全文获取类型
收费全文 | 381318篇 |
免费 | 3068篇 |
国内免费 | 1005篇 |
专业分类
化学 | 204574篇 |
晶体学 | 6366篇 |
力学 | 17614篇 |
综合类 | 14篇 |
数学 | 39372篇 |
物理学 | 117451篇 |
出版年
2019年 | 3561篇 |
2018年 | 4760篇 |
2017年 | 4712篇 |
2016年 | 6829篇 |
2015年 | 3842篇 |
2014年 | 6449篇 |
2013年 | 15743篇 |
2012年 | 11532篇 |
2011年 | 13934篇 |
2010年 | 10442篇 |
2009年 | 10514篇 |
2008年 | 12980篇 |
2007年 | 13037篇 |
2006年 | 11908篇 |
2005年 | 10658篇 |
2004年 | 9968篇 |
2003年 | 9088篇 |
2002年 | 8975篇 |
2001年 | 10709篇 |
2000年 | 8063篇 |
1999年 | 6262篇 |
1998年 | 5159篇 |
1997年 | 5241篇 |
1996年 | 5015篇 |
1995年 | 4539篇 |
1994年 | 4526篇 |
1993年 | 4310篇 |
1992年 | 5053篇 |
1991年 | 5068篇 |
1990年 | 4951篇 |
1989年 | 5028篇 |
1988年 | 4914篇 |
1987年 | 4930篇 |
1986年 | 4581篇 |
1985年 | 6055篇 |
1984年 | 6124篇 |
1983年 | 5124篇 |
1982年 | 5278篇 |
1981年 | 5190篇 |
1980年 | 4921篇 |
1979年 | 5406篇 |
1978年 | 5620篇 |
1977年 | 5652篇 |
1976年 | 5595篇 |
1975年 | 5286篇 |
1974年 | 5120篇 |
1973年 | 5261篇 |
1972年 | 3759篇 |
1968年 | 3367篇 |
1967年 | 3440篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
R. Grosseuvres A. Comandini A. Bentaib N. Chaumeix 《Proceedings of the Combustion Institute》2019,37(2):1537-1546
The present work reports new experimental and numerical results of the combustion properties of hydrogen based mixtures diluted by nitrogen and steam. Spherical expanding flames have been studied in a spherical bomb over a large domain of equivalence ratios, initial temperatures and dilutions at an initial pressure of 100 kPa (Tini = 296, 363, 413 K; N2/O2 = 3.76, 5.67, 9; %Steam = 0, 20, 30). From these experiments, the laminar flame speed , the Markstein length L’, the activation energy Ea and the Zel'dovich β number have been determined. These parameters were also simulated using COSILAB® in order to verify the validity of the Mével et al. [1] detailed kinetic mechanism. Other parameters as the laminar flame thickness δ and the effective Lewis number Leeff were also simulated. These new results aim at providing an extended database that will be very useful in the hydrogen combustion hazard assessment for nuclear reactor power plant new design. 相似文献
2.
ABSTRACTQM(UB3LYP)/MM(AMBER) calculations were performed for the locations of the transition structure (TS) of the oxygen–oxygen (O–O) bond formation in the S4 state of the oxygen-evolving complex (OEC) of photosystem II (PSII). The natural orbital (NO) analysis of the broken-symmetry (BS) solutions was also performed to elucidate the nature of the chemical bonds at TS on the basis of several chemical indices defined by the occupation numbers of NO. The computational results revealed a concerted bond switching (CBS) mechanism for the oxygen–oxygen bond formation coupled with the one-electron transfer (OET) for water oxidation in OEC of PSII. The orbital interaction between the σ-HOMO of the Mn(IV)4–O(5) bond and the π*-LUMO of the Mn(V)1=O(6) bond plays an important role for the concerted O–O bond formation for water oxidation in the CaMn4O6 cluster of OEC of PSII. One electron transfer (OET) from the π-HOMO of the Mn(V)1=O(6) bond to the σ*-LUMO of the Mn(IV)4–O(5) bond occurs for the formation of electron transfer diradical, where the generated anion radical [Mn(IV)4–O(5)]-? part is relaxed to the ?Mn(III)4?…?O(5)- structure and the cation radical [O(6)=Mn(V)1]+ ? part is relaxed to the +O(6)–Mn(IV)1? structure because of the charge-spin separation for the electron-and hole-doped Mn–oxo bonds. Therefore, the local spins are responsible for the one-electron reductions of Mn(IV)4->Mn(III)4 and Mn(V)1->Mn(IV)1. On the other hand, the O(5)- and O(6)+ sites generated undergo the O–O bond formation in the CaMn4O6 cluster. The Ca(II) ion in the cubane- skeleton of the CaMn4O6 cluster assists the above orbital interactions by the lowering of the orbital energy levels of π*-LUMO of Mn(V)1=O(6) and σ*-LUMO of Mn(IV)4–O(5), indicating an important role of its Lewis acidity. Present CBS mechanism for the O–O bond formation coupled with one electron reductions of the high-valent Mn ions is different from the conventional radical coupling (RC) and acid-base (AB) mechanisms for water oxidation in artificial and native photosynthesis systems. The proton-coupled electron transfer (PC-OET) mechanism for the O–O bond formation is also touched in relation to the CBS-OET mechanism. 相似文献
3.
