全文获取类型
收费全文 | 223篇 |
免费 | 2篇 |
专业分类
化学 | 119篇 |
晶体学 | 8篇 |
力学 | 22篇 |
数学 | 28篇 |
物理学 | 48篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2015年 | 6篇 |
2014年 | 9篇 |
2013年 | 12篇 |
2012年 | 12篇 |
2011年 | 24篇 |
2010年 | 5篇 |
2009年 | 9篇 |
2008年 | 15篇 |
2007年 | 12篇 |
2006年 | 9篇 |
2005年 | 4篇 |
2004年 | 8篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 6篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1970年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有225条查询结果,搜索用时 0 毫秒
1.
A discrete facility location problem is formulated where the total fixed cost for establishing the facilities includes a component that is a nonlinear function of the number of facilities being established. Some theoretical properties of the solution are derived when this fixed cost is a convex nondecreasing function of the number of facilities. Based on these properties an efficient bisection heuristic is developed where at each iteration, the classical uncapacitated facility location and/or m-median subproblems are solved using available efficient heuristics. 相似文献
2.
Stølen S Mohn CE Ravindran P Allan NL 《The journal of physical chemistry. B》2005,109(25):12362-12365
We discuss the importance of the topography of the potential energy hypersurface for the ionic conductivity of perovskite-related A(2)B(2)O(5) oxides. A correlation between the energetic preference of the cations for different coordination geometries and the ionic conductivity is proposed based on a first principles periodic density functional theory study of selected possible structures for Ba(2)In(2)O(5), Sr(2)Fe(2)O(5), Sr(2)Mn(2)O(5), and La(2)Ni(2)O(5). There are a large number of low-energy local minima on the potential energy hypersurfaces of the two first compounds due to an energetic preference for BO(4) tetrahedra. Tetrahedral environments are energetically unfavorable for Mn(III) in Sr(2)Mn(2)O(5) and for Ni(II) in La(2)Ni(2)O(5), and the number of low-energy configurations is relatively low in these two cases. Consistent with our findings, in contrast to Sr(2)Fe(2)O(5) and Ba(2)In(2)O(5), Sr(2)Mn(2)O(5) and La(2)Ni(2)O(5) do not exhibit transitions to disordered phases on heating, and there appear to be no reports of enhanced ionic conductivity for these compounds. Thus we suggest that the possibility of many different oxygen orderings associated with a variety of low-energy connectivity schemes within tetrahedral layers such as in the brownmillerite-based structures of Sr(2)Fe(2)O(5) and Ba(2)In(2)O(5) is a prerequisite for high ionic conductivity in perovskite-related A(2)B(2)O(5) oxides. 相似文献
3.
D. Indumathi M. V. N. Murthy V. Ravindran 《Zeitschrift fur Physik C Particles and Fields》1992,56(3):427-436
Following recent interest in the subject of polarisation phenomena, we discuss the cross-sections and polarisation asymmetry in 2-jet production in polarised proton-polarised proton (
) scattering. We set up a complete set of parametrisations for the proton spin-dependent parton densities and use them to demonstrate that this cross-section is dominated by gluonic terms. Hence, a measurement of the asymmetry in such processes will provide information on the gluon spin-dependent density. We further show that a factorisation of the hadronic cross-section a la Combridge and Maxwell's work in unpolarised 2-jet production also applies to the spin-dependent case. Hence, the cross-section can be written in terms of a genericpolarised parton density, which can then be measured in the process. 相似文献
4.
