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1.
Debendra K. Mohapatra Dhananjoy Mondal Mukund S. Chorghade Mukund K. Gurjar 《Tetrahedron letters》2006,47(52):9215-9219
The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy. 相似文献
2.
Sherif Yehia C. Mitros Sanjeev Kumar S. Jha Glenn M. Julian R. A. Dunlap 《Hyperfine Interactions》1987,34(1-4):415-418
The systematics of hyperfine magnetic fields at sp impurities on the Z-sites in Co based Heusler alloys are investigated. New TDPAC measurements of Cd hyperfine fields are reported. 相似文献
3.
In this article, the question is considered whether there exist finite translation planes with arbitrarily small kernels admitting nonsolvable collineation groups. For any integerN, it is shown that there exist translation planes of dimension >N and orderq
3 admittingGL(2,q) as a collineation group. 相似文献
4.
Mukund G. Kulkarni Attrimuni P. Dhondge Dnyaneshwar D. Gaikwad Ajit S. Borhade Sanjay W. Chavhan 《Tetrahedron letters》2006,47(6):1003-1005
A two-step synthetic sequence for an efficient synthesis of 3-allylindoles is described. 相似文献
5.
Mukund K. Gurjar 《Tetrahedron letters》2006,47(39):6979-6981
The synthesis of a chiral cyclic nitrone with l-arabino configuration and its application in the total synthesis of radicamine B is reported. An agreement in the spectral data with natural radicamine B but specific rotation with an opposite sign warranted a revision of the absolute configuration of radicamine B. 相似文献
6.
Translation planes of order q
2 containing non-Desarguesian Baer subplanes are used to construct transversal-free translation nets with very small deficiencies. Also, a generalization of the ideas of Bruen shows that any non-Desarguesian spread in PG(3, q) produces a transversal-free net of small deficiency. 相似文献
7.
We have studied isospin symmetry violation in nuclear reactions by measuring simultaneously the cross-section of the following
two reactionsp +d →3H π+ andp +d →3He π0. The experiment was perfomed at the cooler synchrotron accelerator COSY, Jülich at several beam energies close to the correspondingη production threshold. We also have ongoing programmes onη-nucleus final-state interaction studies viap+6 Li →7 Be +η reactions, high resolution search for dibaryonic resonances and lambda-proton final state interaction studies. The experimental
details and results obtained so far are presented here 相似文献
8.
We have initiated a search for a new type of nuclear matter, theη-mesic nucleus, using beams from the multi-GeV hadron facility, COSY at Juelich, Germany. A large acceptance scintillator detector, ENSTAR has been designed and built at BARC, Mumbai and fully assembled and tested at COSY. A test run for calibration and evaluation has been completed. In this contribution we present the design and technical details of the ENSTAR detector and how it will be used to detect protons and pions (the decay products ofη-mesic bound state). The detector is made of plastic scintillators arranged in three concentric cylindrical layers. The readout of the detectors is by means of optical fibres. The layers are used to generate ΔE –E spectra for particle identification and total energy information of stopped particles. The granularity of the detector allows for position (θ and ?ø determination making the event reconstruction kinematically complete 相似文献
9.
Mukund K. Gurjar Seetaram Mohapatra Usha D. Phalgune Vedavati G. Puranik Debendra K. Mohapatra 《Tetrahedron letters》2004,45(42):7899-7902
An enantioselective synthesis of the C12-C29 fragment of amphidinolide E is described. Key transformations include an intramolecular mercuriocyclization reaction, stereoselective introduction of methyl group at the C2 position, and Stille coupling for the introduction of the diene side chain. 相似文献
10.
Efficient syntheses of the phytoalexins brassilexin, sinalexin, and analogues are demonstrated through the application of the Vilsmeier formylation to indoline-2-thiones followed by a new aqueous ammonia workup procedure. Similarly, a very concise two-pot synthesis of the phytoalexins wasalexins using sequential formylation-amination of indolin-2-ones is described. Remarkably, this novel aqueous ammonia workup allows the sequential one-pot formylation-amination, expanding substantially the scope of the Vilsmeier formylation of both indoline-2-thiones and indolin-2-ones. The examination of the formylation-amination reaction and optimization of conditions, as well as the syntheses and antifungal activities of several brassilexin analogues, are reported. 相似文献