric cynthaurins. The peptide lipid interaction was monitored in isotherm measurements showing a strong adsorption of the peptide and stabilization at the interface promoted by the lipid monolayer. The X-ray diffraction measurements in agreement with fluorescence microscopy studies showed that the peptide destabilizes the condensed chain lattice, leading to a complete fluidization of the condensed lipid phase on physiological buffer. The adsorption of the peptide to the negatively charged lipid monolayer and the fluidization of the condensed chain lattice suggest a direct link to the peptides' ability to expand the bacterial membrane that would be relevant for the in vivo mode of action.     

Three kinds of TVS in a SIR epidemic model with saturated infectious force and vertical transmission

Three different vaccination and treatment strategies in the SIR epidemic model with saturated infectious force and vertical transmission are analyzed. The dynamics of epidemic models are globally investigated by using Floquet theory and comparison theorem of impulsive differential equation. Thresholds are identified and global stability results are proved. For every treatment and vaccination strategy, the disease-free periodic solution of impulsive system has been obtained and is found to be globally asymptotically stable when the basic reproduction number is less than one, equivalently the cure rate is larger than the threshold value, whereas the disease is persistent when the basic reproduction number is larger than one. These results indicate that a large cure rate will lead to the eradication of a disease.     

The dynamics of an impulsive delay SI model with variable coefficients

An impulsive delayed SI model with variable coefficients and a nonlinear incidence is formulated and analyzed. By introducing three thresholds, we obtain sufficient conditions for eradication and permanence of the disease, respectively. It is shown that the conditions depend on time delay for both the global attractivity of the positive infection-free periodic solution and permanence of the model. Furthermore, our results indicate that the disease will disappear if the ratio of the maximum to minimum of the pulse vaccination rate is lager than some value. The main feature of this paper is that we introduce multi-delays and variable coefficients into the SI model, and exhibit a new method which is applied to investigate this model. Numerical results show that the system we considered has complex dynamics including periodic and quasi-periodic oscillations.     

High-temperature impedance spectroscopy of BaFe0.5Nb0.5O3 ceramics doped with Bi0.5Na0.5TiO3

Bi_0.5Na_0.5TiO₃ (BNT)-doped BaFe_0.5Nb_0.5O₃ (BFN) ceramics were synthesized by a two-step solid-state reaction. Temperature dependence of dielectric properties measured at different frequencies was investigated over broad temperature and frequency ranges. Impedance spectroscopy and universal dielectric response were employed to study the relaxation behavior and conductivity mechanism of the ceramics in a frequency range from 40 Hz to 100 MHz and a temperature range from 300 K to 800 K. The complex plane impedance data revealed the bulk and grain boundary contributions toward conductivity processes in the form of semicircular arcs. The high-temperature conductivity of ceramics is attributable to thermally activated second ionized oxygen vacancy.