Selvan Ravindran Sudipta Basu Santosh Kapil Kumar Gorti Prashant Surve Navya Sloka 《Biomedical chromatography : BMC》2013,27(5):575-582
The sulfonylurea urea drug glyburide (glibenclamide) is widely used for the treatment of diabetes milletus and gestational diabetes. In previous studies monohydroxylated metabolites were identified and characterized for glyburide in different species, but the metabolite owing to the loss of cyclohexyl ring was identified only in mouse. Glyburide upon incubation with hepatic microsomes resulted in 10 metabolites for human. The current study identifies new metabolites of glyburide along with the hydroxylated metabolites that were reported earlier. The newly identified drug metabolites are dihydroxylated metabolites, a metabolite owing to the loss of cyclohexyl ring and one owing to hydroxylation with dehydrogenation. Among the 10 identified metabolites, there were six monohydroxylated metabolites, one dihydroxylated metabolite, two metabolites owing to hydroxylation and dehydrogenation, and one metabolite owing to the loss of cyclohexyl ring. New metabolites of glyburide were identified and characterized using liquid chromatography–diode array detector–quadruple‐ion trap–mass spectrometry/mass spectrometry (LC‐DAD‐Q‐TRAP‐MS/MS). An enhanced mass scan–enhanced product ion scan with information‐dependent acquisition mode in a Q‐TRAP‐MS/MS system was used to characterize the metabolites. Liquid chromatography with diode array detection was used as a complimentary technique to confirm and identify the metabolites. Metabolites formed in higher amounts were detected in both diode array detection and mass spectrometry detection. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
5.
It has been observed that poly(styrene peroxide) with a high molecular weight is thermally less stable than the same polymer with a low molecular weight. This has been explained as being due to the strain on the O-O bond due to the greater polymer chain length. 相似文献
6.
Gurmessa Getahun Tadesse Singh Girija Shankar 《Research on Chemical Intermediates》2017,43(11):6447-6504
Research on Chemical Intermediates - Metal–carbenoids from α-diazocarbonyl compounds are well-known reactive intermediates with a long history of useful applications in synthetic organic... 相似文献
7.
The spectroscopic properties of Nω-nitro-l-arginine were investigated by FT-IR, UV-VIS, and 1H NMR spectra. Geometrical parameters and energies were calculated using the density functional theory (DFT) B3LYP method with the 6-311G basis set. Geometrical optimization of the molecule has been performed, vibrational spectra have been calculated, and fundamental vibrations have been determined from the total energy distribution (TED) of the vibrational modes. The HOMO-LUMO analysis is carried out for various electric fields (0.0–0.025 A?1). The HOMO-LUMO gap is decreased while increasing the electric field. The calculated quantum chemical parameters are calculated and correlated to the inhibition efficiency, A Mullliken population was also important for determining local reactivity by indicating reactive centers and identifying potential nucleophilic and electrophilic attack sites. Charge transfer occurs inside the compound based on the HOMO LUMO gap. Calculations of DFT were evaluated in their ability to predict inhibition efficiency. 相似文献
8.
Nair Supriya Aswathy UV Mathew Ann Raghavan Rajeev 《Journal of Thermal Analysis and Calorimetry》2017,128(3):1731-1741
Journal of Thermal Analysis and Calorimetry - Thermal decomposition, thermal conductivity, specific heat and flammability of polydimethyl siloxane (PDMS) resin and three PDMS-based systems with... 相似文献
9.
R. Ravindran 《Rheologica Acta》1972,11(1):93-98
Summary In the present paper, we have undertaken a comparative study of the flow behaviour of two types of fluids —Eringen's mioropolar fluid andStokes' couple stress fluid — in a simple oscillatory flow. This study was undertaken with a view to see if the close resemblance of the flow behaviour of these two fluids in steady shearing flows was maintained even in time dependent flows. We find that the flow behaviour of these two fluids are widely different in oscillatory motion. 相似文献
10.
High pressure Raman spectroscopic studies are carried out on negative thermal expansion material ZrW2O8. The system exhibits amorphization at 2.2+/-0.3 GPa via an intermediate orthorhombic phase. In the cubic phase most modes below 50 meV are found to have negative Gruneisen parameter. Using the reported phonon density of states thermal properties are calculated and compared with the reported results. In contrast to the earlier belief, the present results show that modes of energies much higher than 10 meV also contribute substantially to the negative thermal expansion. 相似文献