全文获取类型
收费全文 | 1437篇 |
免费 | 40篇 |
国内免费 | 14篇 |
专业分类
化学 | 878篇 |
晶体学 | 7篇 |
力学 | 46篇 |
数学 | 328篇 |
物理学 | 232篇 |
出版年
2023年 | 5篇 |
2022年 | 13篇 |
2021年 | 17篇 |
2020年 | 25篇 |
2019年 | 14篇 |
2018年 | 31篇 |
2017年 | 26篇 |
2016年 | 55篇 |
2015年 | 57篇 |
2014年 | 41篇 |
2013年 | 96篇 |
2012年 | 81篇 |
2011年 | 105篇 |
2010年 | 84篇 |
2009年 | 55篇 |
2008年 | 84篇 |
2007年 | 84篇 |
2006年 | 58篇 |
2005年 | 60篇 |
2004年 | 64篇 |
2003年 | 37篇 |
2002年 | 45篇 |
2001年 | 23篇 |
2000年 | 32篇 |
1999年 | 21篇 |
1998年 | 14篇 |
1997年 | 14篇 |
1996年 | 13篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 12篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1966年 | 6篇 |
1965年 | 4篇 |
1962年 | 6篇 |
1959年 | 7篇 |
1958年 | 7篇 |
1957年 | 22篇 |
1956年 | 13篇 |
1955年 | 15篇 |
排序方式: 共有1491条查询结果,搜索用时 15 毫秒
1.
G. Ullrich D. Herzog R. Liska P. Burtscher N. Moszner 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4948-4963
Camphorquinone (CQ), a widely used photoinitiator (PI) in dental applications, was covalently bonded to aromatic amines to enhance the rate of electron and proton transfer effect due to the close vicinity of the diketone and the amine group. 10‐bromocamphorquinone and 10‐bromomethylcamphorquinone were selected as suitable precursors for esterification with the carboxyl group containing aromatic amines based on 4‐dimethylaminobenzoic acid. Properties of the new photoinitiating systems were investigated by UV spectroscopy and differential scanning photocalorimetry in lauryl acrylate. Compared to physical mixtures, in all cases similar or even better performance was obtained. Surprisingly, 10‐acetyl derivatives 7 – 9 and 18 especially, were found to be highly reactive. Compared to CQ/ethyl 4‐dimethylaminobenzoate, the rate of photopolymerization was increased by a factor of up to 2. Intramolecular reaction was confirmed by photo‐differential scanning calorimetry experiments with varying PI concentrations. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4948–4963, 2004 相似文献
2.
3.
Miroslav Ploščica 《Algebra Universalis》2003,49(1):1-12
4.
In this paper we prove that all positive eigenvalues of the Laplacian of an arbitrary simple graph have some positive lower bounds. For a fixed integer k 1 we call a graph without isolated vertices k-minimal if its kth greatest Laplacian eigenvalue reaches this lower bound. We describe all 1-minimal and 2-minimal graphs and we prove that for every k 3 the path Pk+1 on k + 1 vertices is the unique k-minimal graph. 相似文献
5.
Let A be a Weil algebra. The bijection between all natural operators lifting vector fields from m-manifolds to the bundle functor K
A
of Weil contact elements and the subalgebra of fixed elements SA of the Weil algebra A is determined and the bijection between all natural affinors on K
A
and SA is deduced. Furthermore, the rigidity of the functor K
A
is proved. Requisite results about the structure of SA are obtained by a purely algebraic approach, namely the existence of nontrivial SA is discussed. 相似文献
6.
A comparison of the concept of volume increments created by W. Biltz with that based on quantum mechanical calculations by R.F.W. Bader was performed for crystal structures of binary metal nitrides and ‐subnitrides. The mutual comparison of both concepts permits insights into the bonding relationships of these compounds and reveals the considerable range of volume demand of a strongly polarisable bonding partner, such as the nitride ion. Finally it becomes clear that the Biltz volume increments show a quantum‐chemical relevance in the chemistry of solids. 相似文献
7.
Miroslav Menšík 《Czechoslovak Journal of Physics》1998,48(4):469-475
A time solution of the excimer-ion pair system is presented here with a special attention to the time asymptote.
Presented at the Czech-Israeli-German Symposium “Dynamical Processes in Condensed Molecular Systems”, Prague, Czech Republic,
26–30 May 1997.
This work was supported by the grant No. C 1050601 of the Grant Agency of the Academy of Sciences of the Czech Republic. 相似文献
8.
Monika Schuster Robert Inführ Claudia Turecek Jürgen Stampfl Franz Varga Robert Liska 《Monatshefte für Chemie / Chemical Monthly》2006,4(4):843-853
To substitute cross-linked photopolymers in rapid prototyping of mold materials and therefore extend the range of materials
which can be casted, organo-soluble photopolymers were developed. Branched bisalkylacrylamides were suitable as base component
for such formulations, due to their high reactivity, good mechanical properties, and excellent solubility of the formed polymers.
These molding materials were used to prepare cellular biocompatible materials which could be used as bone replacement materials.
Biocompatible crosslinkers based on methacrylates from hydrolyzed gelatine or lactic acid ethyleneglycol blockcopolymers and
commercially available reactive diluents are the base components of such a formulation. Biocompatibility was investigated
by osteoblast-like cells. Cellular biocompatible parts were obtained by thermal polymerization in soluble mould materials
prepared by 3D-photoshaping. 相似文献
9.
Fibers and 3D mesh scaffolds from biodegradable starch-based blends: production and characterization
The aim of this work is the production of fibers from biodegradable polymers to obtain 3D scaffolds for tissue engineering of hard tissues. The scaffolds required for this highly demanding application need to have, as well as the biological and mechanical characteristics, a high degree of porosity with suitable dimensions for cell seeding and proliferation. Furthermore, the open cell porosity should have adequate interconnectivity for a continuous flow of nutrients and outflow of cell metabolic residues as well as to allow cell growth into confluent layers. Blends of corn starch, a natural biodegradable polymer, with other synthetic polymers (poly(ethylene vinyl alcohol), poly(epsilon-caprolactone), poly(lactic acid)) were selected for this work because of their good balance of properties, namely biocompatibility, processability and mechanical properties. Melt spinning was used to produce fibers from all the blends and 3D meshes from one of the starch-poly(lactic acid) blends. The experimental characterization included the evaluation of the tensile mechanical properties and thermal properties of the fibers and the compression stiffness, porosity and degradation behavior of the 3D meshes. Light microscopy picture of 3D meshes. 相似文献
10.
The phase analysis of cryolite (Na3AlF6) and sodium metasilicate (Na2SiO3) was performed by thermal analysis. The eutectic system with a region of two immiscible substances at a concentration of Na2SiO3 between 42.8 and 46.3 mol‐% was identified and the eutectic temperature determined to (886±2) °C. Based on the results of mass‐loss measurements, it was assumed that the introduced Na2SiO3 reacts with Na3AlF6 due to the formation of some nonvolatile stable compounds. The stable reaction products were identified by X‐ray diffraction analysis and IR spectroscopy of the spontaneously cooled samples, which established the formation of NaF and stable amorphous aluminosilicate compounds. 相似文献