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排序方式: 共有93条查询结果,搜索用时 15 毫秒
1.
Pimenta AM Rates B Bloch C Gomes PC Santoro MM de Lima ME Richardson M Cordeiro Mdo N 《Rapid communications in mass spectrometry : RCM》2005,19(1):31-37
Previous studies of the fractionated venom of the Brazilian armed spider Phoneutria nigriventer, obtained by gel filtration, have demonstrated the presence of a fraction PhM, a pool of small peptides (up to 2000 Da) that provoke contractions in smooth muscle of guinea pig ileum. Initial attempts to sequence these peptides were largely unsuccessful because of the low purification yield and the fact that the majority seemed to be blocked at their N-termini. In the present work, analysis of this venom fraction by mass spectrometry has revealed the existence of a highly complex mixture of peptides with molecular weights corresponding to those observed for the muscle-active peptides previously described (800-1800 Da). These peptides appear to be a family of isoforms with some particular features. The amino acid sequences of 15 isoforms have been determined by tandem mass spectrometry (MS/MS) using both electrospray ionization quadrupole time-of-flight mass spectrometry (ESI-Q/ToFMS) and matrix-assisted laser desorption/ionization tandem time-of-flight mass spectrometry (MALDI-ToF/ToFMS). These molecules contain post-translational modifications such as proteolysis and C-terminal amidation, which combine to generate additional isoforms. All the isoforms sequenced in this study possess an N-terminal pyroglutamic acid residue. A search for sequence similarities with other peptides in databanks revealed that these peptides are structurally related to the tachykinins, a family of neuro-hormone peptides. The data obtained in this study will be essential for the subsequent steps of this research, the synthesis of these peptides and pharmacological characterization of their biological activity. 相似文献
2.
Marcos T.O. Pimenta Sérgio H.M. Soares 《Journal of Mathematical Analysis and Applications》2012,390(1):274-289
Some superlinear fourth order elliptic equations are considered. A family of solutions is proved to exist and to concentrate at a point in the limit. The proof relies on variational methods and makes use of a weak version of the Ambrosetti–Rabinowitz condition. The existence and concentration of solutions are related to a suitable truncated equation. 相似文献
3.
An easy and mild two-step one-pot reaction allowed the synthesis of functionalized N-triazolyl maleimide. Next, the addition of propargyl alcohol and propargyl amine to the N-acyliminium ion mediated by Lewis acid, In(OTf)3, allowed the introduction of a second 1,2,3-triazol ring at position 5 of the amide. The products in both reactions were achieved in moderate to good yields. 相似文献
4.
Hybrid and multi-field variational principles for geometrically exact three-dimensional beams 总被引:2,自引:0,他引:2
This paper addresses the development of several alternative novel hybrid/multi-field variational formulations of the geometrically exact three-dimensional elastostatic beam boundary-value problem. In the framework of the complementary energy-based formulations, a Legendre transformation is used to introduce the complementary energy density in the variational statements as a function of stresses only. The corresponding variational principles are shown to feature stationarity within the framework of the boundary-value problem. Both weak and linearized weak forms of the principles are presented. The main features of the principles are highlighted, giving special emphasis to their relationships from both theoretical and computational standpoints. 相似文献
5.
A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented. The orientation of the carbon hexagons with respect to the edge axis, in the so-called armchair or zigzag arrangements, is distinguished spectroscopically by the intensity of a disorder-induced Raman peak. This effect is explained by applying the double resonance theory to a semi-infinite graphite crystal and by considering the one-dimensional character of the defect. 相似文献
6.
J. J. Barroso P. J. Castro A. A. Pimenta V. A. Spassov R. A. Corrêa T. Idehara I. Ogawa 《International Journal of Infrared and Millimeter Waves》1997,18(11):2147-2160
The design and operation of a 32 GHz pulsed gyrotron are reported. The device is step-tuned between the TE1,2 (24.16 GHz) and TE0,2 (31.78 GHz) modes with cathode voltages ranging from 30 to 40kV and beam current up to 5.0A. Experimental frequencies are in close agreement with the self-consistent calculated values and in the TE2,2 resonator mode an output peak power of 6kW corresponding to an 18% efficiency was measured by using a fast response calorimeter with a thermal sensitivity of 0.1°C/Wmin. 相似文献
7.
M. C. Abreu M. Alimi C. Baglin A. Baldit G. P. Barreira M. Bedjidian P. Bordalo S. Borenstein J. Britz A. Bussiere P. Busson A. Casaca R. Cases J. Castor C. Charlot B. Chaurand D. Contardo E. Descroix A. Devaux J. Fargeix X. Felgeyrolles P. Force L. Fredj J. M. Gago C. Gerschel P. Gomes P. Gorodetzky J. Y. Grossiord A. Guichard J. P. Guillaud R. Haroutunian L. Kluberg L. Kraus G. Landaud I. Linck C. Louren?o A. Maio L. Peralta M. Pimenta J. R. Pizzi C. Racca S. Ramos A. Romana R. Salmeron A. Sinquin P. Sonderegger J. Varela NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,38(1):129-133
The like-sign dimuons copiously recorded in the NA 38 experiment both inp-U and O?U reactions at 200 GeV/nucleon are interpreted as resulting from decays of π andK mesons in comparable proportions. The ++/?? ratio is large (?1.7) and ascribed to theK + being more copiously produced than theK ?. Both the average transverse momentum and the ++/?? ratio are comparable forp-U and O?U reactions, and both increase only slightly with the transverse energyE T . 相似文献
8.
9.
AbstractThis article presents an overview of optical methodologies to aid the diagnosis and differentiation of thyroid and parathyroid tissues. In particular, we review the several techniques and associated methodologies that allow in vivo and ex vivo optical characterization of thyroid and parathyroid tissues. Emphasis is placed on the research potential of these techniques and whether intrinsic characteristics can provide useful contrast for the diagnosis of human thyroid and parathyroid malignant lesions. 相似文献
10.
The combined effects of the processing parameters upon rheological properties of biopolymers produced by Rhizobium tropici were studied as a function of the Ca(+2) ions' concentration variation, yeast extract concentration added to the medium, aeration, and agitation, maintaining the mannitol concentration in 10 g/L. The experiments were carried out using a fermenter with 20-L capacity as a reactor. All processing parameters were monitored online. The temperature [(30 +/- 1) degrees C] and pH values (7.0) were kept constant throughout the experimental time. As a statistical tool, a complete 2(3) factorial design with central point and response surface was used to investigate the interactions between relevant variables of the fermentation process: calcium carbonate concentration, yeast extract concentration, aeration, and agitation. The processing parameter setup for reaching the maximum response for rheological propriety production was obtained when applying mannitol concentration of 10.0 g/L, calcium carbonate concentration 1.0 g/L, yeast extract concentration 1.0 g/L, aeration 1.30 vvm, and agitation 800 rpm. The viscosimetric investigation of polysaccharide solutions exposed their shear-thinning behavior and polyelectrolytic feature. 相似文献