4.
A 1.5-μm eye-safe, 3-D scanning, and compact Mie LIght Detection and Ranging (LIDAR) is presented. The transmitter of the LIDAR is based on a KTA optical parameter oscillator (OPO) resonator. For detecting return signals, an InGaAs APD is used. The all solid-state OPO laser transmitter has the feature of small volume and lightweight, which allows a 165-lb compact eye-safe scanning LIDAR to be constructed. A system simulation using our own model was conducted to direct the system development. A method to solve the problem with small active area APD detectors was developed and described. The preliminary field-test measurement results indicated that the LIDAR has the capability to detect aerosols and clouds in lower atmospheres up to three dimensions. 相似文献
5.
The structure, chemical composition, and magnetic properties of electrochemically deposited nanocrystalline Co-Ni-Fe films
were investigated using a number of techniques. A high saturation magnetic induction up to B
s
= 21 kG was attained. An enhancement of the saturation magnetization compared to the ideal anticipated one was revealed,
which correlated with the nonlinear behavior of the structural phase composition and lattice parameters with the change of
the composition.
The text was submitted by the authors in English. 相似文献
6.
N. I. Golovina G. N. Nechiporenko G. G. Nemtsev G. P. Dolganova V. P. Roshchupkin D. B. Lempert G. B. Manelis 《Russian Journal of Applied Chemistry》2007,80(1):24-30
Methods for phase stabilization of ammonium nitrate were sought for in order to considerably expand the application area of this oxidizing agent in various-purpose self-combustible formulations, including that in a new generation of gas-generating formulations for automobile air bags. New methods for stabilization of ammonium nitrate were studied and, in particular, a search was made for organic compounds that can stabilize ammonium nitrate even at their low content. The mechanism of phase state stabilization of ammonium nitrate by compounds of this kind was examined. 相似文献
7.
The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature. 相似文献
8.
9.
A. N. Grishkov 《Algebra and Logic》1998,37(5):294-306
Ordinary cohomologies in an algebra most often exhibit themselves either as objects that describe extensions (of algebras,
groups, or modules) or as subjects hindering the existence of algebraic constructions. We introduce the notion of nonlinear
cohomologies at a level of cochain complexes, furnish particular examples for Lie algebras, and give an interpretation of
first nonlinear cohomologies in terms of “quasiextensions” of orthogonal modules.
Translated fromAlgebra i Logika, Vol. 37, No. 5, pp. 522–541, September–October, 1998. 相似文献
10.
We investigate theoretically the effects of optical absorption and saturation of the non-linear index of refraction on the
bistability of non-linear distributed feedback structures (NLDFBs). By assuming that the Kerr non-linearity saturates in an
exponential fashion, we obtain for the first time closed-form expressions for the so-called self-phase and cross-phase modulation
terms. Our investigation shows that both absorption and, in particular, saturation significantly affect the bistable properties
of this structure and in many cases eliminate this response completely. In some cases, however, saturation alters the NLDFB's
transfer characteristics in a potentially useful manner. We find that weak levels of saturation may increase the contrast
ratio between the intensities of the high and low bistable states. At increasing levels of saturation, where bistability is
no longer observed, we find regimes where the NLDFB structure could possibly be used for optical amplification.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献